Materials Literature
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The presence of a PbO‐rich liquid phase was previously shown to affect the densification of lead zirconate‐lead titanate (PZT) ceramics. The present work attempts to quantify the role of this liquid phase. Increasing amounts of PbO‐rich liquid phase is shown to increase the rates of densification in the initial and in…
The kinetics of devitrification in ZrF 4 ‐BaF 2 ‐LaF 3 (62–33–5 mol % ) glass were studied by isothermal and nonisothermal methods using differential scanning calorimetry. The crystallization reaction followed the Avrami equation, x =1‐exp[—( kt) ], where x is the fraction crystallized after time t . The rate con stan…
We have used photoemission techniques with synchrotron radiation to study the adsorption of oxygen on the Si(111)-(7×7) and Si(100)-(2×1) surfaces at room temperature in the submonolayer and monolayer regimes. High resolution Si 2p core-level spectra, valence-band spectra, work-function, and Fermi-level pinning positi…
Abstract With a view of developing latent heat storage materials, mixtures of pseudo-binary system, CH3CO2Na·3H2O–CO(NH2)2 (sodium acetate trihydrate–urea) were subjected to differentital scanning calorimetry, and the partial phase diagram for ternary system CH3CO2Na–CO(NH2)2–H2O at ambient pressure was constructed. T…
The 84% Zr–16% Al nonevaporable getter alloy has been used for a long time in vacuum technology and, more recently, has been adopted in advanced applications such as fusion technology and particle accelerators. A new getter material consisting of a Zr–V–Fe ternary alloy having interesting characteristics for these app…
The oxidation of zinc in air at 294 K has been studied for exposure times from 1 min to 150 h. The fraction of zinc in the Zn+2 valence state has been determined by high resolution Auger electron spectroscopy. Surface oxide thickness was measured by using AES with argon ion sputter etching. The adsorbed oxygen was sho…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInvestigation by small-angle neutron scattering of the chain conformation in equilibrium-swollen poly(dimethylsiloxane) networksMichel Beltzung, Jean Herz, and Claude PicotCite this: Macromolecules 1983, 16, 4, 580–584Publication Date (Print):April 1, 1983Publication History…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDifferential scanning calorimetry characterization of polypropylene. Dependence of Tg on polymer tacticity and molecular weightDavid R. Burfield and Yoshiharu DoiCite this: Macromolecules 1983, 16, 4, 702–704Publication Date (Print):April 1, 1983Publication History Published…
Oxygen does not quench the luminescence of either free Tb or of Tb bound to dipicolinate. However, sensitized Tb luminescence in complexes of that ion with elastase, thermolysin, and alpha-amylase is quenched by oxygen at rates that far exceed that with which the intrinsic fluorescence of the proteins is quenched. We…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMicrowave structure measurements on the furan-argon complexStephen G. KukolichCite this: J. Am. Chem. Soc. 1983, 105, 8, 2207–2210Publication Date (Print):April 1, 1983Publication History Published online1 May 2002Published inissue 1 April 1983https://pubs.acs.org/doi/10.102…
The lattice-dynamical properties of tetragonal (black) SnO (with space-group symmetry $\frac{P4}{\mathrm{nmm}}$) have been examined over the temperature range $78\ensuremath{\le}T\ensuremath{\le}300$ K by variable-temperature $^{119}\mathrm{Sn}$ M\"ossbauer-effect measurements. The lattice temperature calculated from…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical characterization of p-type semiconducting tungsten disulfide photocathodes: efficient photoreduction processes at semiconductor/liquid electrolyte interfacesJoseph A. Baglio, Gary S. Calabrese, D. Jed Harrison, Emil Kamieniecki, Antonio J. Ricco, Mark S. Wrig…
The Fourier and variance methods are used to analyse the breadths of X-ray diffraction peaks from ZnO powder obtained from the thermal decomposition of Zn 3 (OH) 4 (NO 3 ) 2 . The shape, size, distribution of size and orientation of the crystallites are determined. It is found that the form is markedly anisotropic and…
The two $4f$-derived photoemission features recently observed for Ce pnictides are identified with hybridized $4f$-hole and ligand-hole final states. Simple expressions obtained for a $\mathrm{Ce}{X}_{6}$ cluster explain the change in the relative intensity of the two $4f$ features without energy shifts. Analogous exp…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-resolution carbon-13 CP/MAS NMR spectra of solid cellulose oligomers and the structure of cellulose IIR. L. Dudley, C. A. Fyfe, P. J. Stephenson, Y. Deslandes, G. K. Hamer, and R. H. MarchessaultCite this: J. Am. Chem. Soc. 1983, 105, 8, 2469–2472Publication Date (Print…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidative electropolymerization of polypyridyl complexes of rutheniumCharles D. Ellis, Lawrence D. Margerum, Royce W. Murray, and Thomas J. MeyerCite this: Inorg. Chem. 1983, 22, 9, 1283–1291Publication Date (Print):April 1, 1983Publication History Published online1 May 2002…
Methods of PbO atmosphere control during the sintering of PZT ceramics are briefly reviewed. The problem of atmosphere control of PZT compositions containing a PbO excess (PbO/(Zr,Ti)O 2 >1) is discussed. Weight‐loss experiments were performed to compare with behavior predicted by reference to the PbO‐rich part of…
Rigorous coupled-wave theory of diffraction by dielectric gratings is extended to cover E-mode polarization and losses. Unlike in the H-mode-polarization case, it is shown that, in the E-mode case, direct coupling exists between all diffracted orders rather than just between adjacent orders.
The electrochemical behavior of a carbon steel in 3% NaCl solution has been investigated using a rotating disk electrode. Both steady‐state (diffusional current vs. the disk angular velocity plots) and transient (frequency analysis of the electrohydrodynamical impedance) measurements which specifically sample mass tra…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTActivation and transfer of nitrogen from a nitridomanganese(V) porphyrin complex. Aza analog of epoxidationJohn T. Groves and Tadashi TakahashiCite this: J. Am. Chem. Soc. 1983, 105, 7, 2073–2074Publication Date (Print):April 1, 1983Publication History Published online1 May…