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Thermal Decomposition of Metal Nitrates in Air and Hydrogen Environments

S. Yuvaraj、Lin Fan-Yuan、Tsong-Huei Chang 等 4 位作者2003-01-01OpenAlex

The decomposition of metal nitrates in air has been systematically studied by thermogravimetry. Observed temperatures of decomposition ( T d ) have been inversely correlated to the charge densities (CD) of the metal cations. Due to a back-donation of electronic cloud from the nitrate to an unfilled d-orbital of transi…

Thermal and Kinetic AnalysisCatalytic Processes in Materials ScienceInorganic and Organometallic Chemistry

Facile synthesis of high quality mesoporous SBA-15 with enhanced control of the porous network connectivity and wall thickness

Minkee Choi、Wonjoon Heo、Freddy Kleitz 等 4 位作者2003-01-01OpenAlex

Convenient and commercially viable synthesis conditions are described, providing efficient and reproducible control of pore connectivity and pore wall thickness for the synthesis of high quality SBA-15 mesoporous silica.

Polyoxometalates: Synthesis and ApplicationsZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Blocking Grain Boundaries in Yttria‐Doped and Undoped Ceria Ceramics of High Purity

Xin Guo、Wilfried Sigle、Joachim Maier2003-01-01OpenAlex

CeO 2 samples doped with 10, 1.0, and 0.1 mol% Y 2 O 3 and undoped CeO 2 samples of high purity were studied by impedance spectroscopy at temperatures <800°C and under various oxygen partial pressures. According to microstructural investigations by SEM and analytical STEM (equipped with EDXS), the grain boundaries…

Electronic and Structural Properties of OxidesCatalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel Cells

Electrochemical bandgaps of substituted polythiophenes

Tomas Johansson、Wendimagegn Mammo、Mattias Svensson 等 5 位作者2003-01-01OpenAlex

The electrochemical bandgaps for different soluble substituted polythiophenes have been measured by cyclic voltammetry. The effect of substituents on the oxidation/reduction potentials is discussed. Bandgaps obtained by cyclic voltammetry have been found to be in general higher than optical bandgaps. Among regioregula…

Conducting polymers and applicationsAnalytical Chemistry and SensorsOrganic Electronics and Photovoltaics

Using multiple structure alignments, fast model building, and energetic analysis in fold recognition and homology modeling

Donald Petrey、Zhexin Xiang、Christopher L. Tang 等 13 位作者2003-01-01OpenAlex

We participated in the fold recognition and homology sections of CASP5 using primarily in-house software. The central feature of our structure prediction strategy involved the ability to generate good sequence-to-structure alignments and to quickly transform them into models that could be evaluated both with energy-ba…

Enzyme Structure and FunctionProtein Structure and DynamicsGlycosylation and Glycoproteins Research

Crystal and co-crystal

Gautam R. Desiraju2003-01-01OpenAlex

The first page of this article is displayed as the abstract.

X-ray Diffraction in CrystallographyCrystallography and molecular interactionsNonlinear Optical Materials Research

Transparent Sintered Corundum with High Hardness and Strength

Andreas Krell、Paul S. Blank、Hongwei Ma 等 6 位作者2003-01-01OpenAlex

Commercial corundum powder and a liquid‐shaping approach are used for manufacturing complex hollow components and large flat windows of sintered and hot isostatically pressed Al 2 O 3 ceramics having grain sizes of 0.4–0.6 μm at relative densities of >99.9%. High macrohardness (HV10 = 20–21 GPa) and four‐point bend…

Advanced materials and compositesFerroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesis

Rubidium 85 D Line Data

D. Steck2003-01-01OpenAlex

In this reference we present many of the physical and optical properties of Rb that are relevant to various quantum optics experiments. In particular, we give parameters that are useful in treating the mechanical effects of light on Rb atoms. The measured numbers are given with their original references, and the calcu…

Spectroscopy and Quantum Chemical StudiesCold Atom Physics and Bose-Einstein CondensatesCrystal Structures and Properties

Structure Validation by C Geometry: , and C Deviation

Simon C. Lovell、Ian Davis、W.B. Arendall 等 8 位作者2003-01-01OpenAlex

Geometrical validation around the C is described, with a new C measure and up- dated Ramachandran plot. Deviation of the ob- served C atom from ideal position provides a single measure encapsulating the major structure-valida- tion information contained in bond angle distor- tions. C deviation is sensitive to incompat…

Enzyme Structure and FunctionEnzyme Production and CharacterizationProtein Structure and Dynamics

Radiation Effects in Zircon

Rodney C. Ewing2003-01-01OpenAlex

The widespread distribution of zircon in the continental crust, its tendency to concentrate trace elements, particularly lanthanides and actinides, its use in age-dating, and its resistance to chemical and physical degradation have made zircon the most important accessory mineral in geologic studies. Because zircon is…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

Grain-Boundary Sliding in AZ31 Magnesium Alloys at Room Temperature to 523 K

Junichi Koike、R. Ohyama、Takuya Kobayashi 等 5 位作者2003-01-01OpenAlex

Rolled sheets of AZ31 Mg alloys were subjected to tensile testing at temperatures ranging from room temperature to 523 K. The occurrence of grain-boundary sliding (GBS) at room temperature was demonstrated by the displacement of scribed lines across grain boundaries of deformed samples. Surface relief of deformed samp…

Aluminum Alloys Composites PropertiesMagnesium Alloys: Properties and ApplicationsAdvanced Welding Techniques Analysis

A general review of polymeric insulation for use in HVDC cables

Tracey Hanley、R.P. Burford、R.J. Fleming 等 4 位作者2003-01-01OpenAlex

The authors present a review article of the properties of XLPE and an examination of the origins of space charge and how it is measured. The space charge in the insulation and the conduction current can affect the electric stress distribution in the insulation. The effect of morphology on the electrical properties of…

Power Transformer Diagnostics and InsulationDielectric materials and actuatorsHigh voltage insulation and dielectric phenomena

Fuel Composition and Diluent Effect on Gas Transport and Performance of Anode-Supported SOFCs

Yi Jiang、Anil V. Virkar2003-01-01OpenAlex

Anode-supported solid oxide fuel cells (SOFCs) with Ni+yttria-stabilized zirconia (YSZ) anode, YSZ-samaria-doped ceria (SDC) bilayer electrolyte, and Sr-doped (LSC)+SDC cathode were fabricated. Fuel used consisted of diluted with He, or mixtures of and CO, and mixtures of CO and Cell performance was measured at 800°C…

Fuel Cells and Related MaterialsElectrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel Cells

Hydrogen in Trapping States Innocuous to Environmental Degradation of High-strength Steels

Kenichi Takai、Ryu Watanuki2003-01-01OpenAlex

Hydrogen in trapping states innocuous to environmental degradation of the mechanical properties of highstrength steels has been separated and extracted using thermal desorption analysis (TDA) and slow strain rate test (SSRT). The high-strength steel occluding only hydrogen desorbed at low temperature (peak 1), as dete…

Microstructure and Mechanical Properties of SteelsMaterial Properties and Failure MechanismsHydrogen embrittlement and corrosion behaviors in metals

Transition-metal complexes for liquid-phase catalytic oxidation: some aspects of industrial reactions and of emerging technologies

Jean‐Marie Brégeault2003-01-01OpenAlex

This review presents recent developments in some important industrial processes. For homolytic systems, the similarities and specificities of the transformation of cyclohexane into adipic acid (via the formation and isolation of the cyclohexanol–cyclohexanone mixture) and of the process for the preparation of terephth…

Oxidative Organic Chemistry ReactionsCatalysis and Oxidation ReactionsPolyoxometalates: Synthesis and Applications

Compact linear lead/lag metamaterial phase shifters for broadband applications

Marco A. Antoniades、George V. Eleftheriades2003-01-01OpenAlex

A compact one-dimensional phase shifter is proposed using alternating sections of negative refractive index (NRI) metamaterials and printed transmission lines (TL). The NRI metamaterial sections consist of lumped element capacitors and inductors, arranged in a dual TL (high-pass) configuration. By adjusting the NRI-me…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Metallic interconnectors for solid oxide fuel cells – a review

W. J. Quadakkers、J. Pirón-Abellán、V. Shemet 等 4 位作者2003-01-01OpenAlex

For planar solid oxide fuel cell (SOFC) designs, ceramic as well as metallic materials are being considered as construction materials for the interconnectors. Compared to the ceramics, mostly compounds on the basis of La-chromite, metallic materials have the advantage of easier fabricability, lower costs as well as hi…

Magnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of OxidesAdvancements in Solid Oxide Fuel Cells

A controllable synthetic route to Cu, Cu2O, and CuO nanotubes and nanorodsElectronic supplementary information (ESI) available: EDS patterns of nanotubes and SEM images of nanorods. See http://www.rsc.org/suppdata/cc/b3/b304505f/

Minhua Cao、Changwen Hu、Yonghui Wang 等 6 位作者2003-01-01OpenAlex

Reducing Cu(OH)4(2-) with hydrazine hydrate and glucose in the presence of a structure-directing surfactant at room temperature gave Cu and Cu2O nanotubes/nanorods, respectively, whereas facile hydrothermal treatment of Cu(OH)4(2-) precursor resulted in CuO nanotubes/nanorods.

ZnO doping and propertiesCopper-based nanomaterials and applicationsGas Sensing Nanomaterials and Sensors

Ionic liquid salt-induced inactivation and unfolding of cellulase from Trichoderma reesei

Megan B. Turner、Scott K. Spear、Jonathan G. Huddleston 等 5 位作者2003-01-01OpenAlex

The potential for performing cellulase-catalyzed reactions on cellulose dissolved in 1-butyl-3-methylimidazolium chloride ([bmim]Cl) has been investigated. We have carried out a systematic study on the irreversible solvent and ionic strength-induced inactivation and unfolding of cellulase from Trichoderma reesei (E.C.…

Catalysis for Biomass ConversionAdvanced Cellulose Research StudiesBiofuel production and bioconversion

Gram-scale CCVD synthesis of double-walled carbon nanotubes

Emmanuel Flahaut、Revathi Bacsa、Alain Peigney 等 4 位作者2003-01-01OpenAlex

Synthesis of clean double-walled carbon nanotubes by a catalytic chemical vapour deposition (CCVD) method is reported; the catalyst is a Mg(1 - x)Co(x)O solid solution containing additions of Mo oxide; this MgO-based catalyst can be easily removed, leading to gram-scale amounts of clean carbon nanotubes, 77% of which…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications