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The structure of two manganese hexacyanometallates(II): Mn 2 [Fe(CN) 6 ].8H 2 O and Mn 2 [Os(CN) 6 ].8H 2 O

Ariel Gómez、V. H. Lara、P. Bosch 等 4 位作者2002-06-01Powder Diffraction

The crystal structures of two manganese hexacyanometallates(II), Mn 2 [Fe(CN) 6 ].8H 2 O and Mn 2 [Os(CN) 6 ].8H 2 O, were refined from X-ray powder diffraction data using the Rietveld method, with the reported structure for Mn 2 [Ru(CN) 6 ].8H 2 O used as a structural model. These compounds are isomorphous and crysta…

Magnetism in coordination complexesInorganic Chemistry and MaterialsX-ray Diffraction in Crystallography

Fiber-modified scaling in heat transfer fouling mitigation

S.N. Kazi、Geoffrey G Duffy、Xiao Dong Chen2002-06-01Chemical Engineering Communications

The study of heat exchanger fouling using supersaturated calcium sulphate solutions has been widely reported. In this study fouling was investigated in a larger-scale heat exchange apparatus using stainless-steel pipe, and data were obtained at different flow rates, concentrations and temperature differences. The depo…

Calcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic EffectsFreezing and Crystallization Processes

Use of algae for monitoring of heavy metals in the River Vardar, Macedonia

Zlatko Levkov、Svetislav Krstić2002-06-01Mediterranean Marine Science

Aiming to resolve some of the problems regarding monitoring of heavy metals in rivers using Cladophora glomerata and epilithic algal communities, a year’s survey of Co, Cd, Cu, Fe, Mn, Pb and Zn has been conducted on the river Vardar, FY Republic of Macedonia. Obtained results and statistical analysis clearly point ou…

Heavy metals in environmentDiatoms and Algae ResearchInvertebrate Taxonomy and Ecology

Spectroscopic Study of Neodymium(III) in Sodium Tellurite Glass

Hong Li、S. K. Sundaram、P. A. Blanc‐Pattison 等 4 位作者2002-06-01Journal of the American Ceramic Society

The local environment of Nd‐O in a sodium tellurite glass was elucidated as a function of Nd 2 O 3 concentration, from 0.1 to 2.5 mol%, using optical spectroscopy. The Judd‐Ofelt (J‐O) theory was used to determine the oscillator strength parameters (J‐O parameters) of the glasses. According to the J‐O parameters, a si…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsOptical properties and cooling technologies in crystalline materials

Energetic and Electronic Structure of the Hypothetical Cubic Zincblende-Like Semiconductors GeC and SnC

Abdelnour Benzair、H. Aourag2002-06-01physica status solidi (b)

First-principles all-electron total-energy calculations of the structural and electronic properties for the group-IV zincblende-like compounds GeC, SnC using the full-potential linearized plane wave (FP-LAPW) approach within the density functional theory (DFT) in the local density approximation (LDA) and the generaliz…

Boron and Carbon Nanomaterials ResearchSemiconductor materials and interfacesMXene and MAX Phase Materials

Determinação de fase vítrea em bauxitas refratárias

Cláudia Pascoal、Raquel C. Machado、V. C. Pandolfelli2002-06-01Cerâmica

A refratariedade e a resistência ao choque térmico dos materiais estão intrinsecamente ligadas às fases que os compõem, de modo que a identificação destas fases através da técnica de difração de raios X é atualmente imprescindível para a completa caracterização de matérias-primas de produtos cerâmicos. Em 1969, H. M.…

Metallurgical Processes and ThermodynamicsX-ray Diffraction in CrystallographyPigment Synthesis and Properties

REFINEMENT OF THE CRYSTAL STRUCTURE OF USHKOVITE FROM NEVADOS DE PALERMO, REPUBLICA ARGENTINA

Miguel Ángel Galliski、F. C. Hawthorne2002-06-01The Canadian Mineralogist

Nous avons affine la structure cristaline de l'ushkovite, triclinique, a 5.3468(4), b 10.592(1), c 7.2251(7) A, a 108.278(7), β 111.739(7), γ 71.626(7)°, V 351.55(6) A 3 , Z = 2, groupe spatial P1, jusqu'a un residu R de 2.3% en utilisant 1781 reflexions observees mesurees avec rayonnement MoKa. Le meme cristal a par…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

Size Reduction of Particulate Energetic Material

Ulrich Teipel、Irma Mikonsaari2002-06-01Propellants Explosives Pyrotechnics

The size reduction by dispersers in the liquid phase was investigated for different energetic materials such as hexogen (RDX), octogen (HMX), 3-nitro-1,2,4-triazole-5-one (NTO), hexanitrostilbene (HNS), ammonium nitrate (AN) and hexanitrohexaazaisowurtzitane (CL20). Two different dispersers, an ultrasonic device and a…

Energetic Materials and CombustionMinerals Flotation and Separation TechniquesThermal and Kinetic Analysis

In Situ Characterization and Differentiation of Kaolinites in Lateritic Weathering Profiles Using Infrared Microspectroscopy

Anicet Beauvais、Jacques Bertaux2002-06-01Clays and Clay Minerals

Abstract Lateritic weathering kaolinites have been characterized in situ and differentiated for the first time by means of infrared microspectroscopy (IRMS). Four classical OH-stretching bands have been observed in the Fourier transform infrared (FTIR) spectra, at 3695, 3668, 3650 and 3620 cm −1 , denoted ν 1 , ν 2 ,…

Geological and Geochemical AnalysisClay minerals and soil interactionsGeochemistry and Geologic Mapping

Spatial and intensity modulation of light emission from a silicon LED matrix

M. du Plessis、H. Aharoni、Lukas W. Snyman2002-06-01IEEE Photonics Technology Letters

A novel experimental multiterminal silicon light emitting diode matrix is described, where both the emitted light intensity and the spatial light pattern of the device are controlled by insulated metal-oxide-semiconductor (MOS) gate voltages. It is found that the light intensity is a nonlinear quadratic function of th…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

The Effect of Oxygen on the Kinetics and Particle Size Distribution in Vinyl Chloride Emulsion Polymerization

Costas Kiparissides、Dimitris S. Achilias、Costas E. Frantzikinakis2002-06-01Industrial & Engineering Chemistry Research

A comprehensive mathematical model is developed to quantify the effect of the oxygen concentration on the polymerization rate and particle size distribution in an unseeded vinyl chloride batch emulsion polymerization reactor. Particle formation is assumed to proceed by both the homogeneous and micellar nucleation mech…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Science and PVC

High-Voltage on-Site Commissioning Tests for Gas-Insulated Substations Using UHF Partial Discharge Detection

R. N. Bell、C. Charlson、S. Halliday 等 6 位作者2002-06-01IEEE Power Engineering Review

This paper describes the practical application of the UHF Partial Discharge Detection method that VA TECH Reyrolle has routinely applied to high-voltage on-site commissioning tests on gas-insulated substations (GIS) for over 10 years. The location of the partial discharge (PD) sensors has a significant effect on the s…

High voltage insulation and dielectric phenomenaThermal Analysis in Power TransmissionPower Line Inspection Robots

Hydroxynitrile lyase-catalyzed addition of HCN to 4-substituted cyclohexanones: stereoselective preparation of tetronic acids

Franz Effenberger、Jürgen Roos、C. Kobler 等 4 位作者2002-06-01Canadian Journal of Chemistry

The addition of HCN to 4-alkylcyclohexanones 1 to give cyanohydrins 2 is strongly catalyzed by hydroxy-ni trile lyases (HNLs). With PaHNL, from bitter almond, trans-addition occurs almost exclusively, yielding trans-2. With MeHNL, from cassava, cis-addition is preferred to give cis-2. cis-Selectivity is nearly quantit…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionEnzyme Production and Characterization

Influence of post-manufacturing residual mechanical stress and crosslinking by-products on dielectric strength of HV extruded cables

N. Amyot、Éric David、S.Y. Lee 等 4 位作者2002-06-01IEEE Transactions on Dielectrics and Electrical Insulation

Residual mechanical stresses from manufacturing always exist in freshly extruded HV cables. These stresses are not uniformly distributed in the cable insulation bulk material. Five different HV cables were analyzed with respect to residual mechanical stresses and dielectric breakdown strength. Photoelastic measurement…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationThermal Analysis in Power Transmission

Modelling oxide thin films

Dean C. Sayle、C. Richard A. Catlow、Nicu Dulamiţă 等 7 位作者2002-06-01Molecular Simulation

Three simulation methodologies have been employed to investigate the growth, nucleation, and structure of oxides supported on oxide substrates, these are atom-by-atom deposition, layer-by-layer deposition and finally amorphisation of a structure followed by recrystallisation. The materials which have been investigated…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

The Reaction of Poly(chlorophosphazene)s withp-Aminophenol − Specific Formation of Aminophosphazenes with Terminal OH Groups and Aryloxyphosphazenes with Terminal NH2 Groups

Gabino A. Carriedo、José I. Martínez、Francisco J. Garcı́a Alonso 等 5 位作者2002-06-01European Journal of Inorganic Chemistry

The outcome of the reaction of the bifunctional reagent p-aminophenol (HO-C6H4-NH2) with the cyclic triphosphazene [N3P3Cl6] is very dependent on the solvent, the temperature, and the proton abstractor. In THF at room temperature with K2CO3 the reaction is very slow and takes place only through the NH2 group to give a…

Flame retardant materials and propertiesInorganic and Organometallic ChemistryThermal and Kinetic Analysis

Streamer propagation along profiled insulator surfaces

L Pritchard、N.L. Allen2002-06-01IEEE Transactions on Dielectrics and Electrical Insulation

Experimental results on the propagation of positive streamers along contoured, axially symmetric, polytetrafluoroethylene (PTFE) insulation surfaces are presented. A plane parallel electrode configuration provides a substantially uniform electric field for streamer propagation and a point electrode at the ground plane…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Hoganite and paceite, two new acetate minerals from the Potosi mine, Broken Hill, Australia

David E. Hibbs、Uwe Kolitsch、Peter Leverett 等 5 位作者2002-06-01Mineralogical Magazine

Abstract Hoganite, copper(II) acetate monohydrate, and paceite (pronounced ‘pace-ite’), calcium(II) copper(II) tetraacetate hexahydrate, occur as isolated crystals embedded in ferruginous gossan from the Potosi Pit, Broken Hill, New South Wales, Australia. They are associated with goethite, hematite, quartz, linarite,…

Geological and Geochemical AnalysisCrystal Structures and PropertiesMineralogy and Gemology Studies

Flavonoids with Activity against Methicillin-Resistant Staphylococcus aureus from Dalea scandens var. paucifolia

N. P. Dhammika Nanayakkara、Charles L. Burandt、Melissa R. Jacob2002-06-01Planta Medica

Bioassay-guided fractionation of the ethyl acetate extract of the roots of Dalea scandens (Miller) R. Clausen var. paucifolia led to the isolation of new flavonoids, 2( S)-5'-(-1"',1"'-dimethylallyl)-8-(3",3"-dimethylallyl)-2',4',5,7-tetrahydroxyflavanone, 2( S)-5'-(1"',1"'-dimethylallyl)-8-(3",3"-dimethylallyl)-2'-me…

Fungal Biology and ApplicationsPhytochemical compounds biological activitiesPhytochemistry and Bioactive Compounds

Resonant Raman scattering measurements of strains in ZnS epilayers grown on GaP

Young‐Moon Yu、Myung Ho Hyun、S. Nam 等 8 位作者2002-06-01Journal of Applied Physics

The relaxation of strain in the ZnS epilayers grown on (100) GaP was investigated with resonant Raman scattering measurement. The single LO phonon resonant Raman shift and the intensity increased but the full width at half maximum decreased with the increasing ZnS epilayer thickness. These were attributed to the relax…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films