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Highly-metallized phosphonium polyelectrolytes

Amir Rabiee Kenaree、Bradley M. Berven、Paul J. Ragogna 等 4 位作者2014-01-01Chemical Communications

The synthesis and characterization of a novel class of highly-metallized, redox-active polyelectrolytes that employ phosphorus as a scaffold for the installation of transition metals is described. Pyrolysis of thin films of the title polyelectrolytes resulted in the production of magnetite crystallites and ill-defined…

Polymer Surface Interaction StudiesFlame retardant materials and propertiesDendrimers and Hyperbranched Polymers

A comparative study on the elastic modulus of polyvinyl alcohol sponge using different stress-strain definitions

Alireza Karimi、Mahdi Navidbakhsh、Mansour Alizadeh 等 4 位作者2014-01-01Biomedizinische Technik/Biomedical Engineering

There have been different stress-strain definitions to measure the elastic modulus of spongy materials, especially polyvinyl alcohol (PVA) sponge. However, there is no agreement as to which stress-strain definition should be implemented. This study was aimed to show how different results are given by the various defin…

Mechanical Behavior of CompositesAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Synthesis and Physicochemical Characterization of Biodegradable Star-Shaped Poly Lactide-Co-Glycolide-<i>β</i>-Cyclodextrin Copolymer Nanoparticles Containing Albumin

Soodabeh Davaran、Akbar Rezaei、Somayeh Alimohammadi 等 7 位作者2014-01-01Advances in Nanoparticles

The purposes of this research were to synthesize and characterize star-shaped poly lactide-co-glycolide-β-cyclo-dextrin (PLGA-β-CD) copolymer by reacting L-lactide, glycolide and β-cyclodextrin in the presence of stannous octoate as a catalyst. The structure of PLGA-β-CD copolymer was confirmed with 1H-NMR, 13C-NMR an…

Nanoparticle-Based Drug DeliveryProteins in Food SystemsAdvanced Drug Delivery Systems

Spectrum Activity and Lauric Acid Release Behaviour of Antimicrobial Starch-based Film

Eraricar Salleh、Ida Idayu Muhammad、Qadly Ameen Pahlawi2014-01-01Procedia Chemistry

This study aimed at the development of antimicrobial (AM) packaging based on wheat starch incorporated with chitosan and lauric acid as antimicrobial agents. A series of blends with different ratio of starch, chitosan and lauric acid (S:C:LA) were prepared by casting method. Effects of incorporation of antimicrobial a…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsAntimicrobial agents and applications

Tuning the underwater oleophobicity of graphene oxide coatings via UV irradiation

Hang Li、Yi Huang、Yating Mao 等 6 位作者2014-01-01Chemical Communications

Ultraviolet (UV) irradiation was utilized to gradually modify the chemistry and structure of graphene oxide (GO) flakes, as confirmed by XPS and AFM. Ultrathin GO coatings/membranes, made of UV-irradiated flakes, showed tunable underwater oleophobicity. UV-treated, superoleophobic GO membranes exhibited excellent anti…

Graphene research and applicationsSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Droplet topology control of Janus emulsion prepared in one-step high energy mixing

Lingling Ge、Wanqing Shao、Shuhui Lu 等 4 位作者2014-01-01Soft Matter

Droplet topology of a Janus emulsion in a vegetable oil (VO)/silicone oil (SO)/Tween 80 aqueous solution (Aq) system prepared in a one-step high energy mixing was investigated, mainly by image observation. Quantitative information of the topology was analyzed referring to the curvature of VO/SO interface, the location…

Surfactants and Colloidal SystemsInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes

Sebastiano Di Pietro、Daniel Imbert、Marinella Mazzanti2014-01-01Chemical Communications

Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the lumin…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Novel design approaches for multifunctional information carriers

Melanie Ecker、Thorsten Pretsch2014-01-01RSC Advances

Information carriers with an unprecedented combination of thermochromic and shape memory properties are presented. The studied material systems may be used in anti-counterfeiting applications.

Polymer composites and self-healingPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Carbon nanotube and graphene oxide directed electrochemical synthesis of silver dendrites

Li Fu、Guosong Lai、Peter J. Mahon 等 8 位作者2014-01-01RSC Advances

A simple one-step electro-deposition method was employed for the synthesis of silver dendritic structures with the aid of graphene oxide (GO) modified multi-walled carbon nanotubes (MWCNTs) which are dispersed in an AgNO <sub>3</sub> solution.

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Unexpected luminescence enhancement of upconverting nanocrystals by cation exchange with well retained small particle size

Mingliang、Deng、LeyuWang2014-01-01纳米研究:英文版

nanorods (NR ) 。在阳离子交换以后, nanorod 与更强壮的排放被分解为二 NP。阳离子交换了恐水病的 UCNP 进一步被包含与 poly (氨基酸) 并且成功地申请了指向的癌症房间 UC 光成像。

Luminescence Properties of Advanced MaterialsQuantum Dots Synthesis And PropertiesLuminescence and Fluorescent Materials

Energy band alignment at ferroelectric/electrode interface determined by photoelectron spectroscopy

Feng Chen、Wenbin Wu、Shunyi Li 等 4 位作者2014-01-01Chinese Physics B

The most important interface-related quantities determined by band alignment are the barrier heights for charge transport, given by the Fermi level position at the interface. Taking Pb(Zr,Ti)O 3 (PZT) as a typical ferroelectric material and applying X-ray photoelectron spectroscopy (XPS), we briefly review the interfa…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

In situ formation of lithium fast-ion conductors and improved hydrogen desorption properties of the LiNH2–MgH2 system with the addition of lithium halides

Bo Li、Yongfeng Liu、Chao Li 等 5 位作者2014-01-01Journal of Materials Chemistry A

Lithium halides were introduced into the LiNH2–MgH2 system by ball milling the corresponding chemicals under 50 bar of H2 to decrease the dehydrogenation temperature and enhance the dehydrogenation kinetics. The results show that the LiNH2–MgH2–0.05LiBr sample exhibited optimal hydrogen storage performance. The onset…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Benzocyclobutene-functionalized poly(m-phenylene): A novel polymer with low dielectric constant and high thermostability

童佳伟、刁屾、金凯凯 等 7 位作者2014-01-01OpenAlex

A novel benzocyclobutene-fimctionalized poly(m-phenylene) was synthesized. This polymer showed good solubility and film-forming ability. When being heated at high temperature, the polymer film converted to an insoluble cross-linked network structure and did not show any cracks. Thermogravimetric analysis of the polyme…

Organic Electronics and PhotovoltaicsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Photothermal release of CO 2 from capture solutions using nanoparticles

Du T. Nguyen、Richard Truong、Richard Lee 等 5 位作者2014-01-01Energy & Environmental Science

We report the use of actinic light for the photo-thermal enhanced regeneration of CO <sub>2</sub> from capture solutions containing nanoparticles. Regeneration efficiency increased with higher nanoparticle concentrations and initial solution temperatures.

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCarbon Dioxide Capture Technologies

Electronic and transport properties of porous graphenes: two-dimensional benzo- and aza-fused π-conjugated-microporous-polymer sheets and boron–nitrogen co-doped derivatives

Zhao-Di Yang、Wenzhi Wu、Xiao Cheng Zeng2014-01-01Journal of Materials Chemistry C

2D benzo-CMP and aza-CMP sheets and their BN co-doped derivatives possess distinct structural, electronic and transport properties that are notably different from those of graphene.

Graphene research and applicationsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Lanthanide CPs: the guest-tunable drastic changes of luminescent quantum yields, and two photon luminescence

Cheng-Hui Zeng、Jing-Ling Wang、Yang-Yi Yang 等 7 位作者2014-01-01Journal of Materials Chemistry C

Drastic change of luminescent QY was found in a serial of guest-tuned lanthanide CPs. An octupolar-like structure lanthanide CP shows a high two-photon luminescence.

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes