Materials Literature
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Abstract Acrylonitrile-butadiene-styrene terpolymer (ABS) is one of the engineering plastics most frequently used as outer casings for computer equipment such as monitors, keyboards and other similar components. In an attempt to recycle, blends of scrap computer plastics (SCP) based on ABS with nitrile rubber (NBR) we…
This paper reports an analysis of the influence of polyester and yarn type on the abrasion resistance of 50/50 wool/polyester blended woven fabrics. Recently developed polyester fibers put into the blend and two-strand Sirospun yams are compared with 2.5 denier standard polyester and two-fold ring yarns. Mass losses o…
Abstract A large distribution coefficient and large sorption capacity were observed during selenate adsorption by cation (Fe3+, Cu2+, and H+)-anchored diamino-functionalized MCM-41. Moreover, these synthetic adsorption media showed excellent selectivity for selenate sorption in the presence of other anions. In a pure…
The mechanical, structural, and dyeing properties of solvent-spun lyocell fibers in a plain weave fabric are studied before and after industrial treatments of mechanical fibrillation and enzymatic defibrillation. Stress-strain relationships, surface morphology, crystallinity, and dye uptake are assessed for each of th…
Three Ru2(5+) diruthenium complexes, (4,0) Ru2(2-CH3ap)4Cl, (3,1) Ru2(2-Fap)4Cl, and (3,1) Ru2(2,4,6-F3ap)4Cl where ap is the 2-anilinopyridinate anion, were examined as to their electrochemical and spectroelectrochemical properties in five different nonaqueous solvents (CH2Cl2, THF, PhCN, DMF, and DMSO). Each compoun…
We have used deposited polymeric nanofibers as nonlithographic templates for the fabrication of semiconductor nanostructures. We deposited oriented poly(methyl methacrylate) (PMMA) fibers, with diameters ranging from 85 to 350 nm, on the surface of various substrates using a microfabricated electrospinning source. By…
Abstract The reinforcing effect of up to 6 parts per hundred rubber by weight (phr) bis- (3-triethoxysilylpropyl) tetrasulfide (TESPT), a bifunctional organosilane, on the crosslink density, bound rubber, and technical properties of some conventional accelerator/sulfur compounds of natural rubber, containing 30 phr pr…
Alacranite from the type locality (Uzon caldera, Kamchatka, Russian Federation) was submitted for structural analysis. A single crystal was selected and the following lattice parameters were determined: a = 9.942(4), b = 9.601(2), c = 9.178(3) Å, β = 101.94(3)°, V = 857.1 (5) Å 3 . The crystal structure was solved in…
The sliding interface of a flyer/target system is subject to immense forces caused by dynamic loads and impact of the flyer with the target. In addition, tremendous heating caused by aerodynamic and frictional effects is produced at the interface. The buildup of the temperature caused by external heat sources is impor…
Gray-scale electron beam lithography has been used to create high-efficiency (63%, output normalized) blazed gratings suitable for use at extreme ultraviolet (EUV) wavelengths (i.e., 13.4 nm). The total blaze height at these wavelengths is ≈7 nm. The surface topography was generated in a single processing step in hydr…
The interactions of two pyridoxal-5-phosphate (PLP)-dependent enzymes, alanine aminotransferase (ALT) and glutamate decarboxylase (GAD), with pyridoxal kinase (PK) were studied by fluorescence polarization as well as surface plasmon resonance techniques. The results demonstrated that PK can specifically bind to ALT an…
Abstract By using electromagnetic levitation, liquid Cu–Co alloys can be undercooled below their liquidus temperature into the metastable miscibility gap, leading to a phase separation into a cobalt‐rich L 1 phase and a cobalt‐poor L 2 phase. This paper reports on experimental and theoretical investigations into the p…
A hierarchy of CO2-based solvents is used to remove post-etch residues from vias and trenches in low-k patterned porous methylsilsesquioxane (pMSQ) interlayer dielectrics. Spectroscopic ellipsometry measurements indicate that, upon pressurization and depressurization with CO2, the thickness and refractive index return…
For photon-based maskless lithography we show that a system based on the incoherent addition of scanned, multiplexed, and on-axis focal spots from an array of diffractive-optical elements, such as binary-phase zone plates, has significant advantages over systems based on partially coherent projection of the image of a…
Threonine synthase, which is a PLP-dependent enzyme, catalyzes the beta,gamma-replacement reaction of l-homoserine phosphate to yield threonine and inorganic phosphate. The three-dimensional structures of the enzyme from Thermus thermophilus HB8 in its unliganded form and complexed with the substrate analogue 2-amino-…
In this article it is shown that moment models for batch crystallization processes are orbitally flat. The state dependent time scaling involved in orbital flatness is physically meaningful and leads to a notion of time that is very natural for the crystallization process. A procedure is presented to check if a desire…
TaN deposited by magnetron sputtering has application in semiconductor interconnect structures as a diffusion barrier and adhesion layer. TaN used in these applications has a hexagonal or cubic structure consistent with roughly 1:1 Ta:N levels, with a bulk resistivity of 300–500 μΩ cm and a diffusion barrier failure t…
The in situ time-resolved analysis of Co-exchanged synthetic ferrierite was performed in the range 53−810 °C by Rietveld refinements of powder diffraction data. The small contraction of the unit cell volume (−2.35%) confirmed that the ferrierite framework behaves as a noncollapsible framework. Moreover, continuous mon…
A series of new side chain cholesteric liquid crystalline elastomers (P-2–P-6) containing the nematic crosslinking monomer 4-(10-undecen-1-yloyloxy)benzoyl-4′-allyloxybenzoyl-p-benzenediol bisate (M-1) and the cholesteric monomer 4-cholesteryl 4-(10-undecen-1-yloyloxy)benzoate (M-2) were synthesized. The chemical stru…
New regenerated cellulose fibers are prepared from solution (chemical cellulose con tents, 3, 4.5, 6, and 9 wt%) using N-methylmorpholine-N-oxide (NMMO)/water (87/13 wt%) as a solvent by dry-wet spinning at a winding speed of 20-100 m/min. The chemical cellulose (97% α-cellulose content, 918 DPw, 98% JIS whiteness) us…