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Controlled biosilification using self-assembled short peptides A6K and V6K

Qinrong Wang、Jun Yu、Xin Zhang 等 7 位作者2012-12-20RSC Advances

We report the molecular self-assembly of two amphiphilic peptides (A6K and V6K) and the application of their self-assemblies as organic templates to direct biosilica formation. Under ambient conditions, A6K self-assembled into nanotubes 2.7 nm tall and approximately 1 μm to 2 μm long. In contrast, V6K self-assembled i…

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsDiatoms and Algae Research

Effect of the Wire Width and Magnetic Field on the Intrinsic Detection Efficiency of Superconducting Nanowire Single-Photon Detectors

R. Lusche、A. Semenov、K. Ilin 等 9 位作者2012-12-20IEEE Transactions on Applied Superconductivity

We present thorough measurements of the intrinsic detection efficiency in the wavelength range from 350 to 2500 nm for meander-type TaN and NbN superconducting nanowire single-photon detectors with different widths of the nanowire. The width varied from 70 nm to 130 nm. The open-beam configuration allowed us to accura…

Quantum Information and CryptographyDiamond and Carbon-based Materials ResearchSuperconducting and THz Device Technology

Synthesis and electronic properties of chemically functionalized graphene on metal surfaces

A. Grüneis2012-12-20Journal of Physics Condensed Matter

A review on the electronic properties, growth and functionalization of graphene on metals is presented. Starting from the derivation of the electronic properties of an isolated graphene layer using the nearest neighbor tight-binding (TB) approximation for π and σ electrons, the TB model is then extended to third-neare…

Advancements in Battery MaterialsGraphene research and applicationsSurface and Thin Film Phenomena

One-step polymer surface modification for minimizing drug, protein, and DNA adsorption in microanalytical systems

E. Larsen、Niels B. Larsen2012-12-20Lab on a Chip

The non-specific adsorption of dissolved analytes strongly reduces the sensitivity and reliability in polymer microanalytical systems. Here, a one-step aqueous phase procedure modifies polymer material surfaces to strongly reduce their non-specific adsorption of a broad range of organic analytes including hydrophobic…

Bone Tissue Engineering MaterialsAnalytical chemistry methods developmentPolymer Surface Interaction Studies

A Versatile Star PEG Grafting Method for the Generation of Nonfouling and Nonthrombogenic Surfaces

P. Thalla、Angel Contreras‐García、Hicham Fadlallah 等 7 位作者2012-12-20BioMed Research International

Polyethylene glycol (PEG) grafting has a great potential to create nonfouling and nonthrombogenic surfaces, but present techniques lack versatility and stability. The present work aimed to develop a versatile PEG grafting method applicable to most biomaterial surfaces, by taking advantage of novel primary amine-rich p…

Knee injuries and reconstruction techniquesElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Controllable Formation of Pyrene (C16H10) Excimers in Polystyrene/Tetrabutylammonium Hexafluorophosphate Films through Solvent Vapor and Temperature Annealing

Hyun‐Sook Jang、Ying Wang、Yu Lei 等 4 位作者2012-12-20The Journal of Physical Chemistry C

Pyrene, because of its wide applications in fluorescence sensors, has been studied extensively. Nevertheless, the formation of pyrene excimers in the solid state has not been well understood compared to that in its solution state. It has been shown that electrospun pyrene/polystyrene/tetrabutylammonium hexafluorophosp…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Surface ion engineering for tuning dual emission of ZnxCd1−xS nanocrystals

Satyapriya Bhandari、Raihana Begum、Arun Chattopadhyay2012-12-20RSC Advances

Oleate capped Zn doped CdS (ZnxCd1−xS) colloidal nanocrystal exhibited dual emission, which was tunable by selective removal of the cations, over its surface and in its immediate vicinity, using cation exchange resin beads (CB). The near band gap emission disappeared more rapidly in comparison to deep level emission,…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Studies

The strain effect on colossal oxygen ionic conductivity in nanoscale zirconia electrolytes: a first-principles-based study

Feng Li、Ruifeng Lu、Haiping Wu 等 7 位作者2012-12-20Physical Chemistry Chemical Physics

Density functional theory calculations and first-principles molecular dynamics (MD) simulations have been performed to examine the strain effect on the colossal oxygen ionic conductivity in selected sandwich structures of zirconia electrolytes. For the KTaO(3)/YSZ/KTaO(3) sandwich structure with 9.7% lattice mismatch,…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Polycarbosilane‐supported titanium(IV) catalyst for Knoevenagel condensation reaction

Kunniyur Mangala、K. Sreekumar2012-12-20Applied Organometallic Chemistry

Polycarbosilane (PCS) was synthesized by the polycondensation of trichloromethylsilane and trimethoxyvinylsilane in the presence of sodium metal. PCS has a highly crosslinked structure, high ceramic yield and high surface area. Titanium metal ion was attached to the polycarbosilane and its catalytic activity was inves…

Advanced ceramic materials synthesisCatalytic Cross-Coupling ReactionsSynthesis and properties of polymers

Nanomechanical Energy Storage in Twisted Nanotube Ropes

David Teich、Zacharias G. Fthenakis、Gotthard Seifert 等 4 位作者2012-12-20Physical Review Letters

We determine the deformation energetics and energy density of twisted carbon nanotubes and nanotube ropes that effectively constitute a torsional spring. Using ab initio and parametrized density functional calculations, we identify structural changes in these systems and determine their elastic limits. The deformation…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Highly efficient uptake of ultrafine mesoporous silica nanoparticles with excellent biocompatibility by Liriodendron hybrid suspension cells

Bing Xia、Chen Dong、Weigang Zhang 等 6 位作者2012-12-20Science China Life Sciences

The characteristics of the interactions co-cultures of ultrafine mesoporous silica nanoparticles (MSNs) and the Liriodendron hybrid suspension cells were systematically investigated using laser scanning confocal microscope (LSCM) and scanning electron microscopy (SEM). Using fluorescein isothiocyanate (FITC) labeling,…

Plant tissue culture and regenerationQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Unexpected weak spatial variation in the local density of states induced by individual Co impurity atoms in superconducting Na(Fe1−xCox)As crystals revealed by scanning tunneling spectroscopy

Huan Yang、Zhenyu Wang、Delong Fang 等 10 位作者2012-12-20Physical Review B

We use spatially resolved scanning tunneling spectroscopy in Na(Fe${}_{1\ensuremath{-}x}$Co${}_{x}$)As to investigate the impurity effect induced by Co dopants. The Co impurities are successfully identified, and the spatial distributions of local density of state at different energies around these impurities are inves…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Corrosion Inhibition of Tubing Steel during Acidization of Oil and Gas Wells

Mahendra Yadav、Sumit Kumar、Premanand Yadav2012-12-20Journal of Petroleum Engineering

Acidization is an oil reservoir stimulation technique for increasing oil well productivity. Hydrochloric acid is used in oil and gas production to stimulate the formation. The acid treatment occurs through N80 steel tubes. The process requires a high degree of corrosion inhibition of tubing material (N80 steel). In th…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Collective Dipole Behavior and Unusual Morphotropic Phase Boundary in Ferroelectric Pb(Zr0.5Ti0.5)O3 Nanowires

Xiujun Fu、Ivan I. Naumov、Huaxiang Fu2012-12-20Nano Letters

Dipole collective behavior and phase transition in ferroelectric (FE) Pb(Zr(0.5)Ti(0.5))O(3) nanowires, caused by modulated electric fields, are reported. Our result also leads to the finding of a rather outstanding electromechanical d(31) response in a 8.4 nm diameter PZT wire, which may potentially outperform bulk P…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Atomistic modeling of long-term evolution of twist boundaries under vacancy supersaturation

Enrique Martínez、Alfredo Caro2012-12-20Physical Review B

Vacancy accumulation in 4${}^{\ensuremath{\circ}}$ ${110}$ bcc Fe and 2${}^{\ensuremath{\circ}}$ ${111}$ fcc Cu twist boundaries (TBs) has been studied. These interfaces are characterized by different sets of screw dislocations: two sets of $\frac{{a}_{0}}{2}$$\ensuremath{\langle}$111$\ensuremath{\rangle}$ and one set…

Microstructure and mechanical propertiesFusion materials and technologiesHigh Temperature Alloys and Creep

Effect of Magnetic Nanoparticles on Tobacco BY-2 Cell Suspension Culture

Olga Kryštofová、Jiří­ Sochor、Ondřej Zítka 等 7 位作者2012-12-20International Journal of Environmental Research and Public Health

Nanomaterials are structures whose exceptionality is based on their large surface, which is closely connected with reactivity and modification possibilities. Due to these properties nanomaterials are used in textile industry (antibacterial textiles with silver nanoparticles), electronics (high-resolution imaging, logi…

Nanoparticles: synthesis and applications

Bi–Mn Binary Phase Diagram in High Magnetic Fields

Yoshifuru Mitsui、Keiichi Koyama、Kazuo Watanabe2012-12-20MATERIALS TRANSACTIONS

To examine magnetic field effects on the Bi–Mn equilibrium phase, a high-magnetic fields differential thermal analysis (HF-DTA) was performed for fields up to 18 T and temperatures ranging from 300 to 753 K. For zero field, the peritectic temperatures Tp1 (BiMn1.08 + Bi-rich liquid → BiMn) and Tp2 (αMn + Bi-rich liqui…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Synthesis of dendrimers terminated by DABCO ligands and applications of its palladium nanoparticles for catalyzing Suzuki–Miyaura and Mizoroki–Heck couplings

Yijing Xu、Zhanyi Zhang、Jia Zheng 等 5 位作者2012-12-20Applied Organometallic Chemistry

A new kind of silica‐supported third‐generation dendrimers capped by 1,4‐diaza‐bicyclo[2.2.2]octane (DABCO) group‐stabilized palladium(0) nanoparticles, and their enhanced catalytic activity in Suzuki–Miyaura and Mizoroki–Heck reactions in excellent yield under mild conditions, was reported. The resulting silica‐suppo…

Catalytic Cross-Coupling ReactionsSynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers

Synthesis of a CdSe–graphene hybrid composed of CdSe quantum dot arrays directly grown on CVD-graphene and its ultrafast carrier dynamics

Yong‐Tae Kim、Hee-Won Shin、Young‐Seon Ko 等 5 位作者2012-12-20Nanoscale

We report the original fabrication and performance of a photocurrent device that uses directly grown CdSe quantum dots (QDs) on a graphene basal plane. The direct junction between the QDs and graphene and the high quality of the graphene grown by chemical vapor deposition enables highly efficient electron transfer fro…

Graphene research and applicationsQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

MRI contrast variation of thermosensitive magnetoliposomes triggered by focused ultrasound: a tool for image‐guided local drug delivery

Cyril Lorenzato、Alexandru Cernicanu、Marie-Edith Meyre 等 10 位作者2012-12-20Contrast Media & Molecular Imaging

Improved drug delivery control during chemotherapy has the potential to increase the therapeutic index. MRI contrast agent such as iron oxide nanoparticles can be co-encapsulated with drugs in nanocarrier liposomes allowing their tracking and/or visualization by MRI. Furthermore, the combination of a thermosensitive l…

Nanoparticle-Based Drug DeliveryUltrasound and Hyperthermia ApplicationsCharacterization and Applications of Magnetic Nanoparticles