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New high-sensitivity hybrid magnetostrictive/electroactive magnetic field sensors

Jiankang Huang、Robert C. O’Handley、David Bono2003-07-25Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A recently developed class of magnetic field sensors is based on the action of a magnetostrictive material on a piezoelectric material. Described here is a significant improvement on this class, a passive magnetic field sensor made of layers of Terfenol-D {Fe<sub>2</sub>(Dy<sub>0.7</sub>Tb<sub>0.3</sub>)} magnetostric…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

A Novel β-CD−Hemin Complex Photocatalyst for Efficient Degradation of Organic Pollutants at Neutral pHs under Visible Irradiation

Yingping Huang、Wanhong Ma、Jing Li 等 7 位作者2003-07-25The Journal of Physical Chemistry B

A novel photooxidative system for degrading toxic organic pollutants, including organic dyes and small molecular compounds such as Rhodamine B (RhB) and 2,4-dichlorophenol (DCP), is reported. A metal−organic complex (β-cyclodextrin−hemin, CDH), synthesized by combining β-CD with the bioactive small molecule hemin, can…

Advanced Photocatalysis TechniquesPorphyrin and Phthalocyanine ChemistryCovalent Organic Framework Applications

Long-Range Ferromagnetic Ordering in Two-Dimensional Coordination Polymers Co[N(CN)2]2(L) [L = Pyrazine Dioxide (pzdo) and 2-Methyl Pyrazine Dioxide (mpdo)] with Dual μ- and μ3-[N(CN)2] Bridges

Hao‐Ling Sun、Song Gao、Bao‐Qing Ma 等 4 位作者2003-07-25Inorganic Chemistry

Two novel coordination polymers of Co(II) with dicyanamide (dca) were obtained by the addition of ancillary ligands of pyrazine dioxide (pzdo) and 2-methyl pyrazine dioxide (mpdo) into the Co-dca binary system, respectively. Co[N(CN)(2)](2)(pzdo) (1) crystallizes in the orthorhombic space group of Pnnm (No. 58) with a…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

In situ epoxidized natural rubber: Improved oil resistance of natural rubber

Varaporn Tanrattanakul、Boonsit Wattanathai、Adul Tiangjunya 等 4 位作者2003-07-25Journal of Applied Polymer Science

Abstract This study sought to synthesize an in situ epoxidized natural rubber (NR) from 20% dry rubber content latex stabilized by nonionic surfactant, 5 phr of Terric 16A16, in the presence of hydrogen peroxide and formic acid at the temperature of 50°C. The molar ratios of H 2 O 2 and HCOOH to isoprene unit were equ…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Self-Assembly of Mesoporous Nanoscale Silica/Gold Composites

Robert Nooney、Dhanasekaran Thirunavukkarasu、Yimei Chen 等 5 位作者2003-07-25Langmuir

The effect of cetyltrimethylammonium bromide (CTAB) template concentration, solvent conditions, and silica source on the structure and self-assembly of mesoporous nanoscale silica/gold composites was investigated. Nanocomposites were analyzed using X-ray diffraction, transmission electron microscopy, and liquid nitrog…

Catalytic Processes in Materials SciencePhotonic Crystals and ApplicationsMesoporous Materials and Catalysis

Polymerization of maleic anhydride–modified plant oils with polyols

Tarık Eren、Seli̇m H. Küsefoǧlu、Richard P. Wool2003-07-25Journal of Applied Polymer Science

Abstract In this study soybean oil triglycerides were reacted with maleic anhydride in an ene reaction to introduce more than two maleate residues per triglycerides. The maleinized soybean oil (SOMA) was then polymerized with diols to the half‐ester stage only. Two different types of alcohols was used in this work: (1…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Towards direct correlations between spin-crossover and structural features in iron(II) complexes

Mathieu Marchivie、Philippe Guionneau、Jean‐François Létard 等 4 位作者2003-07-25Acta Crystallographica Section B Structural Science

The [Fe(PM-BiA)(2)(NCS)(2)] complex, where PM is N-2-pyridylmethylene and BiA is 4-aminobiphenyl, crystallizes in two polymorphs. The two phases, denoted (I) and (II), undergo a spin-crossover when the sample is cooled and present distinct spin-transition features as (I) shows a very abrupt spin transition, while (II)…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

A Carbon Nanotube Cross Structure as a Nanoscale Quantum Device

Alireza Nojeh、Gregory W. Lakatos、Shu Peng 等 5 位作者2003-07-25Nano Letters

Traditional lithographically defined quantum wells in 2D electron gases are often too big (several hundreds of nanometers to a few micrometers) to exhibit single-electron effects at room temperature. Here, a structure is proposed that makes use of the electromechanical properties of single-walled carbon nanotubes to f…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Diffusive motion of antiphase domain boundaries inFe3O4films

W. Eerenstein、T. T. M. Palstra、T. Hibma 等 4 位作者2003-07-25Physical review. B, Condensed matter

The antiphase domain structure in epitaxial ${\mathrm{Fe}}_{3}{\mathrm{O}}_{4}$ films determines its physical properties such as superparamagnetism, resistivity, and magnetoresistance. A good knowledge and control of the domain sizes in these films is therefore of utmost importance. We report on the finding that the a…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Vertically Aligned Carbon Nanotubes Grown by Pyrolysis of Iron, Cobalt, and Nickel Phthalocyanines

Nam Seo Kim、Yun Tack Lee、Jeunghee Park 等 8 位作者2003-07-25The Journal of Physical Chemistry B

Carbon nanotubes (CNTs) were grown vertically aligned on silicon oxide substrates by pyrolyzing iron phthalocyanine (FePc), cobalt phthalocyanine (CoPc), and nickel phthalocyanine (NiPc) in the temperature range 700−1000 °C. As the temperature increases from 700 to 1000 °C, the growth rate of CNTs increases by a facto…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Anticancer and antioxidative effects of micronized zeolite clinoptilolite.

Neven Žarković、Kamelija Žarković、Marijeta Kralj 等 8 位作者2003-07-25PubMed

BACKGROUND: Treatment of cancer-bearing mice and dogs with micronized zeolite clinoptilolite (MZ) led to improvement of the overall health status, prolongation of life span and decrease of tumor size in some cases. It also reduced lipid peroxidation in the liver of mice. MATERIALS AND METHODS: The experiments were per…

Mesoporous Materials and CatalysisChemotherapy-induced cardiotoxicity and mitigationNigella sativa pharmacological applications

Current-density functional theory of the response of solids

Neepa T. Maitra、Ivo Souza、Kieron Burke2003-07-25Physical review. B, Condensed matter

The response of an extended periodic system to a homogeneous field (of wave-vector $q=0)$ cannot be obtained from a $q=0$ time-dependent density functional theory (TDDFT) calculation, because the Runge-Gross theorem does not apply. Time-dependent current--density functional theory is needed and demonstrates that one k…

Spectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallographyChemical and Physical Properties of Materials

Evidence for nano-scale inhomogeneities in bilayer manganites in the Mn\sp{4+} rich region: $\bm{0.54 \leq x \leq 0.80}$

Xiangyun Qiu、Simon J. L. Billinge、Carmen R. Kmety 等 4 位作者2003-07-25arXiv

The atomic pair distribution function (PDF) technique is employed to probe the atomic local structural responses in naturally double layered manganites \lsmo in the doping range $0.54 \leq x \leq 0.80$. Our low temperature neutron powder diffraction measurements suggest the coexistence of two different Jahn-Teller (JT…

Materials ScienceStrongly Correlated Electrons

Induced Ge Spin Polarization at the Fe/Ge Interface

J. W. Freeland、R. H. Kodama、M. Vedpathak 等 8 位作者2003-07-25arXiv

We report direct experimental evidence showing induced magnetic moments on Ge at the interface in an Fe/Ge system. Details of the x-ray magnetic circular dichroism and resonant magnetic scattering at the Ge L edge demonstrate the presence of spin-polarized {\it s} states at the Fermi level, as well as {\it d} characte…

Materials Science

Ferroelectric and antiferroelectric coupling in superlattices of paraelectric perovskites at room temperature

Hans M. Christen、E. D. Specht、Sherwood S. Silliman 等 4 位作者2003-07-25Physical review. B, Condensed matter

Results from dielectric and structural measurements on epitaxial ${\mathrm{SrTiO}}_{3}/{\mathrm{BaZrO}}_{3}$ superlattices reveal properties that cannot be explained simply in terms of those measured on single films of the constituent materials. For large superlattice periodicities (20/20 and 38/38 structures---i.e.,…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Curie temperature limit in ferromagneticGa1−xMnxAs

K. M. Yu、W. Walukiewicz、T. Wójtowicz 等 8 位作者2003-07-25Physical review. B, Condensed matter

We provide experimental evidence that the upper limit of \ensuremath{\sim}110 K commonly observed for the Curie temperature ${T}_{C}$ of ${\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{As}$ thin films (thickness &gt;50 nm) is caused by Fermi-level-induced hole saturation. Ion channeling, electrical, and magn…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Shear yielding of amorphous glassy solids: Effect of temperature and strain rate

Jörg Rottler、Mark O. Robbins2003-07-25Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We study shear yielding and steady state flow of glassy materials with molecular dynamics simulations of two standard models: amorphous polymers and bidisperse Lennard-Jones glasses. For a fixed strain rate, the maximum shear yield stress and the steady state flow stress in simple shear both drop linearly with increas…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesGlass properties and applications

Dynamics of a magnetic moment induced by a spin-polarized current

Wonkee Kim、F. Marsiglio2003-07-25arXiv

Effects of an incoming spin-polarized current on a magnetic moment are explored. We found that the spin torque occurs only when the incoming spin changes as a function of time inside of the magnetic film. This implies that some modifications are necessary in a phenomenological model where the coefficient of the spin t…

Materials Science

Determining carrier densities in InMnAs by cyclotron resonance

G. D. Sanders、Y. Sun、C. J. Stanton 等 11 位作者2003-07-25arXiv

Accurate determination of carrier densities in ferromagnetic semiconductors by Hall measurements is hindered by the anomalous Hall effect, and thus alternative methods are being sought. Here, we propose that cyclotron resonance (CR) is an excellent method for carrier density determination for InMnAs-based magnetic str…

Mesoscale and Nanoscale PhysicsMaterials Science

Semiclassical Mode-Coupling Factorizations of Coherent Nonlinear Optical Response

Thomas la Cour Jansen、Shaul Mukamel2003-07-25arXiv

The identification of relevant collective coordinates is crucial for the interpretation of coherent nonlinear spectroscopies of complex molecules and liquids. Using an $\hbar$ expansion of Liouville space generating functions, we show how to factorize multitime nonlinear response functions into products of lower-order…

Materials Science