Materials Literature
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A short review is given of recent experimental studies of helium in metals, emphasizing fundamental He behavior at low temperatures (room temperature and below), low He concentrations (∼1 at.% He) and in the absence of radiation induced defects. Some of the main points are: (a) interstitial He is generally locally mob…
Water-soluble, diamagnetic metalloporphyrins have been prepared which contain either zinc(II), palladium(II) or tin(IV) ions as the central metals and their photophysical properties have been measured in dilute aqueous solution. All the compounds undergo efficient intersystem crossing to form long-lived excited triple…
This book should be of interest to undergraduates and postgraduates in materials engineering.
The biodegradability of poly (ethylene carbonate) and poly (propylene carbonate), synthesized from carbon dioxide and alkylene epoxides, was investigated. The biodegradation of poly (ethylene carbonate) pellets in the peritoneal cavity in rats was observable 2 d after implantation and was nearly completed within 2 wee…
A detailed X-ray photoelectron, i.r., and Raman spectral study has been made of Ce2(MoO4)3 and five novel cerium molybdenum oxides (α- and β-Ce2Mo4O15, β- and γ-Ce2Mo3O13, and Ce8Mo12O49), which are of particular interest as they are closely related to the cerium molybdenum oxide species which are expected to play an…
Description This book is aimed at the practicing engineer who is involved with the design, fabrication of operation of zirconium core components. The Metals Properties Council, as part of its continuing role of collecting, analyzing, and updating materials properties data, has arranged for the preparation of this book…
Specimens of Ca2Nd8(SiO4)6O2 were doped with 1.2 wt% 244Cm and the effects of self-radiation damage from alpha decay were determined as a function of cumulative dose. The macroscopic volume of the specimens increased exponentially with dose to a limiting (saturation) value of ∼8.0%. The initially crystalline material…
Diagnose latine de la nouvelle famille des C. Cle de determination basees sur la microscopie optique ou electronique. Traitement systematique
The available models for grain-boundary diffusion are reviewed together with the relevant mathematical techniques for extracting the grain-boundary diffusivity from the various types of experimental data. The more useful experimental techniques are described, fo11owed by a presentation of results that shed light on th…
The radiation enhanced diffusion (coefficient D*) of U-233 and Pu-238 in UO2 and (U, Pu)O2 with 2.5 and 15% Pu was measured during fission in a nuclear reactor. Normal diffusion sandwiches with a thin tracer layer were used. A radio-frequency furnace allowed the temperatures to be varied between 130 and 1400°. Neutron…
This paper deals with a detailed experimental investigation on the collapse of a single spark-generated bubble near a solid wall and the mechanism of its induced impact pressure generation. By changing L//?max from 0.14 to 17.1, where L is the distance between the electrodes and the solid wall and /?max a maximum bubb…
Material Balances in Non-Reacting Processes. Species Balances in Reacting Systems. Element Balances. Material Balances in Process Flowsheets. Introduction to Energy Balances. Energy Balances for Nonreacting Systems. Energy Balances for Reacting Systems. Material and Energy Balances in Process Flowsheets. Appendixes.
The first synthesis of pentapyrrole macrocycle analogous to the porphyrins is described.
The inhibition of 3H-thymidine incorporation into DNA of L1210 cells in culture by liposomes was used as an index of liposome toxicity. Inhibition of 3H-thymidine incorporation appeared to be dose dependent for some lipid compositions tested. The commonly used neutral lipids, phosphatidylcholine and cholesterol did no…
The thermal decomposition of both βNiO(OH) and ‘nickel peroxide’ have been studied by combining X-ray photoelectron spectroscopic (X.p.s.) studies of the solid with mass-spectrometric analysis of the gas phase. Through monitoring the O(1s) and Ni(2p) spectra of the as-prepared solids during decomposition, with simulta…
For the reduced second moment measure of stationary point processes several estimators are presented. In order to show the most general conditions under which the estimators are applicable, some properties of non-stationary point processes are introduced making it possible to reduce the second moment measure as in the…
The reduction of dioxygen to water has been investigated on ternary ruthenium(IV) oxides having the pyrochlore structure; in particular, compounds of the general form Bi2–2xPb2xRu2O7-y have been studied. Oxygen reduction on these materials appears to proceed by a rate-determining outer-sphere electron transfer, follow…
Current experimental findings on the effects of helium on the evolution of radiation damage microstructure in metals at temperatures where vacancies are mobile are reviewed. It is shown that helium concentrations as low as a few parts per million promote the formation of cavities and dislocations, may increase or decr…
Heat capacity of polyglycolide, poly(ε-caprolactone), poly(ethylene terephthalate), poly(ethylene sebacate), polyglycine, poly(L-alanine), poly(L-valine),nylon 6, nylon 6.6 and nylon 6.12 is reviewed on the basis of measurements on 35 samples reported in the literature. All heat capacity data are compiled and a set of…
The characteristics of the surface of various stainless steels are reviewed. The property of these alloys that makes them stainless is the formation of Cr2O3 on the surface. It has been found that this protective layer can be modified relatively easily by heating, abrading, chemical treatment, or ion bombardment. Modi…