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Evaluation of the fire‐retardant properties of new modifiers in unsaturated polyester resins using the cone calorimetric method

Ewa Kicko‐Walczak2003-10-01Macromolecular Symposia

Abstract An investigation of the burning behaviour of a series of unsaturated polyester resin formulations has been carried out using the Cone calorimeter technique. A complex analysis of the pyrolysis of selected glass‐reinforced polyester (GRP) laminates was made based on fire‐nonretarded, fire‐retarded and smoke su…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFlame retardant materials and properties

Conformational characteristics of stereoregular PMMA and of the stereocomplex: new insights from FTIR measurements

О. Н. Третинников2003-10-01Macromolecular Symposia

Abstract Isotactic (i) and syndiotactic (s) PMMA polymers differ markedly in the physical properties. The fact that these physically unlike macromolecules strongly attract each other with the resultant formation of stereocomplexes is indeed remarkable. Although stereoregular PMMAs and the stereocomplex have been studi…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Deformation mechanism and inverse Hall – Petch behavior in nanocrystalline materials

D. Wolf、V. Yamakov、Simon R. Phillpot 等 4 位作者2003-10-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract It is widely accepted that for the very smallest grain sizes (typically below 20 – 30 nm), dislocations play no significant role in the deformation of nanocrystalline materials. However, the grain-boundary mechanisms responsible for the reported decrease in strength with decreasing grain size in this regime (…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies

Impact of grain boundary character on grain boundary kinetics

Dmitri A. Molodov、L.S. Shvindlerman、Günter Gottstein2003-10-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The current research on grain boundary dynamics in metals is reviewed. The boundary dynamics, i. e., the boundary reaction to applied forces, is strongly dependent on the grain boundary character, which is commonly reduced to the orientation relationship between adjacent grains and impurity segregation at the…

Microstructure and mechanical propertiesMechanical stress and fatigue analysisMetal Alloys Wear and Properties

Application of SMAs in modern spacecraft and devices

А. И. Разов、A. G. Cherniavsky2003-10-01Journal de Physique IV (Proceedings)

The use of shape memory alloys in spacecraft and devices was suggested practically as soon as the first materials of this type had been discovered and investigations of their unique functional and mechanical properties had begun. However, various reasons led to a more than 30-years delay in realization of ideas in dev…

Shape Memory Alloy Transformations

In situ neutron diffraction studies of martensitic transformations in NiTi

Petr Šittner、P. Lukáš、D. Neov 等 5 位作者2003-10-01Journal de Physique IV (Proceedings)

Martensitic transformations in commercial near equiatomic Ni49.5Ti (at. %) polycrystalline thick wires induced by thermal and/or mechanical loading were investigated by in-situ high-resolution neutron powder diffraction techniques with the aim to develop neutron diffraction methods of stress and phases fraction evalua…

Metal and Thin Film MechanicsMicrostructure and Mechanical Properties of SteelsShape Memory Alloy Transformations

Crystal Structures of Biotite at High Temperatures and of Heat-Treated Biotite using Neutron Powder Diffraction

Chul‐Min Chon、Shin Ae Kim、Hi‐Soo Moon2003-10-01Clays and Clay Minerals

Abstract The crystal structure of biotite-1 M from Bancroft, Ontario, with the formula: <mml:math xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mnf="http://cambridge.org/core/manifest" xmlns:cup="http://contentservices.cambridge.org" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:m="http://cambridge.org/core/…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsNuclear materials and radiation effects

Scale up of NiTi shape memory alloy production by EBM

Jorge Otubo、Odair Doná Rigo、C. Moura Neto 等 5 位作者2003-10-01Journal de Physique IV (Proceedings)

Abstract. The usual process to produce NiTi shape memory alloy is by vacuum induction melting (VIM) using a graphite crucible, which causes contamination of the melt with carbon. Contamination with oxygen originates from the residual oxygen inside the melting chamber. An alternative process to produce NiTi alloys is b…

Shape Memory Alloy Transformations

Crystallization studies of amorphous melt-spun Ti50Ni25Cu25

P. Schloßmacher、N. Boucharat、Harald Rösner 等 4 位作者2003-10-01Journal de Physique IV (Proceedings)

Amorphous ribbons of the ternary shape memory alloy Ti 50 Ni 25 Cu 25 crystallize polymorphously upon heating. The subsequent growth proceeds isotropic resulting in the formation of perfectly spherical grains in an amorphous matrix at intermediate stages of the transformation. These experimental results match exactly…

Metallic Glasses and Amorphous AlloysShape Memory Alloy TransformationsQuasicrystal Structures and Properties

Thermal characteristics of high voltage whole-solid-insulated polymeric zno surge arrester

Jinliang He、Rong Zeng、Shuiming Chen 等 4 位作者2003-10-01IEEE Transactions on Power Delivery

A new type of 110-kV and 220-kV whole-solid-insulation polymeric ZnO surge arresters is developed. The power loss characteristics of ZnO varistors are discussed, which are simulated by an artificial neural network (ANN) model. The thermal performances of the new developed polymeric arresters are analyzed by the finite…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrical Fault Detection and Protection

Crystal structure of orthorhombic martensite in TiNi-Cu and TiNi-Pd intermetallics

Pavel Potapov、S. E. Kulkoval、A. V. Shelyakov 等 6 位作者2003-10-01Journal de Physique IV (Proceedings)

The crystal structure of orthorhombic martensite in ternary TiNi-based compounds has been several times examined, although, in all cases, the structure was not completely solved as the positions of atoms in the unit cell remained unknown. In the present work, the X-ray patterns of TiNi-Cu and TiNi-Pd films were refine…

Microstructure and Mechanical Properties of SteelsShape Memory Alloy TransformationsMagnetic Properties and Applications

Thermal Degradation of Polyurethane Elastomers: Determination of Kinetic Parameters

Emi Govorčin Bajsić、Vesna Rek、Ante Agić2003-10-01Journal of Elastomers & Plastics

The objective of this study is determining the kinetic parameters of thermal degradation of polyurethane elastomers before and after UV irradiation. To determine the kinetic parameters of elastomeric polyurethane (PUR) decomposition the Freeman-Carroll method of calculation is applied. The effect of soft segment and h…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingThermal and Kinetic Analysis

A method for linking thermally activated dislocation mechanisms of yielding with continuum plasticity theory

Craig S. Hartley2003-10-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

This work combines classical continuum mechanics, the continuously dislocated continuum theory as developed by Kröner and Bilby with discrete dislocation theory to develop quantities that permit models involving interactions between individual dislocations to be incorporated into a description of multiaxial yielding o…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsAluminum Alloys Composites Properties

Electrical tuning of dispersion characteristics of surface electromagnetic-spin waves propagating in ferrite~ferroelectric layered structures

V. E. Demidov、B. A. Kalinikos、S. F. Karmanenko 等 5 位作者2003-10-01IEEE Transactions on Microwave Theory and Techniques

Electrical tuning of dispersion characteristics has been studied experimentally for hybrid surface electromagnetic-spin waves propagating perpendicularly to the direction of the static magnetization in tangentially magnetized layered structures containing ferrite and ferroelectric layers. The tuning is realized throug…

Magnetic Properties and Applications

Synthesis of Polyphenylene Ether Derivatives: Estimation of Their Dielectric Constants

Yuusuke Seike、Yuriko Okude、Izumi Iwakura 等 6 位作者2003-10-01Macromolecular Chemistry and Physics

Abstract A series of poly(2‐alkyl‐6‐phenylphenylene ether)s were prepared by the oxidative polymerization of 2‐alkyl‐6‐phenylphenols. Their dielectric constants were approximately 2.5, whereas it was found that the phenyl group at the 6‐position clearly increased the Q factor of the polymer compared with poly(2,6‐dime…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Living polymerization of cyclic esters – a route to (bio)degradable polymers. Influence of chain transfer to polymer on livingness

Stanisław Penczek、Ryszard Szymański、Andrzej Duda 等 4 位作者2003-10-01Macromolecular Symposia

Abstract Polymerization of cyclic esters leads to (bio)degradable polymers of the increasing industrial importance. These polymerizations are of the living nature, although chain transfer to polymer with chain scission may cause deviations from the livingness and introduce structural differences (e.g. in end‐groups),…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Highly Coupled Dyads Based on Phthalocyanine−Ruthenium(II) Tris(bipyridine) Complexes. Synthesis and Photoinduced Processes

Ana González-Cabello、Purificación Vázquez、Tomás Torres⊗ 等 4 位作者2003-10-01The Journal of Organic Chemistry

A new series of multicomponent ZnPc-Ru(bpy)(3) systems, 1a-c, consisting of a zinc-phthalocyanine linked through conjugated and/or nonconjugated connections to a ruthenium(II) tris(bipyridine) complex, has been synthesized. The ruthenium complexes 1a-c were prepared from phthalocyanines 2a-c, bearing a 4-substituted-2…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Preparation of strach‐graft‐polyacrylamide copolymers by reactive extrusion

J. L. Willett、Victoria L. Finkenstadt2003-10-01Polymer Engineering and Science

Abstract Graft copolymers of starch and polyacrylamide (PAAm) were prepared by reactive extrusion using a co‐rotating twin‐screw extruder and ammonium presulfate initiator. Feed rates were 109 g/min to 325 g/min (all components) at a moisture content of 50%, with screw speeds in the range 100 rpm to 300 rpm. Starch/ac…

Food composition and propertiesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Use of reactive surfactants in basalt fiber reinforced polypropylene composites

Sz. Matkó、P. Anna、Gy. Marosi 等 7 位作者2003-10-01Macromolecular Symposia

Abstract Basalt fibers, similarly to other silicate fibers, can be introduced into both thermoplastic and thermosetting polymer matrices. In this work some basalt fiber reinforced polypropylene composites were investigated. The fiber‐matrix adhesion was improved by commercial and non‐commercial maleic anhydride deriva…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Transfer molding imide resins based on 2,3,3′,4′‐biphenyltetracarboxylic dianhydride

Joseph G. Smith、John W. Connell、P. M. Hergenrother 等 5 位作者2003-10-01Macromolecular Symposia

Abstract Phenylethynyl containing imide oligomers have been under investigation as part of an effort to develop resins for non‐autoclave composite fabrication processes such as resin transfer molding (RTM). These high performance/high temperature composites are potentially useful on advanced aerospace vehicles such as…

Epoxy Resin Curing ProcessesCopper Interconnects and ReliabilitySynthesis and properties of polymers