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Matching molecular and optical multipoles in photoisomerizable nonlinear systems

Rozenn Piron、Sophie Brasselet、D. Josse 等 6 位作者2005-06-01Journal of the Optical Society of America B

We experimentally investigate the coupling rules between molecules and optical fields in the all-optical poling scheme. The efficiency and symmetry of the photoinduced quadratic nonlinearity is shown to be dependent on tensorial selection rules connecting the symmetries of the optical poling fields and the molecular t…

Advanced Fiber Laser TechnologiesNonlinear Optical Materials ResearchPhotorefractive and Nonlinear Optics

Stable electroluminescence from passivated nano‐crystalline porous silicon using undecylenic acid

Bernard Gelloz、Hikaru Sano、Rabah Boukherroub 等 6 位作者2005-06-01Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Stabilization of electroluminescence from nanocrystalline porous silicon diodes has been achieved by replacing silicon-hydrogen bonds terminating the surface of nanocrystalline silicon with more stable silicon-carbon (Si-C) bonds. Hydrosilylation of the surface of partially and anodically oxidized porous silicon sampl…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnodic Oxide Films and Nanostructures

SITE OCCUPANCY OF Co AND Ni IN ERYTHRITE ANNABERGITE SOLID SOLUTIONS DEDUCED BY VIBRATIONAL SPECTROSCOPY

Wayde N. Martens、J. Theo Kloprogge、R. L. Frost 等 4 位作者2005-06-01The Canadian Mineralogist

Members of the solid-solution series between erythrite [CO (ASO)2•8HO] and annabergite [Ni (AsO)2•8HO] were synthesized and studied by a combination of X-ray diffraction, scanning electron microscopy, and Raman and infrared spectroscopy. The solid solution is complete, with the space group C2/m (monoclinic) being reta…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Large area etching for porous semiconductors

Jürgen Carstensen、M. Christophersen、S. Lölkes 等 8 位作者2005-06-01Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

While electrochemical etching of small samples in the 1 cm region is relatively easy, this is not true for large areas, i.e. standard wafer sizes up to 300 mm. The paper outlines the specific demands and difficulties in some detail, discusses large area etching strategies and systems, in particular for very deep macro…

Surface Modification and SuperhydrophobicityCopper Interconnects and ReliabilityAnodic Oxide Films and Nanostructures

Plasma-catalytic Selective Reduction of NO with C2H4 in the Presence of Excess Oxygen

Qi Sun、Ai‐Min Zhu、Xuefeng Yang 等 7 位作者2005-06-01Chinese Chemical Letters

This paper reports observations of significant synergistic effects between dielectric barrier discharge (DBD) plasmas and Cu-ZSM-5 catalysts for C2H4 selective reduction of NOx at 250℃ in the presence of excess oxygen by using a one-stage plasma-over-catalyst (POC) reactor. With the reactant gas mixture of 530ppm NO,…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsPlasma Applications and Diagnostics

Exploration Study of Multifunctional Metallic Nanocomposite Utilizing Single-Walled Carbon Nanotubes for Micro/Nano Devices

Quanfang Chen、Guang Chai、Bo Li2005-06-01Proceedings of the Institution of Mechanical Engineers Part N Journal of Nanoengineering and Nanosystems

Carbon nanotubes (CNTs) are excellent multifunctional materials in terms of mechanical robustness, thermal, and electrical conductivities. These multifunctional properties, as well as the small size of the structures, make CNTs ideal building blocks in developing nanocomposites. However, the matrix materials and the f…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Black permanganate conversion coatings on aluminium alloys for thermal control of spacecraft

R. Rani、Anand Sharma、S.M. Mayanna 等 5 位作者2005-06-01Surface Engineering

A black conversion coating on aluminium alloys in an electrolyte system consisting of potassium permanganate, copper nitrate, arsenic trioxide and nitric acid was investigated. To optimise the process, the effects of various operating parameters, i.e. electrolyte concentration, operating temperature, treatment time an…

Corrosion Behavior and InhibitionSilicone and Siloxane ChemistryThermal Expansion and Ionic Conductivity

Development of EBC for Silicon Nitride

Shunkichi Ueno、Daniel Doni Jayaseelan、Naoki Kondo 等 6 位作者2005-06-01Key engineering materials

Various coating methods of EBC layer for silicon nitride were discussed. High density EBC layer was successfully coated by different techniques such as sputtering, sol-gel and reaction sintering methods. Water vapor corrosion and recession mechanisms of Lu2Si2O7 which is a potential material for EBC were discussed. Th…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsSemiconductor materials and devices

Liquid Crystal Digital Beam Steering Device Based on Decoupled Birefringent Deflector and Polarization Rotator

Oleg Pishnyak、Liubov Kreminska、Oleg D. Lavrentovich 等 6 位作者2005-06-01Molecular Crystals and Liquid Crystals

We describe digital beam deflectors (DBDs) based on liquid crystals. Each stage of the device comprises polarization rotator and birefringent prism deflector. We used prisms made of the uniaxial smectic A (SmA) liquid crystal and a solid yttrium orthovanadate crystal. SmA prisms have high birefringence and can be cons…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced optical system design

Theoretical nonlinear optics equivalence between mesoionic and polyenic bridges in push-pull compounds

Andréa Monteiro Santana Silva、Gerd B. Rocha、Paulo Henrique Menezes 等 5 位作者2005-06-01Journal of the Brazilian Chemical Society

In this work we report a semiempirical investigation with the purpose of establishing an equivalence in terms of the value of the first static hyperpolarizability, beta(0), of push-pull compounds of the type electron-acceptor(A) - bridge - electron-donor(D), either formed by polyenic bridges or by mesoionic bridges, k…

Photonic and Optical DevicesNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Vitamins: Potential inhibitors for nickel in acidic media

Sita Rani Malhotra、Gurmeet Singh2005-06-01Surface Engineering

Corrosion of Ni in 1N HNO 3 has been investigated in the presence of Vitamins B 1 , B 6 and C. Galvanostatic study carried out at a temperature range of 308 K to 328 K revealed a very high inhibition efficiency of these additives. The I% varied in the range of 99·1–99·7% for 10 −2 M concentration of Vitamin B 1 , 43·7…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Alumina/Alumina and Alumina‐Zirconia/Alumina‐Zirconia Joints Through Glass Interlayers, Microstructure, Mechanical Properties and Residual Stresses

Maria Giulia Faga、Stefano Guicciardi、L. Esposito 等 5 位作者2005-06-01Advanced Engineering Materials

As alternative to traditional joining methods, Ca‐Al silicate glasses were used to self‐bond alumina and alumina‐zirconia ceramics under different processing conditions. Microstructures, mechanical properties and residual stress studies have shown glassy interlayer characteristics to be correlated with the chemistry o…

Advanced ceramic materials synthesisGlass properties and applicationsNuclear materials and radiation effects

Switching Processes and Formation of the Stable Artificial Domain Structure in Ferroelectric LaBGeO5

B. A. Strukov、E. V. Milov、V. N. Milov 等 8 位作者2005-06-01Ferroelectrics

The processes of polarization switching in LaBGeO 5 (LBGO) crystals are studied in details for the triangle and pulse electric field in the wide temperature range from room temperature (RT) to Tc = 530°C. It is revealed that the temperature dependence of a coercive field (f = 0.1 Hz) has an exponential form and this f…

Nonlinear Optical Materials ResearchAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Investigation on Mechanical Compatibility Matching for Biomedical Titanium Alloys

Zhen Yu、Lian Zhou、Lijuan Luo 等 5 位作者2005-06-01Key engineering materials

The effects of alloying elements such as Mo, Sn, Zr, Nb, deforming-rate, solid solution and aging treatment on mechanical property and microstructure of near βtype biomedical Ti alloys based on Ti-Nb-Zr system were studied. The Influential factors and their solution were discussed to keep matching of strength, elastic…

Orthopaedic implants and arthroplastyAdditive Manufacturing Materials and ProcessesTitanium Alloys Microstructure and Properties

Photochromic Dynamics of Salicylidene Aniline in Solid State by Using Femtosecond Transient Absorption Spectroscopy

Tsuyoshi Asahi、Hiroshi Masuhara、Keitaro Nakatani 等 4 位作者2005-06-01Molecular Crystals and Liquid Crystals

This paper reports the dynamics of the photochromic reaction of crystalline N-(3,5-di-tert-butylsalicyliden)-4-aminopyridine which can be applied for nonlinear optical photoswitches. The transient absorption spectra of the microcrystalline powder were measured by femtosecond diffuse reflectance spectroscopy and compar…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryNonlinear Optical Materials Studies

Mechanical properties of N,N,N-trimethylchitosan chloride films

Douglas de Britto、Sérgio Paulo Campana Filho、O. B. G. Assis2005-06-01Polímeros

Films of chitosan and N,N,N-trimethylchitosan were cast from aqueous solutions. Chitosan was dissolved in 1% acetic acid while deionized water was the solvent for N,N,N-trimethylchitosan chloride. The resulting films presented different mechanical behaviors as evaluated by DMTA. The film of chitosan exhibited an elast…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolymer Surface Interaction Studies

Mesogenic Schiff's base ester with chloroethyl tail

A. K. Prajapati、Nilesh L. Bonde、H. N. Patel2005-06-01Phase Transitions

Two new mesogenic homologous series of Schiff's base ester with chloroethyl tail having the following general formula have been synthesized. The molecular structures of the synthesized compounds were characterized by the standard spectroscopic methods and elemental analysis. The mesomorphic behaviour of these new Schi…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Characterization of Maleic Acid/Anhydride Copolymer Films by Low-Rate Dynamic Liquid−Fluid Contact Angle Measurements Using Axisymmetric Drop Shape Analysis

Petra Uhlmann、Sebastian Skorupa、Carsten Werner 等 4 位作者2005-06-01Langmuir

Thin films of alternating maleic acid/anhydride copolymers (poly(octadecene-alt-maleic acid/anhydride), POMA; poly(propene-alt-maleic acid/anhydride), PPMA; poly(styrene-alt-maleic acid/anhydride), PSMA) were studied to unravel the influence of the comonomer characteristics in the backbone on the surface-energetic pro…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPickering emulsions and particle stabilization

Electrical Conductivity of Polymer Composites Filled with Metal

Hideo Horibe、Tomosumi Kamimura、Kunio Yoshida2005-06-01Japanese Journal of Applied Physics

Conductive polymer composites filled with conductive filler particles exhibit a positive temperature coefficient (PTC) effect. It is desirable to develop these composites with a low resistivity at room temperature and a high resistivity after polymer melting. We evaluated the relationships between the PTC properties o…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesThermal properties of materials