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Polyamide 66/Clay Nanocomposites via Melt Intercalation

Xiaohui Liu、Qiuju Wu2002-03-01Macromolecular Materials and Engineering

Polyamide 66/clay nanocomposites (PA66CN) were prepared via a melt compounding method using a new kind of organophilic clay, which was obtained through co-intercalation of epoxy resin and quaternary ammonium into Na-montmorillonite. The dispersion effect of silicate layers in the matrix was studied by means of XRD and…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersTribology and Wear Analysis

Characteristics of Near-Neutral-pH Stress Corrosion Cracks in an X-65 Pipeline

W. Chen、Fraser King、E. Vokes2002-03-01CORROSION

Two patches of near-neutral-pH stress corrosion cracks (SCC), as developed on a pipeline steel during service, have been characterized. The two patches can be characterized as containing either dense cracks or sparse cracks, based on their spatial separation. Cracks from both patches were categorized as either linked…

Hydrogen embrittlement and corrosion behaviors in metalsEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Numerical Simulation of 3D Dynamic Garment Pressure

X. Zhang、K.W. Yeung、Yi Li2002-03-01Textile Research Journal

This paper presents a mechanical model for numerical simulations of 3D dynamic garment pressure during wear using a finite element method. Based on analyzing the contact characteristics between the human body and the garment, a mechanical model is developed based on the theory of dynamic contact mechanics. The garment…

Textile materials and evaluationsMechanical stress and fatigue analysisContact Mechanics and Variational Inequalities

Exploring and Expanding the Three-Dimensional Structural Diversity of Supramolecular Dendrimers with the Aid of Libraries of Alkali Metals of Their AB3 Minidendritic Carboxylates

Virgil Percec、Marian N. Holerca、Satoshi Uchida 等 7 位作者2002-03-01Chemistry - A European Journal

The synthesis of the alkali metal salts of 3,4,5-tris(n-alkan-1-yloxy)benzoic acid [(3,4,5)nG1-CO(2)M, where n is the number of methylenic units in the alkane group for n=12, 14, 16, 18 and M=Li, Na, K, Rb, Cs] is described. The structural analysis of these AB(3) molecules by a combination of methods which includes X-…

Supramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Temperature-Induced Extended Helix/Random Coil Transitions in a Group 1 Late Embryogenesis-Abundant Protein from Soybean

José L. Soulages、Kang Min Kim、Christina Walters 等 4 位作者2002-03-01PLANT PHYSIOLOGY

Group 1 late embryogenesis-abundant (LEA) proteins are a subset of hydrophilins that are postulated to play important roles in protecting plant macromolecules from damage during freezing, desiccation, or osmotic stress. To better understand the putative functional roles of group 1 LEA proteins, we analyzed the structu…

Proteins in Food SystemsSeed Germination and PhysiologyEnzyme Structure and Function

Semiconductor spintronics

Hiroyuki Akinaga、Hideo Ohno2002-03-01IEEE Transactions on Nanotechnology

We review recent progress made in the field of semiconductor spintronics, a branch of semiconductor electronics where both charge and spin degrees of freedom play an important role in realizing unique functionalities. We first describe the new spin-dependent phenomena found in semiconductors including carrier-induced…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Percutaneous Tumor Ablation: Increased Necrosis with Combined Radio-frequency Ablation and Intravenous Liposomal Doxorubicin in a Rat Breast Tumor Model

S. Nahum Goldberg、Geoffrey D. Girnan、Anatoly N. Lukyanov 等 12 位作者2002-03-01Radiology

PURPOSE: To determine whether a combination of intravenous liposomal doxorubicin and radio-frequency (RF) ablation increases tumor destruction compared with RF alone in an animal tumor model. MATERIALS AND METHODS: R3230 mammary adenocarcinoma 1.4-1.8-cm- diameter nodules were implanted subcutaneously in 132 female Fi…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsUltrasound and Hyperthermia Applications

Effect of degumming on the tensile properties of silkworm (Bombyx mori) silk fiber

José Pérez‐Rigueiro、M. Elices、Javier LLorca 等 4 位作者2002-03-01Journal of Applied Polymer Science

Abstract Forcibly reeled silkworm ( Bombyx mori ) silk was used to study how exposure to a degumming treatment (boiling in distilled water for 30 min) affects tensile properties. Because forcibly reeled and naturally spun fibers exhibit comparable mechanical behavior, the results can be generalized to material obtaine…

Viral Infectious Diseases and Gene Expression in InsectsSilk-based biomaterials and applicationsSilkworms and Sericulture Research

Soil and Litter Phosphorus‐31 Nuclear Magnetic Resonance Spectroscopy

B.J. Cade‐Menun、C. W. Liu、Rudi Nunlist 等 4 位作者2002-03-01Journal of Environmental Quality

Phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy is an excellent tool with which to study soil organic P, allowing quantitative, comparative analysis of P forms. However, for 31P NMR to be tative, all peaks must be completely visible, and in their correct relative proportions. There must be no line broadeni…

Soil Carbon and Nitrogen DynamicsClay minerals and soil interactionsIron oxide chemistry and applications

X-ray photoelectron spectroscopy and high resolution electron microscopy studies of Aurivillius compounds: Bi4−xLaxTi3O12(x=0, 0.5, 0.75, 1.0, 1.5, and 2.0)

Ming‐Wen Chu、M. Ganne、Maria Teresa Caldés 等 4 位作者2002-03-01Journal of Applied Physics

In order to determine the fatigue-free origin of the ferroelectric Bi3.25La0.75Ti3O12, a series of x-ray photoelectron spectroscopy and high resolution electron microscopy studies were performed on the polycrystalline Bi4−xLaxTi3O12 (BLTx, x=0, 0.5, 0.75, 1.0, 1.5, and 2.0) powders. From the XPS study, the surfaces of…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Smooth and high-rate reactive ion etching of diamond

Yutaka Ando、Yoshiki Nishibayashi、Koji Kobashi 等 5 位作者2002-03-01Diamond and Related Materials

Diamond surfaces with patterned Al masks were etched by a reactive ion etching (RIE) system under conditions that the RF power was 100–280 W, the CF 4 /O 2 ratio was 0–12.5% and the gas pressure 2–40 Pa. It was found that the roughness of the etched diamond surface decreased with an increase in the CF 4 /O 2 ratio, al…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Cross Sections for Low-Energy (10 – 50 eV) Electron Damage to DNA

Badia Boudaı̈ffa、Pierre Cloutier、D. J. Hunting 等 5 位作者2002-03-01Radiation Research

We report direct measurements of the formation of single-, double- and multiple strand breaks in pure plasmid DNA as a function of exposure to 10-50 eV electrons. The effective cross sections to produce these different types of DNA strand breaks were determined and were found to range from approximately 10(-17) to 3 x…

Atomic and Molecular PhysicsElectron and X-Ray Spectroscopy TechniquesRadiation Effects and Dosimetry

Cellular Uptake Studies with -Peptides

Magnus Rueping、Yogesh R. Mahajan、Markus Sauer 等 4 位作者2002-03-01ChemBioChem

Translocation across the membrane into cells is possible for certain peptides and proteins. To investigate the structural requirements of β-peptides for this process, a series of fluorescein-labeled β-peptides has been synthesized and their cellular uptake into 3T3 mouse fibroblast cells determined by fluorescence mic…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsClick Chemistry and Applications

High-Resolution Simulation of Multidimensional Crystal Growth

Laurent David、Danesh K. Tafti、Richard D. Braatz2002-03-01Industrial & Engineering Chemistry Research

Many of the crystals in the pharmaceuticals, photographic, and other industries are multidimensional; that is, their growth is associated with the change of multiple internal coordinates. The main governing equation for such systems is a highly nonlinear multidimensional population balance equation that must be solved…

Coagulation and Flocculation StudiesCrystallization and Solubility StudiesThermal and Kinetic Analysis

Three-Dimensional Cubic Mesoporous Structures of SBA-12 and Related Materials by Electron Crystallography

Yasuhiro Sakamoto、Isabel Dı́az、Osamu Terasaki 等 7 位作者2002-03-01The Journal of Physical Chemistry B

The chemical potential difference between homopolymer fractions in block copolymers can be readily used to selectively design, and cooperatively assemble, inorganic species into highly ordered three-dimensional (3d) periodic composite arrays of separated mesoscale regions. The actual details and symmetry of these regi…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Proof of the Double Bubble Conjecture

Michael Hutchings、Frank Morgan、Manuel Ritoré 等 4 位作者2002-03-01Annals of Mathematics

We prove that the standard double bubble provides the least-area way to enclose and separate two regions of prescribed volume in R 3 .

Pickering emulsions and particle stabilization

Submicron x-ray diffraction and its applications to problems in materials and environmental science

Nobumichi Tamura、Richard Celestre、Alastair A. MacDowell 等 9 位作者2002-03-01Review of Scientific Instruments

The availability of high brilliance third generation synchrotron sources together with progress in achromatic focusing optics allows us to add submicron spatial resolution to the conventional century-old x-ray diffraction technique. The new capabilities include the possibility to map in situ, grain orientations, cryst…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Phase equilibria and glass transition in colloidal systems with short-ranged attractive interactions: Application to protein crystallization

Giuseppe Foffi、Gavin D. McCullagh、Aonghus Lawlor 等 9 位作者2002-03-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We have studied a model of a complex fluid consisting of particles interacting through a hard-core and short-range attractive potential of both Yukawa and square-well form. Using a hybrid method, including a self-consistent and quite accurate approximation for the liquid integral equation in the case of the Yukawa flu…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Saddle points and dynamics of Lennard-Jones clusters, solids, and supercooled liquids

Jonathan P. K. Doye、David J. Wales2002-03-01The Journal of Chemical Physics

The properties of higher-index saddle points have been invoked in recent theories of the dynamics of supercooled liquids. Here we examine in detail a mapping of configurations to saddle points using minimization of |∇E|2, which has been used in previous work to support these theories. The examples we consider are a tw…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

PLASMON MODES IN METAL NANOWIRES AND LEFT-HANDED MATERIALS

Viktor A. Podolskiy、Andrey K. Sarychev、Vladimir M. Shalaev2002-03-01Journal of Nonlinear Optical Physics & Materials

The electromagnetic field distribution for thin metal nanowires is found, by using the discrete dipole approximation. The plasmon polariton modes in wires are numerically simulated. These modes are found to be dependent on the incident light wavelength and direction of propagation. The existence of localized plasmon m…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications