Materials Literature
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Three-dimensional (3D) hierarchical porous ZnO architectures constructed by sheet-like structures were prepared through calcination of a bilamellar basic zinc citrate intermediate. The molar ratio of citrate anion/Zn2+ and the pH value of the reaction solution play crucial roles in the formation of the 3D hierarchical…
Two novel zinc alkoxides supported by chelating methyl salicylato (MesalO; MesalOH = methyl salicylate) ligands were successfully synthesized and characterized. Reaction of MesalOH with ZnEt2 (2:1) gives a tetranuclear cluster [Zn(MesalO)2]4 (1), which by addition of pyridine is transformed to the mononuclear compound…
A tripeptide-perylene diimide (PDI) conjugate self-assembles into PDI@β-sheet nanohelices, whose local conformations are sensitive to the external stimuli of concentration, heating and ultrasound, showing stimulus-responsive supramolecular chirality.
Reaction of the mononuclear Ni(II) complex [Ni{2-Py(6-NH2)NHC(S)NP(S)(OiPr)2}2] with different salicylaldehydes leads to new antiferromagnetically coupled trinuclear double-stranded helicates , where Ni(II) metal ions are coordinated by two bis-anionic thiourea ligands and two deprotonated molecules of the correspondi…
MacDonald "2 + 2" condensation of a 1,2'-dipyrrylmethane dialdehyde with a 2,2'-dipyrrylmethane afforded a neo-confused porphyrin in 55% yield. In addition, a novel dihydroporphyrin with two appended pyrrolic units was isolated and structurally characterized.
Low-frequency Raman measurement was performed in alkali and alkaline-earth silicate glasses to elucidate the effect of introduction of network modifiers on boson peak nature. Our study illustrated that introduction of small/medium ions tended to increase in the boson peak frequency (ωBP), whereas the introduction of l…
Nanofibers hold enormous potential for novel nanomaterials due to their ease of fabrication, yet fabrication routes are primarily used to produce bilayer structures. This paper describes a novel process for producing tri-layer ceramic composite fibers, and presents a proof of concept in the form of a multilayer multif…
We proposed fabricating an aluminum microneedle array with a nanochannel structure on the surface by combining micromachining, electrolyte polishing, and anodization methods. The microneedle array provides a three‐dimensional (3D) structure that possesses several hundred times more surface area than a traditional nano…
Halopyridinium cations with multiple halogen and hydrogen bonding donor sites have been used as the counter ions for the Ni(dmit)2 anion (dmit = 1,3-dithiole-2-thione-4,5-dithiolate). Because of the competing supramolecular interactions, such as halogen and hydrogen bondings, some of the Ni(dmit)2 salts showed complic…
An alkaline-developable, positive-type, and photosensitive polyimide (PSPI) based on fluorinated poly(amic acid) (FPAA), poly(amic acid) (PAA), and fluorinated diazonaphthoquinone (FDNQ-1) as a photoactive compound has been successfully developed. The solution of FPAA, PAA, and FDNQ-1 was spin-coated on a silicon wafe…
Ground tire rubber (GTR) from whole passenger car tires is devulcanized using the conditions which are the best compromise for tire rubbers. The elaboration of the optimal devulcanization process for GTR is performed in order to obtain a homogeneous and high degree of devulcanization. Swelling of GTR in a mixture of a…
Mechanical alloying is a simple and useful processing technique that is now being employed in the production of nanocrystals and/or nanoparticles from all material classes. In the present work, preparation of silica nanoparticles (SiO 2 NPs) by wet mechanical attrition of white and yellow sand using a lab scaled ball…
Al-Co metal gate has been recently proposed both for 25 and 11 nm devices as an alternative for Al-Ti used for 45 nm structures. The polishing dispersions used for Al-Ti gates when tested on Al-Co showed severe pitting and static etch rates upto ∼10 nm/min. The present work describes the development of the required ch…
Leather industry is a prominent industrial sector in Bangladesh which has a massive influence on our economy. The industry has become an area of export thrust with footwear having been identified as an area of extreme focus. Though having massive potential, this overgrowing sector has received much criticism on enviro…
The electrochemically-assisted modification of the N-austenitic stainless steel (ASS N25) surface was successfully employed to improve barrier properties of the passive film in a chloride containing solution. The chemical composition, electronic and barrier properties of the surface film before and after the electroch…
The main aim of this paper is to look into the relationship between the structure and air permeability of a woven fabric, and discuss the possibility of the prediction of fabric air permeability. With respect to the relationship between the air permeability and structure of woven fabrics it is not possible to describe…
An approach to carry out chemical reactions using aggressive gases in situ in a transmission electron microscope (TEM), at ambient pressures of 1.5 bar using a windowed environmental cell, called a nanoreactor, is presented here. The nanoreactor coupled with a specially developed holder with platinum tubing permits th…
A novel dual-emission phosphor NaSrBO 3 : Ce 3+ , Mn 2+ was synthesized by the solid state reaction. The crystal structure, photoluminescence properties and concentration quenching of NaSrBO 3 : Ce 3+ , Mn 2+ phosphor were systematically investigated. NaSrBO 3 : Ce 3+ , Mn 2+ phosphors emit two distinctive colors: a b…
To improve the magnetic properties and MRI contrast effect of Fe3O4 superparamagnetic nanoparticles (NPs), a series of oleate-capped, Mn-doped MnxFe(1−x)Fe2O4 (x ≤ 0.4) NPs was prepared via a thermal decomposition method and subsequently assembled into nanoclusters by the carboxylic silane. The effects of Mn doping an…
This review highlights some of the advances that have been made in the study of donor–acceptor interactions and their applications in the construction of functional supramolecular architectures in 2012. The review is organised into three broad sections encompassing light-harvesting photovoltaics, donor–acceptor co-pol…