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Computational Evaluation of Low NOx Operating Conditions in Arch-Fired Boilers

Norberto Fueyo、V. Gambo ́n、César Dopazo 等 4 位作者1999-10-01Journal of Engineering for Gas Turbines and Power

In the present paper, a computational model is used to simulate the aero-dynamic, thermal, and chemical conditions inside an arch-fired coal boiler. The model is based on the Eulerian-Eulerian concept, in which Eulerian conservation equations are solved both for the gas and the particulate phases. A NOx formation and…

Thermochemical Biomass Conversion ProcessesCatalytic Processes in Materials ScienceRadiative Heat Transfer Studies

Structure development in silica-filled rubber composites

Shigeyuki Ono、Yasutaro Kiuchi、Junich Sawanobori 等 4 位作者1999-10-01Polymer International

Structure development in silica filled polyisoprene composites was investigated by wide line pulsed NMR and high-resolution solid-state NMR combined with transmission electron microscopy. The rubber phase in the composites was composed of so-called bound rubber and free rubber. Furthermore, the bound rubber was compos…

Concrete and Cement Materials ResearchPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Studies of thermal polymerization of vegetable oils with a differential scanning calorimeter

Chaohua Wang、Sevim Z. Erhan1999-10-01Journal of the American Oil Chemists Society

Abstract Vegetable oils are often thermally polymerized to provide a vehicle for printing inks and paints. The formations of isomerization, and the intra‐ and intermolecular bonds involved in the thermal process are crucial in designing a product with the appropriate characteristics. It was found, with a differential…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingThermal and Kinetic Analysis

Rigid polyurethane foams with poly(ethylene terephthalate)/triethanolamine recycling products

M. Kacperski、Tadeusz Spychaj1999-10-01Polymers for Advanced Technologies

A product of the chemical degradation of poly(ethylene terephthalate) (PET) with triethanolamine was used as a polyol component for rigid polyurethane foam synthesis. Miscibility of the product with water, some polar organic solvents and commercial polyols was investigated. Viscosities of the product as a function of…

Polymer composites and self-healing

Production of PHAs from agricultural waste material

Gerhart Braunegg、K. Genser、Rodolfo Bona 等 6 位作者1999-10-01Macromolecular Symposia

Abstract Polyhydroxyalkanoates (PHAs) are biodegradable substitutes to fossil fuel plastics that can be produced from renewable raw materials such as saccharides, alcohols and low‐molecular‐weight fatty acids. They are completely degradable to carbon dioxide and water through natural microbiological mineralization. Co…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Glycine Insertion in the Hinge Region of Lactose Repressor Protein Alters DNA Binding

Catherine M. Falcon、Kathleen S. Matthews1999-10-01Journal of Biological Chemistry

Amino acid alterations were designed at the C terminus of the hinge segment (amino acids approximately 51-59) that links two functional domains within lactose repressor protein (LacI). Gly was introduced between Gly(58) and Lys(59) to generate Gly(58+1); Gln(60) was changed to Gly or Pro, and up to three additional gl…

Protein Structure and DynamicsProtein Kinase Regulation and GTPase SignalingEnzyme Structure and Function

Juncus bulbosus as a pioneer species in acidic lignite mining lakes: interactions, mechanism and survival strategies

Abad Chabbi1999-10-01New Phytologist

Bulbous rush ( Juncus bulbosus ) initiates plant colonization in extremely acid lakes resulting from coal mining operations. Various analytical techniques (methylene blue/agar method, Ti 3+ ‐citrate solution) X‐ray diffraction (XRD), scanning electron microscopy (SEM), and Energy‐dispersive X‐ray (EDX) were used to as…

Plant Diversity and EvolutionClay minerals and soil interactionsCoal and Its By-products

Electrical and Optical Properties of Transparent Conducting Homologous Compounds in the Indium–Gallium–Zinc Oxide System

Toshihiro Moriga、Daniel R. Kammler、Thomas O. Mason 等 5 位作者1999-10-01Journal of the American Ceramic Society

The homologous compounds In 1− x Ga 1+ x O 3 (ZnO) k (where k = 1, 2, or 3) were prepared at a temperature of 1400°C. The solubility limits (as determined via X‐ray diffractometry) were 0.47 < [In]/([In] + [Ga]) < 0.67 for the k = 1 member, 0.35 < [In]/([In]+[Ga]) < 0.77 for the k = 2 member, and 0.29 <…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Crystallization Kinetics of Mullite in Alumina–Silica Glass Fibers

Takahiro Takei、Yoshikazu Kameshima、Atsuo Yasumori 等 4 位作者1999-10-01Journal of the American Ceramic Society

The mechanism of mullite crystallization in Al 2 O 3 ‐SiO 2 glass fibers with compositions of 49 and 69 mass% Al 2 O 3 was investigated using isothermal methods. The activation energies ( E a ) of the nucleation and nucleation‐growth of mullite were obtained from the temperature dependence of the incubation times and…

Advanced ceramic materials synthesisRecycling and utilization of industrial and municipal waste in materials productionAdvanced materials and composites

Municipal Solid Waste Recycling Issues

Lester B. Lave、Chris Hendrickson、Noellette Conway‐Schempf 等 4 位作者1999-10-01Journal of Environmental Engineering

Municipal solid waste (MSW) recycling targets have been set nationally and in many states. Unfortunately, the definitions of recycling, rates of recycling, and the appropriate components of MSW vary. MSW recycling has been found to be costly for most municipalities compared to landfill disposal. MSW recycling policy s…

Recycled Aggregate Concrete PerformanceRecycling and Waste Management TechniquesMaterial Selection and Properties

Thin-film synthesis of the orthorhombic phase ofSnO2

F. J. Lamelas、Scott A. Reid1999-10-01Physical review. B, Condensed matter

We demonstrate the formation of an ${\mathrm{SnO}}_{2}$ thin film in an orthorhombic phase which has previously been found in high-pressure experiments. Our starting point was the pulsed-laser deposition of an amorphous film of SnO on Si [001] substrates. During a series of subsequent heat treatments in air, the film…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Fatigue of precipitate strengthened Cu–Ni–Si alloy

Scott Lockyer、F. W. Noble1999-10-01Materials Science and Technology

The fatigue resistance and tensile properties of a precipitate strengthened Cu–Ni–Si alloy have been investigated. Underaged material exhibited greater work hardening rates than either the peak aged or overaged material. It is proposed that this occurs because the δ-Ni2 Si precipitates can be cut by dislocations, but…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsAluminum Alloys Composites Properties

A detailed characterization of polyglycolide prepared by solid-state polycondensation reaction

Karsten Schwarz、Matthias Epple1999-10-01Macromolecular Chemistry and Physics

Polyglycolide (polyglycolic acid, PGA) was prepared by thermally induced solid-state polycondensation from sodium chloroacetate. This reaction leads to a composite of PGA with NaCl, out of which the latter can be extracted by washing with water. A highly porous polymer remains. The course of the reaction was followed…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

An evaluation of Re, as an alternative to Pt, for the 1 bar loop technique; an experimental study at 1400 degrees C

А. В. Борисов、J. H. Jones1999-10-01American Mineralogist

Previous investigators have shown that, at high pressure, Re is a good capsule material and that Fe loss to Re under these conditions is minimal (e.g., Herzberg and Zhang 1997). We present here the first systematic low-pressure study of Re loop stability and of Fe loss from silicate melts to Re loops as a function off…

High-pressure geophysics and materialsAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Crystallinity determination of native and stretched wool by X-ray diffraction

Jinan Cao、Craig A Billows1999-10-01Polymer International

A quantitative study on α–β transition of Merino wool upon stretching has been carried out by wide angle X-ray diffraction using Merino wool fibre bundles. Technical factors affecting this determination, such as subtraction of air scattering and the measurement of crystallinity are considered. The degree of crystallin…

Dyeing and Modifying Textile FibersTextile materials and evaluations

Peroxidase-catalyzed oxidative polymerization ofm-substituted phenol derivatives

Hiroyuki Tonami、Hiroshi Uyama、Shiro Kobayashi 等 4 位作者1999-10-01Macromolecular Chemistry and Physics

Peroxidase-catalyzed oxidative polymerization of m-substituted phenols has been performed in a mixture of a water-miscible organic solvent and buffer at room temperature under air to give a new class of polyphenols. The catalysts used were horseradish and soybean peroxidases (HRP and SBP, respectively). In the polymer…

biodegradable polymer synthesis and propertiesEnzyme-mediated dye degradationBiochemical and biochemical processes

Kinetic model of phase separation in binary mixtures with hard mobile impurities

Valeriy V. Ginzburg、Gongwen Peng、Feng Qiu 等 5 位作者1999-10-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We develop a mean-field rate-equation model for the kinetics of phase separation in binary mixtures with hard mobile impurities. For impurities preferentially wet by one of the components, the phase separation is arrested in the late stage. The "steady-state" domain size depends strongly on both the particle diffusion…

Material Dynamics and PropertiesGranular flow and fluidized bedsnanoparticles nucleation surface interactions

In-situ corrosion investigation at Masnedø CHP plant - a straw-fired power plant

Melanie Montgomery、A. Karlsson1999-10-01Materials and Corrosion

Various austenitic and ferritic steels were exposed on a water-cooled probe in the superheater area of a straw-fired CHP plant. The temperature of the probe ranged from 450–600°C and the period of exposure was 1400 hours. The rate of corrosion was assessed based on unattacked metal remaining. The corrosion products an…

Hydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual StressesNon-Destructive Testing Techniques

Anisotropic Shrinkage in Tape‐Cast Alumina: Role of Processing Parameters and Particle Shape

P. Markondeya Raj、W. Roger Cannon1999-10-01Journal of the American Ceramic Society

Aqueous suspensions of alumina and other powders containing no visible morphological anisotropy were tape cast under different conditions to study the role of processing parameters and powder characteristics in the origin of in‐plane sintering shrinkage anisotropy. High anisotropic shrinkage, with the typical shrinkag…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesPowder Metallurgy Techniques and Materials

Ultrafast optical properties of gold nanoshells

Richard D. Averitt、Sarah L. Westcott、Naomi J. Halas1999-10-01Journal of the Optical Society of America B

We present the results of ultrafast pump–probe measurements on films of gold-coated gold sulfide nanoshells. The measured change in transmission (ΔT/T) agrees with theoretical calculations that relate the increase in the electron temperature to changes in the Drude and interband components of the gold shell dielectric…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchMolecular Junctions and Nanostructures