Materials Literature
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Various DNAs were employed as hosts to investigate the sequence-dependent formation of fluorescent Au nanoclusters (Au NCs) in aqueous solution. By comparison among hairpin DNAs (HP-DNAs) with a pristine stem segment and varied loop sequences, we found that the emission behavior of the HP-DNA-hosted Au NCs is dependen…
A three-dimensional extension of the recently demonstrated generalization of the laws of refraction and reflection was investigated for both flat and curved metasurfaces. We found that out-of-plane refraction occurs for a metasurface that imparts a wavevector out of the plane of incidence onto the incident light beam.…
Conduction between graphene layers is suppressed by momentum conservation whenever the layer stacking has a rotation. Here we show that phonon scattering plays a crucial role in facilitating interlayer conduction. The resulting dependence on orientation is radically different than previously expected, and far more fav…
Tapping mode atomic force microscopy (AFM) is employed for dynamic plowing lithography of exfoliated graphene on silicon dioxide substrates. The shape of the graphene sheet is determined by the movement of the vibrating AFM probe. There are two possibilities for lithography depending on the applied force. At moderate…
The effects of various SO 2 and NO concentrations on the adsorption capacity of activated carbon were measured experimentally for sequential and simultaneous adsorption of SO 2 and NO in a fixed bed using an area integral calculation method. The results show that higher NO concentrations increase SO 2 adsorption, espe…
Self-assembly of isoporous membranes of polystyrene- b -poly(4-vinylpyridine) (PS- b -P4VP) involves many parameters: the block copolymer composition, the solvent and its interactions with the respective blocks, composition of the casting solution, solvent evaporation, and immersion into a water bath. We characterized…
This study aims to develop antimicrobial films consisting of chitosan and silver nanoparticles that are homogeneously distributed throughout the polymer matrix. Nanoparticles were generated in situ during the neutralization of the chitosan acetate film with sodium hydroxide. The temperature of neutralization and the c…
This study focuses on the development of facile polyethylenimine–copper (C2H5N–Cu) supramolecular polymer networks which upon mechanical damage are capable of reversible UV-induced self-repairs by the reformation of Cu–N coordination bonds. The chemical changes responsible for self-healing that leads to network remode…
A straightforward synthesis of the fused-aromatic dione benzo[1,2-b:6,5-b']dithiophene-4,5-dione (BDTD) has been developed. This fused-aromatic dione was subjected to various chemical transformations to generate diverse molecules with potential use in π-conjugated materials for organic electronics.
Little is known about the behavior of engineered nanomaterials (ENM) at the interface from the technosphere to the ecosphere. Previous modeling of ENM flows to the environment revealed that significant amounts of ENM enter the waste stream and therefore waste incineration plants and landfills. It is the aim of this st…
We apply the quasiparticle self-consistent GW approximation (QSGW) to some of the iron pnictide and chalcogenide superconductors. We compute Fermi surfaces and density of states, and find excellent agreement with experiment, substantially improving over standard band-structure methods. Analyzing the QSGW self-energy w…
Three different types of polarization-sensitive perfect absorbers are designed and numerically investigated. The bottle-like and the cup-like absorbers are narrowband absorbers, which strongly absorb light of a specific polarization and reflect almost all light of another polarization. By varying the geometric paramet…
Hydroxy terminated polybutadiene is a low molecular weight telechelic, translucent liquid rubber which finds a wide range of applications. The presence of double bonds and hydroxyl end groups can be effectively utilized to chemically modify into various functional groups such as epoxy, urethane, urethane methacrylate,…
PVA/CuI polymer composite samples have been prepared and subjected to characterizations using FT-IR spectroscopy, DSC analysis, ac spectroscopy and dc conduction. The FT-IR spectral analysis shows remarkable variation of the absorption peak positions whereas DSC illustrates a little decrease of both glass transition t…
Abstract Aluminum‐based salen and salan complexes mediate the ring‐opening polymerization (ROP) of rac ‐β‐butyrolactone (β‐BL), rac ‐lactide, and ε‐caprolactone. Al‐salen and Al‐salan complexes exhibit excellent control over the ROP of rac ‐β‐butyrolactone, yielding atactic poly(3‐hydroxybutyrate) (PHB) with narrow PD…
Producing white light using near-UV LEDs requires the development of new phosphors, as well as the modification of certain existing ones. In this review, we discuss the luminescent properties of potential phosphors: oxides, silicates, phosphates and nitrides. We evaluate phosphors that employ 4f-5d transitions, line e…
We present a new instrumentation and calibration procedure for terahertz time-domain spectroscopic ellipsometry (THz-TDSE) that is a newly established characterization technique. The experimental setup is capable of providing arbitrary angle of incidence in the range of $15^\circ$--$85^\circ$ in the reflection geometr…
Semiconductor nanocrystals, or quantum dots (QDs), are one of the most widely utilized nanomaterials for biological applications. Their cumulative physicochemical and optical properties are both unique among nanomaterials and highly advantageous. In particular, Förster resonance energy transfer (FRET) has been widely…
Aluminium (Al) is an important structural engineering material, its usage ranking only behind ferrous alloys (Birbilis, Muster et al. 2011). The growth in usage and production of Al continues to increase (Davis 1999). The extensive use of Al lies in its strength:density ratio, toughness, and to some degree, its corros…
In the last decade, the nanotechnology advancement has developed a plethora of novel and intriguing nanomaterial application in many sectors, including research and medicine. However, many risks have been highlighted in their use, particularly related to their unexpected toxicity in vitro and in vivo experimental mode…