Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAttractive Inter- and Intramolecular N.cntdot..cntdot..cntdot.O Interactions in N,N-Dipicrylamine and Its Ionic ComplexesKrzysztof Wozniak, Heyong He, Jacek Klinowski, William Jones, and Eugeniusz GrechCite this: J. Phys. Chem. 1994, 98, 51, 13755–13765Publication Date (Prin…
Abstract An apparatus is described to measure interfacial tension for molten polymer pairs. The apparatus is based on the pendant drop method. A CCD color video camera captures the image of a pendant drop profile, which is analyzed on‐line using a microcomputer. These almost continuous measurements permit the detectio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComplementary Shapes in Columnar Liquid Crystals: Structural Control in Homo- and Heteronuclear Bimetallic AssembliesAndre G. Serrette, Chung K. Lai, and Timothy M. SwagerCite this: Chem. Mater. 1994, 6, 12, 2252–2268Publication Date (Print):December 1, 1994Publication Histo…
The low-valent titanium induced reductive coupling of metal(II) 5-formyl-octaethylporphyrin (OEP) (2, 3) leads to the formation of ethene-bridged bisporphyrins. Structural studies on the main products of the coupling of Cu(II) (2) and Ni(II) 5-formyl-OEP (3) revealed, surprisingly, the formation of the cis-isomers 1,2…
Abstract A non‐invasive γ‐ray emission system, employing eight NaI detectors, has been developed to follow the motion of a single radioactive particle in a three‐dimensional spouted bed reactor. The count‐rates measured simultaneously by the detectors are converted into tracer coordinates (x, y, z) using a pre‐establi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb Initio Studies of Neutral and Protonated Triglycines: Comparison of Calculated and Experimental Gas-Phase BasicityKui Zhang, Carolyn J. Cassady, and Alice Chung-PhillipsCite this: J. Am. Chem. Soc. 1994, 116, 25, 11512–11521Publication Date (Print):December 1, 1994Publica…
Abstract Interfacial tension is one of the most important parameters that govern the morphology of polymer blends and the quality of adhesion between polymers. However, few data are available on interfacial tension due to experimental difficulties. A pendant drop apparatus was used for the determination of the interfa…
Abstract Clay samples of greenish colour were collected from submarine hydrothermal chimneys of the Galapagos Rift and Mariana Trough. Mineralogical and chemical investigations of the clay by scanning and transmission electron microscopy, X-ray diffraction, differential thermal analysis, infrared-spectros-copy, X-ray…
The theory for the coupled perturbed Kohn–Sham calculation of hyperpolarizabilities using nonlocal density functionals is presented. Results for calculations on formaldehyde, acetonitrile, and methyl fluoride using moderate size basis sets are reported. These results are compared with previous density functional calcu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of Molecular Structure on the Thermodynamics of Block Copolymer MeltsC. C. Lin, S. V. Jonnalagadda, P. K. Kesani, H. J. Dai, and N. P. BalsaraCite this: Macromolecules 1994, 27, 26, 7769–7780Publication Date (Print):December 1, 1994Publication History Published online…
Natural pyrochlore and zirconolite undergo a crystalline-aperiodic transformation caused by alpha-decay of 232Th and 2380 at dose levels between 2 X 1014 and 3 X 1017 a/mg. The principal effects of the transformation are volume expansion and microfracturing, providing potential pathways for fluids. Geochemical alterat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpin Conversion versus Antiferromagnetic Interaction in Iron(II) Trinuclear Species. Crystal Structures and Magnetic Properties of [Fe3(p-MeOptrz)8(H2O)4](BF4)6 and [Fe3(p-MeOprtz)6(H2O)6](tos)6 [p-MeOptrz = 4-(p-Methoxyphenyl)-1,2,4-triazole, tos = tosylate]Martina Thomann,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMicellization Kinetics of Block Copolymers in Selective SolventChikako Honda, Yuki Hasegawa, Rieko Hirunuma, and Takuhei NoseCite this: Macromolecules 1994, 27, 26, 7660–7668Publication Date (Print):December 1, 1994Publication History Published online1 May 2002Published inis…
Results from a high resolution calorimetric study for the alkylcyanobiphenyl liquid crystal series nCB, with n the number of carbons in the alkyl chain, confined to the 0.2 \ensuremath{\mu}m diam cylindrical pores of Anopore membranes are reported. The orientational order at the pore wall is controlled and varied from…
Summary Soil solution was obtained from potted rhizosphere or non‐rhizosphere soils by water displacement or soil centrifugation. The pH of the displaced solutions was lower than that of bulk soils when solutions were obtained from non‐rhizosphere soil, although it increased as plants grew. This increase probably refl…
Studies investigating the erosion mechanism of the newly developed poly (fatty acid dimer: sebacic acid) polyanhydride (p:[FAD:SA]) are described. The overall erosion of different monomer compositions of p(FAD:SA) copolymers was examined to determine whether and to what extent copolymer properties affected polymer ero…
Impedance spectra of carbon steel in the presence of 1‐hydroxy‐ethane‐1,1‐diphosphonic acid (HEDP) has been investigated in neutral solutions. The aim of the measurements was to study the effect of HEDP on the carbon steel corrosion as a function of inhibitor concentration. An optimal inhibitor concentration was found…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnomalous Double Cyclization Reactions of .beta.-FormylporphyrinsLaurent Barloy, David Dolphin, Daniel Dupre, and Tilak P. WijesekeraCite this: J. Org. Chem. 1994, 59, 26, 7976–7985Publication Date (Print):December 1, 1994Publication History Published online1 May 2002Publish…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSupramolecular Chemistry. 49. Ligand-Porphyrin Complexes: Quantitative Evaluation of Stacking and Ionic ContributionsHans-Joerg Schneider and Manxue WangCite this: J. Org. Chem. 1994, 59, 24, 7464–7472Publication Date (Print):December 1, 1994Publication History Published onl…
The sequence of a 2,437-bp DNA segment from the naphthalene upper catabolic pathway operon of plasmid NAH7 was determined. This segment contains three large open reading frames designated nahQ', nahE, and nahD. The first of these is the 3' end of an open reading frame that has no known function, the second (993 bp) en…