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Preparation and mechanical properties of chemically cross‐linked hydroxypropyl cellulose solid films retaining cholesteric liquid crystalline order

Shinichi Suto、Hiroshi Tashiro、Mikio Karasawa1992-07-25Journal of Applied Polymer Science

Abstract Hydroxypropyl cellulose films were cast from liquid crystalline solutions with a crosslinking agent. The solubility test and the optical measurements of the resultant films were performed. The tensile, dynamic mechanical, and creep properties of the films were determined. The data of solubility in water deter…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Viscometric behavior of ternary concentrated solutions of hydroxypropyl cellulose and ethyl cellulose in m‐cresol

Shinichi Suto、Masato Kosaka、Terusada Sugiura1992-07-25Journal of Applied Polymer Science

Abstract The shear viscosity of blend solutions of hydroxypropyl cellulose (HPC) and ethyl cellulose (EC) in m ‐cresol (both HPC/ m ‐cresol and EC/ m ‐cresol systems form lyotropic liquid crystals) was determined by cone‐plate‐type and capillary‐type viscometers. The textures for the same systems at rest and undergoin…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPolysaccharides Composition and Applications

Intrinsic viscosity and molecular weight measurement of nylon 66 polymers

S. R. Samanta1992-07-25Journal of Applied Polymer Science

Abstract Intrinsic viscosity of several nylon 66 polymers in the molecular weight range 25,000–105,000 was measured in hexafluoroisopropanol (HFIP). The experimentally measured viscosity was compared with the data obtained by least‐squares fit of the classical equations of Huggins and Kraemer. The utility of the singl…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Structure of microporous polypropylene sheets containing CaCO3 filler

Satoshi Nagõ、Shunichi Nakamura、Yukio Mizutani1992-07-25Journal of Applied Polymer Science

Abstract The microporous polypropylene sheets were prepared by biaxially stretching polypropylene sheets containing CaCO 3 filler (particle size, 0.08–3.0 μm), when the CaCO 3 filler content was 59% by weight and the stretching ratio was 2.8 × 1.8. The microstructure of the sheets were investigated in relation to the…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Biodegradable natural composites. I. Processing and properties

Paul Gatenholm、J. Kubát、A. Mathiasson1992-07-25Journal of Applied Polymer Science

Abstract This paper presents an investigation of the properties of composites of bacteria‐produced polyesters reinforced with wood cellulose. Although cellulose fibers improved the strength and stiffness of the polyhydroxybutyrate (PHB), the samples were very brittle. The impact strength and elongation at break of the…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Electrochromism of vanadium-titanium oxide thin films prepared by spin-coating method

Katsumi Nagase、Youichi Shimizu、Norio Miura 等 4 位作者1992-07-20Applied Physics Letters

Electrochromic properties of V2O5-TiO2 thin films prepared by a spin-coating method were strongly dependent on the film compositions and heat-treatment temperatures. It was found that the nearly amorphous film of V2O5-TiO2 (3:7 in molar ratio) heat-treated at 400 °C showed coloration to reddish brown when polarized at…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Slow Dynamics of Isotropic-Nematic Phase Transition in Silica Gels

X. S. Wu、W. I. Goldburg、M. X. Liu 等 4 位作者1992-07-20Physical Review Letters

We report a quasielastic light scattering measurement of the isotropic-nematic phase transition of a liquid crystal in silica gel. The normalized intensity autocorrelation function, ${G}_{2}(t)$, which samples the order-parameter fluctuations, is consistent with the form ${G}_{2}(x)\ensuremath{\sim}\frac{1}{(1+{x}^{2}…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Correlation between non-Debye behavior andQbehavior of the α relaxation in glass-forming polymeric systems

Juan Colmenero、Ángel Alegría、Arantxa Arbe 等 4 位作者1992-07-20Physical Review Letters

By means of quasielastic neutron scattering we have shown that the dynamics of the \ensuremath{\alpha} relaxation on three different polymeric glasses shows a clear non-Debye behavior on a mesoscopic time scale. The spectral shape is found to be independent of temperature and momentum transfer (Q). The characteristic…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Surface and Bulk Charge Density Wave Structure in 1 T-TaS 2

B. Burk、R. E. Thomson、John Clarke 等 4 位作者1992-07-17Science

Incommensurate charge density waves (CDWs) in some materials form domains within which the CDWs may be commensurate. However, two questions have remained controversial: What is the geometrical structure of these domains, and are they or are they not identical on the surface and in the bulk? To address these issues in…

Organic and Molecular Conductors ResearchMachine Learning in Materials ScienceElectronic and Structural Properties of Oxides

Test No. 302B: Inherent Biodegradability: Zahn-Wellens/ EVPA Test

OECD1992-07-17OECD guidelines for the testing of chemicals. Section 3: Degradation and accumulation

This Test Guideline describes the Zahn-Wellens/EMPA Test. It is used to determine inherent biodegradability. A mixture containing the non-volatile and water soluble test substance, mineral nutrients and a relatively large amount of activated sludge in aqueous medium is agitated and aerated at 20-25°C in the dark or i…

Corrosion Behavior and Inhibition

A study on the attachment of human gingival cell structures to oral implant materials.

Massimo Simion、M Baldoni、Paolo Rossi1992-07-16PubMed

A technique enabling the study of adherence occurring among implant materials and epithelial and connective cells cultured in vitro and freshly obtained from explants of human gingival tissue is described. The data show that cell adherence to titanium alloy is influenced by the modality of implant surface preparation.

Electrospun Nanofibers in Biomedical ApplicationsOral and gingival health research

Wettability of nonaqueous elastomeric impression materials.

J Y Chai、T. C. Au Yeung1992-07-16PubMed

The wettability of eight nonaqueous elastomeric impression materials was studied by comparing their contact angles. The materials included three polyethers (one of which was light activated), three hydrophilic poly(vinyl siloxanes), one conventional poly(vinyl siloxane), and one poly(vinyl siloxane) putty. Extracted t…

Dental materials and restorationsSurface Modification and SuperhydrophobicityPhotopolymerization techniques and applications

Structural Studies of Thermally Evaporated Thin Films of Copper Phthalocyanine

A.K. Hassan、R.D. Gould1992-07-16physica status solidi (a)

Thin films of the organic semiconductor copper phthalocyanine (CuPc) are deposited onto glass substrates maintained at room temperature, and their structures investigated using X-ray diffractometry and infrared light absorption. Films of thicknesses approximately 0.1 μm are preferentially oriented in the [001] directi…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Refinement of the structure of barium copper silicate BaCu[Si4O10] at 300 K

Jan Janczak、R. Kubiak1992-07-15Acta Crystallographica Section C Crystal Structure Communications

Cristallisation dans P4/ncc avec a = 7,447 et c = 16,138 A, Z = 4; affinement jusqu'a R = 0,023. La structure est du type BaFe[Si 4 O 10 ]. Elle contient des tetraedres SiO 4 qui partagent des sommets pour former des cycles a 4 membres qui a leur tour forment des couches Si 8 O 20 . Les cations Ba et Cu sont localises…

Crystal Structures and PropertiesClay minerals and soil interactionsX-ray Diffraction in Crystallography

Medium-energy electron diffraction from Cu(100)

Yongli Gao、Ken T. Park1992-07-15Physical review. B, Condensed matter

We have investigated the polar-angle dependence of medium-energy electron diffraction (MEED) from a Cu(100) surface. It is observed that MEED is characterized by a combination of coherent and incoherent scattering, and the incoherent part is governed by the forward-scattering mechanism. The incoherent MEED pattern dif…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Various regimes of charge-density waves in layered compounds

G. P. E. M. van Bakel、J. Th. M. De Hosson1992-07-15Physical review. B, Condensed matter

In this paper we have subjected different layered transition-metal dichalcogenides to scanning tunneling microscopy to reveal the electronic charge distribution associated with the charge-density-wave (CDW) part of the superstructure, in addition to the atomic corrugation. The observations presented display three regi…

2D Materials and ApplicationsMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Lifetime of indirect excitons in AgBr quantum dots

Yasuaki Masumoto、Tomohiro Kawamura、Tomoyuki Ohzeki 等 4 位作者1992-07-15Physical review. B, Condensed matter

The lifetime of indirect excitons in AgBr quantum dots was studied at low temperature. Indirect-exciton luminescence shows a nonexponential decay. The unique nonexponential decay is well explained by a model that takes into account the discrete number of iodine impurities in a AgBr quantum dot. The obtained radiative…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresStrong Light-Matter Interactions

Cationic ring‐opening polymerization of tetrahydrofuran with boron, aluminum, and gallium tristriflate

George A. Olah、Omar Farooq、Cheng X. Li 等 5 位作者1992-07-15Journal of Applied Polymer Science

Abstract Boron, aluminum, and gallium tristriflate are new effective catalysts for the polymerization of tetrahydrofuran (THF). High‐molecular‐weight polytetrahydrofuran (PTHF) was obtained in excellent yield in the bulk polymerization of THF at ambient temperature with all three catalysts. The PTHF samples were chara…

Synthesis and characterization of novel inorganic/organometallic compoundsSynthesis and properties of polymers

Interconversion of diborane (4) isomers

John F. Stanton、Jürgen Gauß、Rodney J. Bartlett 等 7 位作者1992-07-15The Journal of Chemical Physics

Highly correlated electronic structure calculations using many-body perturbation theory (MBPT) and coupled-cluster (CC) gradient techniques are applied to a study of a reaction pathway which links the two forms [C2v and D2d ] of diborane(4) [B2H4]. A reaction coordinate which preserves C2 symmetry is studied, as this…

Hydrogen Storage and MaterialsBoron and Carbon Nanomaterials ResearchBoron Compounds in Chemistry

Structure-function relationships of the yeast fatty acid synthase: negative-stain, cryo-electron microscopy, and image analysis studies of the end views of the structure.

James K Stoops、Steven J. Kolodziej、John P. Schroeter 等 5 位作者1992-07-15Proceedings of the National Academy of Sciences

The yeast fatty acid synthase (M(r) = 2.5 x 10(6)) is organized in an alpha 6 beta 6 complex. In these studies, the synthase structure has been examined by negative-stain and cryo-electron microscopy. Side and end views of the structure indicate that the molecule, shaped similar to a prolate ellipsoid, has a high-dens…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function