Materials Literature
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A new design of luminescent materials by decorating a tetraphenylethene core with four aromatic chromophores is proposed. The generated luminogens exhibit aggregation-enhanced emission and excellent solid-state fluorescence efficiency (93-99%). Efficient non-doped OLEDs based on them afford remarkable efficiencies up…
ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTFundamental Studies of Well-Defined Surfaces of Mixed-Metal Oxides: Special Properties of MOx/TiO2(110) {M = V, Ru, Ce, or W}Darío J. Stacchiola, Sanjaya D. Senanayake, Ping Liu, and José A. Rodriguez*View Author Information Chemistry Department, Brookhaven National Laborator…
We describe a synthesis of Au wavy nanowires in an aqueous solution in the presence of cetyltrimethylammonium bromide (CTAB). The resultant Au nanowires automatically separated from the solution and floated at the air/water interface. We investigated the formation mechanism by characterizing the samples obtained at di…
Phenylethynyl terminated novel imide compound based on 1,3-bis(3-aminophenoxy)benzene (APB) and phenylethynyl trimellitic anhydride (PETA) were prepared. The curing behavior of phenylethynyl terminated imide compound was investigated by differential scanning calorimetry and Fourier transform infrared spectrometry. The…
Cyclic butylene terephthalate oligomers (CBT) were reacted in a ring-opening polymerization with three types of isocyanates: a bifunctional aromatic type, a bifunctional aliphatic type and a polymeric aromatic isocyanate. All reactions took place in a batch mixer. The use of 0.5 to 1 wt% isocyanate led to a dramatic i…
In this work, all-polypropylene composites (all-PP composites) were manufactured by injection moulding. Prior to injection moulding, pre-impregnated pellets were prepared by a three-step process (filament winding, compression moulding and pelletizing). A highly oriented polypropylene multifilament was used as the rein…
We have established a well-defined dome shape Tc curve in Ir0.94-xRhxSe2 superconductors. The maximum Tconset of 9.6K was obtained at x=0.36, at which the Se-Se separation in the dimer anion is the longest. Simultaneously, the destabilization of Se-Se dimers accompanied by partial elec-tron-transfer from the Ir/Rh to…
This paper focuses on the reinforcing of Poly(lactic acid) with chopped basalt fibres by using silane treated and untreated basalt fibres. Composite materials with 5-10-15-20-30-40 wt% basalt fibre contents were prepared from silane sized basalt fibres using extrusion, and injection moulding, while composites with 5-1…
This work aimed to study the effect of different ultraviolet (UV) weathering conditions (natural and accelerated) on the photodegradation of polyvinyl chloride (PVC) and wood/polyvinyl chloride (WPVC) composites by considering the structural and physical changes of PVC and WPVC samples as well as examining the photode…
Hot and cold non-isothermal crystallization of copolymers having glycolide hard segments and glycolide-cotrimethylene carbonate soft segments was investigated by calorimetry, optical microscopy and synchrotron radiation experiments. The effect of composition and microstructural changes on thermal properties and morpho…
Despite similarities in formulae and local structures of Zr2CoH5 and Mg2CoH5, they are shown from ab initio calculations to present contrasted electronic, magnetic, mechanical and bonding properties due to the environment of cobalt with hydrogen characterized by negatively charged CoHx entities (x = 4, 5 resp.) and to…
We investigate spin precession (Hanle effect) in the prototypical organic spintronic giant magnetoresistance (GMR) device La0.7Sr0.3MnO3(LSMO)/tris(8-hydroxyquinoline)(Alq3)/AlOx/Co. The Hanle effect is not observed in measurements taken by sweeping a magnetic field at different angles from the plane of the device. As…
We measured phonon dispersion in single-crystal EuTiO${}_{3}$ using inelastic x-ray scattering. A structural transition to an antiferrodistortive phase was found at a critical temperature ${T}_{0}=287\ifmmode\pm\else\textpm\fi{}1$ K using powder and single-crystal x-ray diffraction. Clear softening of the zone boundar…
By means of multiscale molecular simulations, we show that telechelic-star polymers are a simple, robust, and tunable system, which hierarchically self-assembles into soft-patchy particles and mechanically stabilizes selected, open crystalline structures. The self-aggregating patchy behavior can be fully controlled by…
Crystallographic and spin polarized transport properties of (100) textured and (100) epitaxial Fe/MgO/Fe magnetic tunnel junctions are compared. Strong similarities in the transport properties show that structural coherence and magnetic quality at the 25 nm grain scale in textured junctions are sufficient to issue sig…
We report element-specific X-ray spectroscopy results on the structure and bonding of Au 24 Pt, a thiolate-protected bimetallic nanocluster. Platinum L 3 -edge extended X-ray absorption fine-structure (EXAFS) data, in association with X-ray photoelectron spectroscopy (XPS) compositional analysis, was used to identify…
To develop high performances of inorganic fibers/polymer composites, the interfacial interaction and dispersal of fibers are the two essential issues to be considered. Herein, we report the surface decoration of basalt fibers (BF) with hybrid Fe3O4 microspheres (FePc–Fe3O4) and their microwave absorption application i…
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The newly popular topic of "phonon diodes" is discussed in the context of a broader issue of reciprocity in reflection/transmission (R-T) of waves. We first review a theorem well known in electromagnetism and optics but underappreciated in acoustics and phonon physics, stating that the matrix of R-T coefficients for p…
It is shown theoretically that a single a few picoseconds long acoustic pulse can reverse magnetization in a magneto-strictive material Terfenol-D. Following giant magneto-elastic changes of free energy density the magnetization vector is kicked out of a local in-plane energy mininum and decays into another minimum. F…