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Characteristics of the absorption and the emission of hydrogen in palladium nanoparticles encapsulated into graphite at 1.0 MPa hydrogen pressure

Nobumitsu Hirai、Masayuki Takashima、Toshihiro Tanaka 等 4 位作者2004-01-01Science and Technology of Advanced Materials

Palladium nanoparticles encapsulated into graphite (Pd–graphite intercalation compound: Pd–GIC) were produced from two kinds of graphite, natural graphite (average flake size: 270 μm) and kish graphite (average flake size: 15 mm). Hydrogen storage properties of Pd–GIC have been investigated by means of differential sc…

Advancements in Battery MaterialsRare-earth and actinide compoundsHydrogen Storage and Materials

Nucleation of Slip Bands near Twin Boundary in High-Cycle Fatigue

Takashi Sumigawa、Takayuki Kitamura2004-01-01JSME International Journal Series A

In order to investigate the criterion for the persistent slip band (PSB) formation near a Σ3(111) coherent twin boundary, where is a preferential site for formation of PSB, a high-cycle fatigue test is carried out at room temperature using a copper bicrystal specimen with the twin boundary. PSBs are observed near the…

Microstructure and mechanical propertiesFatigue and fracture mechanicsHigh-Velocity Impact and Material Behavior

ESR Study on Annihilation Process of Radiation Defects Induced in Solid Tritium Breeding Materials by Neutron Irradiation

M. Oyaidzu、Y. Morimoto、M. Sasaki 等 9 位作者2004-01-01Physica Scripta

Annihilation processes of radiation defects induced in solid-tritium breeding materials by neutron irradiation were studied by ESR measurement. The ESR spectrum for neutron-irradiated Li 2 TiO 3 is asymmetric, hence it is consists of several signals. This means that there are some para-magnetic radiation defects. The…

Fusion materials and technologiesNuclear Materials and PropertiesMuon and positron interactions and applications

Pore development during exfoliation of natural graphite

Michio Inagaki、Norimasa Saji、Yongping Zheng 等 5 位作者2004-01-01TANSO

Pore development during exfoliation of natural graphite was studied using residue compounds with sulfuric acid. Pore structure of exfoliated graphite was characterized with an aid of image analysis technique, as functions of exfoliation conditions, temperature, residence time and intercalate content. Pore development…

Graphene research and applicationsFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

Comparisons of deformation and fracture behaviour of PC/ABS blend and ABS copolymer under dynamic shear loading

W.-S. Lee、H.-C. Shen2004-01-01Materials Science and Technology

The dynamic shear deformation and fracture characteristics of PC/ABS blend and ABS copolymer with regard to the relation between mechanical properties and strain rate, are studied experimentally using a torsional split Hopkinson bar at room temperature under strain rates ranging from 8 × 102 s-1 to 3.4 × 103 s-1. Frac…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsHigh-Velocity Impact and Material Behavior

Easy synthesis of phenyl oligomers using a Ni complex

Laura O. Péres、Françoise Guillet、G. Froyer2004-01-01Organic & Biomolecular Chemistry

In this work are described the syntheses of p-sexiphenyl and p-octiphenyl starting from 4-bromo-p-terphenyl and 4-bromo-p-quaterphenyl, respectively, by using a nickel complex in the presence of bipyridine with DMF as solvent. This type of synthesis was shown to give an improved yield as well as easy preparation and p…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Nonlinear Dielectric Spectroscopy of Antiferroelectric Liquid Crystals in Various Smectic Phases

Yasuyuki Kimura、Hiroshi Isono2004-01-01Ferroelectrics

Nonlinear dielectric spectroscopy in frequency domain has been applied to antiferroelectric liquid crystals in various smectic phases including antiferroelectric SmC A *, SmC FI2 * and incommensurate SmCα* phases. We have observed different characteristic third-order nonlinear dielectric spectra ϵη3* in respective pha…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

New Second-Order Nonlinear Octupolar Materials

Anna Samoć、Marek Samoć、Barry Luther‐Davies 等 6 位作者2004-01-01Molecular Crystals and Liquid Crystals

We investigated second-order nonlinear optical properties of non-centrosymmetric crystals built of oblate, trigonal molecules: triphenylamine and adducts(complexes)of arsenic triiodide with sulfur, AsI3 · 3S8, and antimony triiodide with sulfur, SbI3 · 3S8. The efficiency of powder second-harmonic generation(SHG)in tr…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchPhotorefractive and Nonlinear Optics

Melt-Infiltrated SiC Composites for Gas Turbine Engine Applications

Gregory N. Morscher、Vijay V. Pujar2004-01-01OpenAlex

SiC-SiC ceramic matrix composites (CMCs) manufactured by the melt-infiltration (MI) process are leading candidates for many hot-section turbine engine components. A collaborative program between Goodrich Corporation and NASA-Glenn Research Center is aimed at determining and optimizing woven SiC/SiC CMC performance and…

Advanced ceramic materials synthesisHigh-Temperature Coating BehaviorsMaterial Properties and Applications

The Photochemical Isomerization of Pyrazoles: An AB Initio Study

Maurizio D’Auria、Rocco Racioppi2004-01-01Letters in Organic Chemistry

The photochemical isomerization of pyrazoles was studied using ab initio methods. The singlet excited singlet state can evolve to give the Dewar isomer and the corresponding triplet state. The latter shows a lower energy and probably can be obtained with higher efficiency. The triplet state can evolve to give the corr…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistryChemistry and Chemical Engineering

Novel Process for Manufacturing Electret from Polypropylene Nonwoven Fabrics

Jia‐Horng Lin、Ching‐Wen Lou、Zhengyu Yang2004-01-01Journal of the Textile Institute

In this work, a novel procedure for manufacturing an electret was designed, and the relationship between the surface voltage and other variables elucidated. The charge decay of the nonwoven electret over six weeks was also investigated. The new process quickly charges the dielectric to a voltage of between 10 and 30 k…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaAerosol Filtration and Electrostatic Precipitation

Crystal Growth Behavior of Zeolites Elucidated by Atomic Force Microscopy

Toru Wakihara、Tatsuya Okubo2004-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Seeded growths of faujasite and zeolite A were investigated by atomic force microscopy (AFM). For seeded growth, clear aluminosilicate solutions (90Na2O:xAl2O3:9SiO2:5760H2O, where x = 0.1–1.0), which are useful for faujasite or zeolite A growth on seeded faujasite or zeolite A, respectively, were prepared at 353 K. C…

Zeolite Catalysis and SynthesisGlass properties and applicationsClay minerals and soil interactions

Effect of pressure on optical properties of crystalline As2S3

R. Zallen2004-01-01High Pressure Research

Crystalline As2S3 (orpiment) is a layered-structure semiconductor whose optical properties, under ambient conditions, are determined by its diperiodic layer symmetry. We have investigated the effec...

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Molecular design of new π-conjugated poly(ketanil)s with tunable spectroscopic properties

Agnieszka Iwan、Danuta Sęk、Janusz Kasperczyk 等 7 位作者2004-01-01New Journal of Chemistry

New conjugated aryl-substituted poly(azomethine)s, termed poly(ketanil)s, have been synthesised from 1,4-phenylenediamine (or 3,3′,5,5′-tetramethylbenzidine) and two different diketones via polycondensation with the goal to obtain new materials with tunable spectroscopic properties. It is demonstrated that both the ab…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

X-ray Photoelectron Spectroscopy Study of Copper Tellurite Glasses

G.D. Khattak、A. Mekki、A.M. Al-Shukri2004-01-01Physica Scripta

Tellurite glasses containing CuO with the nominal composition (CuO) x (TeO 2 ) 1− x , where x = 0.1, 0.2, 0.3, 0.4 and 0.5, have been prepared and investigated by x-ray photoelectron spectroscopy (XPS). The core level binding energies of Cu 2p, Te 3d, and O 1s in these glasses have been measured. The appearance of a s…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMineralogy and Gemology Studies

Superprotonic solid acids: structure, properties, and applications

Dane A. Boysen2004-01-01OpenAlex

I am part of all that I have met; Yet all experience is an arch wherethro’ Gleams the untravell’d world, whose margin fades For ever and for ever when I move. How dull it is to pause, to make an end, To rust unburnish’d, not to shine in use! As tho ’ to breath were life. Life piled on life Were all too little and of o…

Thermodynamic properties of mixturesAdvanced Chemical Sensor TechnologiesSolid-state spectroscopy and crystallography

Electrochromic Variable Emittance Devices on Silicon Wafer for Spacecraft Thermal Control

Nikolai Kislov2004-01-01AIP conference proceedings

Small light‐weight satellites and space vehicles under development for future NASA missions have reduced thermal mass and are strongly affected by changes in orbital conditions, resulting in large temperature variations. Restrictions on payload weight and volume limit the usefulness of many thermal control technologie…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsAnalytical Chemistry and Sensors

Pitting Inhibition by Surfactants

Zhenqiang Wei、P. Somasundaran、Paul Duby2004-01-01Journal of The Electrochemical Society

Surfactants have been tried as inhibitors of pitting corrosion of various materials such as stainless steels and aluminum alloys. In order to understand the structure-performance relationship in pitting inhibition, surfactants of different charged headgroups, i.e. , anionic sodium dodecylsulfate (SDS), cationic dodecy…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Polymer Electrolyte Based on Ionic Liquid (EMIm)3PO4 as an Electrolyte for Electrochemical Capacitors

Andrzej Lewandowski、Aleksandra Świderska2004-01-01Polish Journal of Chemistry

A series of polymer electrolytes, based on ionic liquid (EMIm) 3 PO 4 , and the polymers PAN, PVdF, PVdF-HFP, PVA and PEO were prepared as thin-foils, using the casting technique. The composite electrolytes showed conductivity at a level of ca. 10 mS/cm, apart from the system PEO-(EMIm) 3 PO 4 . The electrochemical st…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

The Electron Backscatter Diffraction Technique - A Powerful Tool to Study Microstructures by SEM

Stefan Zaefferer2004-01-01Max Planck Institute for Plasma Physics

In the last 10 years the electron backscatter diffraction (EBSD) technique has developed into a powerful tool for the crystallographic analysis of materials in the scanning electron microscope. In particular the emergence of computer algorithms for the fully automated analysis of diffraction patterns has pushed the te…

Microstructure and mechanical propertiesAdvanced Surface Polishing TechniquesElectron and X-Ray Spectroscopy Techniques