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High Rate Performance of Flexible Pseudocapacitors fabricated using Ionic-Liquid-Based Proton Conducting Polymer Electrolyte with Poly(3, 4-ethylenedioxythiophene):Poly(styrene sulfonate) and Its Hydrous Ruthenium Oxide Composite Electrodes

Sellam、S.A. Hashmi2013-04-02ACS Applied Materials & Interfaces

We report the studies on all-solid-state flexible pseudocapacitors based on poly (3,4-ethylenedioxythiophene)-poly (styrene sulfonate) (PEDOT-PSS) and PEDOT-PSS/hydrous ruthenium oxide composite electrodes separated by nonaqueous proton conducting polymer electrolyte. Structural, thermal and electrochemical properties…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Tunable nonreciprocal terahertz transmission and enhancement based on metal/magneto-optic plasmonic lens

Fei Fan、Sai Chen、Xianghui Wang 等 4 位作者2013-04-02Optics Express

A tunable metal/magneto-optic plasmonic lens for terahertz isolator is demonstrated. Based on the magneto-optical effect of the semiconductor material and non-symmetrical structure, this plasmonic lens has not only the focusing feature but also nonreciprocal transmission property. Moreover, a transmission enhancement…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Composition-Dependent Performance of CexZr1–xO2Mixed-Oxide-Supported WO3Catalysts for the NOxStorage Reduction–Selective Catalytic Reduction Coupled Process

Fabien Can、Sébastien Berland、Sébastien Royer 等 5 位作者2013-04-02ACS Catalysis

High Resolution Image Download MS PowerPoint Slide WO 3 /Ce x Zr 1– x O 2 materials were evaluated as a possible NH 3 -selective catalytic reduction (SCR) active catalyst in a NO x storage reduction (NSR) + SCR combined system. The effect of the support composition was investigated at a constant WO 3 loading (9.1 wt %…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Interface engineering of graphene for universal applications as both anode and cathode in organic photovoltaics

Hyesung Park、Sehoon Chang、Matthew J. Smith 等 5 位作者2013-04-02Scientific Reports

The high transparency of graphene, together with its good electrical conductivity and mechanical robustness, enable its use as transparent electrodes in optoelectronic devices such as solar cells. While initial demonstrations of graphene-based organic photovoltaics (OPV) have been promising, realization of scalable te…

Organic Electronics and PhotovoltaicsGraphene research and applicationsNanowire Synthesis and Applications

Wide-Field Multispectral Super-Resolution Imaging Using Spin-Dependent Fluorescence in Nanodiamonds

Edward H. Chen、Ophir Gaathon、Matthew E. Trusheim 等 4 位作者2013-04-02Nano Letters

Recent advances in fluorescence microscopy have enabled spatial resolution below the diffraction limit by localizing multiple temporally or spectrally distinguishable fluorophores. Here, we introduce a super-resolution technique that deterministically controls the brightness of uniquely addressable, photostable emitte…

Diamond and Carbon-based Materials ResearchAdvanced Fluorescence Microscopy TechniquesForce Microscopy Techniques and Applications

Control of Magnetocrystalline Anisotropy by Epitaxial Strain in Double PerovskiteSr2FeMoO6Films

Chunhui Du、Rohan Adur、Hailong Wang 等 6 位作者2013-04-02Physical Review Letters

We demonstrate tuning of magnetocrystalline anisotropy in high-quality Sr(2)FeMoO(6) epitaxial films over a range of several thousand Gauss using strain induced by epitaxial growth on substrates of varying lattice constants. Spectroscopic measurements reveal a striking, linear dependence of the out-of-plane anisotropy…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Photoluminescent Gold–Copper Nanoparticle Alloys with Composition-Tunable Near-Infrared Emission

Christopher M. Andolina、Andrew C. Dewar、Ashley M. Smith 等 6 位作者2013-04-02Journal of the American Chemical Society

Discrete gold nanoparticles with diameters between 2 and 3 nm show remarkable properties including enhanced catalytic behavior and photoluminescence. However, tunability of these properties is limited by the tight size range within which they are observed. Here, we report the synthesis of discrete, bimetallic gold-cop…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Porous Co3O4 Nanorods–Reduced Graphene Oxide with Intrinsic Peroxidase-Like Activity and Catalysis in the Degradation of Methylene Blue

Zhe Zhang、Jinhui Hao、Wenshu Yang 等 7 位作者2013-04-02ACS Applied Materials & Interfaces

A facile two step process was developed for the synthesis of porous Co3O4 nanorods-reduced graphene oxide (PCNG) hybrid materials based on the hydrothermal treatment cobalt acetate tetrahydrate and graphene oxide in a glycerol-water mixed solvent, followed by annealing the intermediate of reduced graphene oxide-suppor…

Electrochemical sensors and biosensorsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Phase Diagram of Diblock Copolymers Confined in Thin Films

Weihua Li、Meijiao Liu、Feng Qiu 等 4 位作者2013-04-02The Journal of Physical Chemistry B

The phase behaviors of diblock copolymers confined in thin films with two identical preferential surfaces are investigated using the self-consistent field theory. Around 20 morphologies, including centrosymmetric and non-centrosymmetric ones, are considered to construct the two-dimensional phase diagram with respect t…

Theoretical and Computational PhysicsBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Metal-insulator transition induced in CaVO3 thin films

Man Gu、Jude Laverock、Bo Chen 等 6 位作者2013-04-02Journal of Applied Physics

Stoichiometric CaVO3 (CVO) thin films of various thicknesses were grown on single crystal SrTiO3 (STO) (001) substrates using a pulsed electron-beam deposition technique. The CVO films were capped with a 2.5 nm STO layer. We observed a temperature driven metal-insulator transition (MIT) in CVO films with thicknesses b…

Semiconductor materials and devicesElectronic and Structural Properties of OxidesChemical and Physical Properties of Materials

Spectroscopic characterization of graphene films grown on Pt(111) surface by chemical vapor deposition of ethylene

Enzo Cazzanelli、T. Caruso、M. Castriota 等 8 位作者2013-04-02Journal of Raman Spectroscopy

This work reports the peculiar properties of a graphene film prepared by the chemical vapor deposition of ethylene in high vacuum on a well oriented and carefully cleaned Pt(111) crystal surface maintained at high temperature. In‐situ and ex‐situ characterization techniques (low‐energy electron diffraction, high‐resol…

Electrocatalysts for Energy ConversionGraphene research and applications2D Materials and Applications

Atomistic-to-continuum coupling

Mitchell Luskin、Christoph Ortner2013-04-02Acta Numerica

Atomistic-to-continuum (a/c) coupling methods are a class of computational multiscale schemes that combine the accuracy of atomistic models with the efficiency of continuum elasticity. They are increasingly being utilized in materials science to study the fundamental mechanisms of material failure such as crack propag…

Microstructure and mechanical propertiesNumerical methods in engineeringComposite Material Mechanics

Nanoscale analysis of the morphology and surface stability of calcium carbonate polymorphs

W. Sekkal、A. Zaoui2013-04-02Scientific Reports

Under earth surface conditions, in ocean and natural water, calcium carbonate is ubiquitous, forming anhydrous and hydrous minerals. These hydrous phases are of considerable interest for their role as precursors to stable carbonate minerals. Atomistic simulation techniques have been employed here to perform a comprehe…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniquesnanoparticles nucleation surface interactions

Three-dimensional quantum photonic elements based on single nitrogen vacancy-centres in laser-written microstructures

Andreas W. Schell、Johannes Kaschke、Joachim Fischer 等 7 位作者2013-04-02Scientific Reports

To fully integrate quantum optical technology, active quantum systems must be combined with resonant microstructures and optical interconnects harvesting and routing photons in three diemsnsions (3D) on one chip. We fabricate such combined structures for the first time by using two-photon laser lithography and a photo…

Diamond and Carbon-based Materials ResearchAdvanced Fiber Laser TechnologiesNonlinear Optical Materials Studies

Bio-Inspired Carbon Nanotube–Polymer Composite Yarns with Hydrogen Bond-Mediated Lateral Interactions

Allison M. Beese、Sourangsu Sarkar、Arun K. Nair 等 10 位作者2013-04-02ACS Nano

Polymer composite yarns containing a high loading of double-walled carbon nanotubes (DWNTs) have been developed in which the inherent acrylate-based organic coating on the surface of the DWNT bundles interacts strongly with poly(vinyl alcohol) (PVA) through an extensive hydrogen-bond network. This design takes advanta…

Carbon Nanotubes in CompositesAdvanced Materials and MechanicsSilk-based biomaterials and applications

A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl

Ahmed A. Al‐Amiery、Abdul Amir H. Kadhum、Abu Bakar Mohamad 等 4 位作者2013-04-02Materials

2-(1-methyl-4-((E)-(2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-ylidene)-hydrazineecarbothioamide (HCB) was synthesized as a corrosion inhibitor from the reaction of 4-aminoantipyrine, thiosemicarbazide and 2-methylbenzaldehyde. The corrosion inhibitory effects of HCB on mild steel in 1.0 M HCl were investiga…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

PT-Symmetric Nonlinear Metamaterials and Zero-Dimensional Systems

G. P. Tsironis、N. Lazarides2013-04-02arXiv

A one dimensional, parity-time (${\cal PT}$)-symmetric magnetic metamaterial comprising split-ring resonators having both gain and loss is investigated. In the linear regime, the transition from the exact to the broken ${\cal PT}$-phase is determined through the calculation of the eigenfrequency spectrum for two diffe…

Materials Sciencenlin.PSphysics.optics

Atomistic potentials for palladium–silver hydrides

Lucas Michael Hale、Bryan M. Wong、Jonathan A. Zimmerman 等 4 位作者2013-04-02Modelling and Simulation in Materials Science and Engineering

New embedded-atom method potentials for the ternary palladium–silver–hydrogen system are developed by extending a previously developed palladium–hydrogen potential. The ternary potentials accurately capture the heat of mixing and structural properties associated with solid solution alloys of palladium–silver. Stable h…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsNuclear Materials and Properties

Ab initio study of the TiO$_2$ Rutile(110)/Fe interface

Anna Gruenebohm、Heike C. Herper、Peter Entel2013-04-02arXiv

Adsorption of Fe on the rutile (110)-surface is investigated by means of {\it ab initio} density functional theory calculations. We discuss the deposition of single Fe atoms, an increasing Fe coverage, as well as the adsorption of small Fe clusters. It is shown that the different interface structures found in experime…

Materials Science

Nonaffine displacements in crystalline solids in the harmonic limit

Saswati Ganguly、Surajit Sengupta、Peter Sollich 等 4 位作者2013-04-02Physical Review E

A systematic coarse graining of microscopic atomic displacements generates a local elastic deformation tensor D as well as a positive definite scalar χ measuring nonaffinity, i.e., the extent to which the displacements are not representable as affine deformations of a reference crystal. We perform an exact calculation…

Material Dynamics and PropertiesTheoretical and Computational PhysicsGranular flow and fluidized beds