Materials Literature
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Scaling of the structural order parameter, polarization, and electrical properties was investigated in model ultrathin epitaxial SrRuO3∕PbZr0.2Ti0.8O3∕SrRuO3∕SrTiO3 heterostructures. High-resolution transmission electron microscopy images revealed the interfaces to be sharp and fully coherent. Synchrotron x-ray studie…
Abstract There exist several methods for the production of highly porous materials; among these, replication processing is well‐adapted for open‐pore microcellular structures. The process begins by making a porous preform, open pores of which are filled with the foam material. Thereafter the preform is removed, genera…
The structure and magnetic properties of the Ba-ordered state in solid solutions of manganites Ln0.70Ba0.30MnO3−δ (Ln = Pr, Nd) with a cation ratio Ln3+/Ba2+ ≫ 1 are studied experimentally. The samples are obtained by two-stage synthesis. The initial stoichiometric Ba-disordered solid solutions Ln0.70Ba0.30MnO3 synthe…
Atomic force microscopy was used to investigate ferroelectric switching and nanoscale domain dynamics in epitaxial Pb(Zr0.2Ti0.8)O3 thin films. Measurements of the writing time dependence of domain size reveal a two-step process in which nucleation is followed by radial domain growth. During this growth, the domain wa…
The electronic properties of N-doped rutile TiO2(110) have been investigated using synchrotron-based photoemission and density-functional calculations. The doping via N2+ ion bombardment leads to the implantation of N atoms (approximately 5% saturation concentration) that coexist with O vacancies. Ti 2p core level spe…
Plasma waves in graphene-based heterostructures with massless (neutrino-like) two-dimensional electron gas and with a highly conducting substrate (n + -Si) serving as a gate and an isolating gate layer (SiO 2 ) are studied. Using the developed model, we show that the sufficiently long plasma waves exhibit a linear (so…
Oleic acid (OA) modified zinc-blende cadmium selenium nanocrystals (NCs) with different diameters, 3-5 nm, have been prepared. We find that the morphology and fluorescent properties of the samples are related to the preparation conditions such as the chain-length and concentration of the cadmium precursor as well as t…
We report an easy synthesis of highly branched gold particles through a seed-mediated growth approach in the presence of citrate. The addition of citrate in the growth solution is found to be crucial for the formation of these branched gold particles. Their size can be varied from 47 to 185 nm. The length of the thumb…
Crystallite size distributions and particle size distributions were determined by transmissions electron microscopy (TEM), X-ray powder diffraction (XRD), and small-angle X-ray scattering (SAXS) for three commercially available TiO2 powders (P25, UV100, and TiO2_5 nm) and one SSEC produced powder (SSEC78). The theoret…
Two series of polyurethanes ( P1 − P10 ) containing NLO chromophores as side chains were prepared, in which the size of isolation groups was changed from small atoms to much larger groups such as carbazolyl groups. The polymers were well characterized. The tested NLO properties of the polymers demonstrate that the NLO…
We show that a thermally excited spin-current naturally appears in metals with embedded ferromagnetic nanoclusters. When such materials are subjected to a magnetic field, a spin current can be generated by a temperature gradient across the sample as a signature of electron-hole symmetry breaking in a metal due to the…
First-principles calculations have been performed for different collinear magnetic orderings in orthorhombic manganites, such as ${\mathrm{HoMnO}}_{3}$, ${\mathrm{TbMnO}}_{3}$, and ${\mathrm{YMnO}}_{3}$, showing large ${\mathrm{GdFeO}}_{3}$-like distortions. Our results suggest that the AFM-$E$ type ordering, experime…
We have studied the Heisenberg antiferromagnets on two-dimensional frustrated lattices, triangular and kagome lattices using linear spin-wave theory. A collinear ground state ordering is possible if one of the three bonds in each triangular plaquette of the lattice becomes weaker or frustrated. We study spiral order i…
This paper describes rheological measurements and associated optical microstructural observations of multiwall carbon nanotubes (MWCNTs) suspended in an epoxy resin matrix. The base epoxy resin was found to be essentially Newtonian, and the progressive incorporation of nanotubes enhanced the low shear rate viscosity o…
Abstract Here we present current issues in understanding the mechanical behavior of nanoporous foams as a new class of high yield strength / low density materials. Gold nanoporous foams are used for a systematic study of mechanical properties since they can be synthesized with a wide range of ligaments sizes and densi…
This paper proposes a hybrid energy system, which consists of a diesel-engine generator and a supercapacitor, for improving performance of a rubber tyred gantry crane (RTGC). The supercapacitor contributes to the energy recovery associated with regenerative braking in "Hoist-Down" braking operation and to the rapid en…
The nuclear industry strives to reduce the fuel cycle cost, enhance flexibility and improve the reliability of operation. This can be done by both increasing the fuel weight and optimizing rod internal properties that affect operational margins. Further, there is focus on reducing the consequences of fuel failures. To…
We studied spark-generated cavitation bubbles inside water drops produced in microgravity. High-speed visualizations disclosed unique effects of the spherical and nearly isolated liquid volume. In particular, (1) toroidally collapsing bubbles generate two liquid jets escaping from the drop, and the "splash jet" disclo…
Directly linked corrole dimer 1, which has a planar cyclooctatetraene in its core, has been synthesized from 2-borylcorrole in excellent yield. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation of 1 provides its oxidized form 4, which has two NH protons in each corrole core. Dicorrole 4 and its Zn(II) complex…
A study of the interaction between a membrane and a submerged oscillating bubble is presented. Though the behavior of such a bubble near an elastic (relatively thick) boundary has been studied by several authors, much less attention is focused on the behavior of such a bubble near a (thin) elastic membrane. For membra…