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Modulated microstructure in synthetic majorite

Yanbin Wang、Tibor Gasparik、Robert C. Liebermann1993-12-01American Mineralogist

Transmission electron microscopy on Mg-end member majorite crystals synthesized at 22 GPa and above 2350°C reveals a modulated microstructure, characterized by mutually intersecting linear contrasts parallel to the tetragonal {101} planes, with a typical wavelength of the modulation between 150 and 300 A. Streaking pe…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Development of a non‐isothermal method for determination of diffusional parameters

LÍLIA ANDRÉ MOREIRA、F.A.R. Oliveira、TERESA R. SILVA 等 4 位作者1993-12-01International Journal of Food Science & Technology

Summary A non‐isothermal method for determination of diffusional parameters was developed. the dependence of diffusivity on temperature was described by an Arrhenius type equation, with the pre‐exponential factor and the activation energy as parameters. These parameters were obtained by optimization of the fit between…

Thermochemical Biomass Conversion ProcessesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Classification of the solubility behaviour of β‐cyclodextrin in aqueous–CO‐solvent mixtures

Anthony W. Coleman、M. Munoz、Alexis K. Chatjigakis 等 4 位作者1993-12-01Journal of Physical Organic Chemistry

Abstract The solubility behaviour of β‐cyclodextrin in aqueous mixtures was studied by determining the interactions between the co‐solvent and water. Three clear classes of co‐solvent are evident. In the first, including ethanol, tetrahydrofuran and acetone, there is formation of clathrate hydrates by the co‐solvent.…

Drug Solubulity and Delivery SystemsProcess Optimization and IntegrationCrystallization and Solubility Studies

Network structure of RO·2B2O3 glasses

Y. Akasaka、Itaru Yasui、Tokuro Nanba1993-12-01Physics and chemistry of glasses

A factor which determines the network structure of diborate glasses containing divalent cations was proposed on the basis of structural studies by a combination of diffraction methods (x-ray and neutron), computer simulation and Raman spectroscopy. Structural analysis revealed that the network of Ba0.2B 2 O 3 and Pb0.…

Glass properties and applicationsPhase-change materials and chalcogenidesMineralogy and Gemology Studies

Variations in the copper(I)-copper(I) distances in multinuclear clusters with identical coordination geometries. Short metal-metal contacts induced by oligomerization

Santosh P. Abraham、Ashoka G. Samuelson、Jayaraman Chandrasekhar1993-12-01Inorganic Chemistry

Factors contributing to the variations in the Cu(I)-Cu(I) distances in two clusters with identical ligand and coordination geometries have been analyzed. While the hexamer, 4, exhibits metal-metal distances in the range 2.81-3.25 Angstrom, shorter contacts are found in the corresponding tetramer, 3 (2.60-2.77 Angstrom…

Magnetism in coordination complexesNanocluster Synthesis and ApplicationsChemical Thermodynamics and Molecular Structure

Fragipan formation in argillic brown earths (Fragiudalfs) of the Milfield Plain, north‐east England. III. Micromorphological, SEM and EDXRA studies of fragipan degradation and the development of glossic features

Robert Payton1993-12-01Journal of Soil Science

SUMMARY The micromorphology of eluvial and glossic areas with weak soi1, strength from the upper fragipan, and the upper parts of grey polygonal zones, in some argillic brown earths (Glossic Fragiudalfs) from north‐east England shows unstable void walls stripped of clay with remnants of ferri‐argillans, pale grey grai…

Geological and Geochemical AnalysisGeochemistry and Elemental AnalysisClay minerals and soil interactions

Die-upset PrCo5-type magnets from melt-spun ribbons

C. D. Fuerst、E. G. Brewer1993-12-01Journal of Applied Physics

We used consolidation (hot pressing) and deformation (die upsetting) techniques to produce magnetically anisotropic permanent magnets from melt-spun PryCo100−y−xCx alloys. The primary phase in these magnets (16≤y≤24 at. %) was the hexagonal PrCo5 phase. The greatest alignment was obtained for low-carbon compositions (…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Effects of Anodization Temperature on Photoluminescence from Porous Silicon

Hiroshi Ono、H. Gomyou、Hiroshi Morisaki 等 8 位作者1993-12-01Journal of The Electrochemical Society

The effects of anodization temperature on the photoluminescence (PL) spectrum of porous silicon (Si) have been studied. The luminescence intensity increases exponentially and the peak wavelength decreases monotonically with increasing anodization temperature during formation of pores on Si. The PL intensity increases…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnodic Oxide Films and Nanostructures

Desorption Kinetics of Radionuclides Fixed in Cement Matrix

T.M. Krishnamoorthy、S. N. Joshi、G.R. Doshi 等 4 位作者1993-12-01Nuclear Technology

Leach characteristics of some typical nuclides such as cesium, strontium, cobalt, I−, and CO3−2 from ordinary portland cement waste forms have been studied using the ISO test method and radiotracers of the respective nuclides, i.e., 134Cs, 85Sr, 60Co, 131I, and 14C. The leach studies suggest a rapid release of radioac…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Linear viscoelastic diffusion in the polystyrene/ethylbenzene system: differential sorption experiments

Gerry F. Billovits、C. J. Durning1993-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLinear viscoelastic diffusion in the polystyrene/ethylbenzene system: differential sorption experimentsG. F. Billovits and C. J. DurningCite this: Macromolecules 1993, 26, 25, 6927–6936Publication Date (Print):December 1, 1993Publication History Published online1 May 2002Pub…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Probing the influence of local coordination environment on ligand binding in nickel hydrogenase model complexes

Mikyung Cha、Christine L. Gatlin、Susan C. Critchlow 等 4 位作者1993-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProbing the influence of local coordination environment on ligand binding in nickel hydrogenase model complexesMikyung Cha, Christine L. Gatlin, Susan C. Critchlow, and Julie A. KovacsCite this: Inorg. Chem. 1993, 32, 25, 5868–5877Publication Date (Print):December 1, 1993Pub…

Electrocatalysts for Energy ConversionHydrogen Storage and MaterialsMetalloenzymes and iron-sulfur proteins

Changes in properties of rigid PVC during weathering

Elvira B. Rabinovitch、James W. Summers、William E. Northcott1993-12-01Journal of Vinyl Technology

Abstract Changes in properties of PVC compounds upon weathering are categorized as due to physical aging or due to chemical change. PVC's tensile strength, flexural strength, tensile modulus, and flexural modulus generally rise slightly with weathering. DSC data on weathered samples show an annealing effect identical…

Polymer crystallization and propertiesMaterial Properties and ProcessingPolymer Science and PVC

Supramolecular photochemistry of crystalline host-guest assemblies: absolute asymmetric photorearrangement of the host component

Tai Y. Fu、Zhaoqing Liu、John R. Scheffer 等 4 位作者1993-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSupramolecular photochemistry of crystalline host-guest assemblies: absolute asymmetric photorearrangement of the host componentTai Y. Fu, Zhaoqing Liu, John R. Scheffer, and James TrotterCite this: J. Am. Chem. Soc. 1993, 115, 25, 12202–12203Publication Date (Print):Decembe…

Metal-Organic Frameworks: Synthesis and ApplicationsPhotochemistry and Electron Transfer StudiesPolyoxometalates: Synthesis and Applications

Lattice-dynamical study of the premartensitic state of the Cu-Al-Be alloys

Lluı́s Mañosa、J. L. Zarestky、T. A. Lograsso 等 5 位作者1993-12-01Physical review. B, Condensed matter

Neutron-scattering techniques have been used to study the premartensitic state of a family of Cu-Al-Be alloys, which transform from the bcc phase to an 18R martensitic structure. We find that the phonon modes of the ${\mathrm{TA}}_{2}$[110] branch have very low energies with anomalous temperature dependence. A slight…

Microstructure and mechanical propertiesIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Density-functional theory of nonuniform classical liquids: An extended modified weighted-density approximation

Christos N. Likos、N. W. Ashcroft1993-12-01The Journal of Chemical Physics

An extension of the modified weighted-density approximation (MWDA) is presented which retains the key features of the original MWDA in that it continues to describe the nonuniform system through the use of low-order correlation functions of the uniform counterpart. However, the approximate free energy functional is no…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Depolarization in liquid-crystal televisions

J. Larry Pezzaniti、Stephen C. McClain、Russell A. Chipman 等 4 位作者1993-12-01Optics Letters

Get PDF Email Share Share with Facebook Tweet This Post on reddit Share with LinkedIn Add to CiteULike Add to Mendeley Add to BibSonomy Get Citation Copy Citation Text J. Larry Pezzaniti, Stephen C. McClain, Russell A. Chipman, and Shih-Yau Lu, "Depolarization in liquid-crystal televisions," Opt. Lett. 18, 2071-2073 (…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesOptical Polarization and Ellipsometry

As-Sb Exchange Energies in Tetrahedrite-Tennantite Fahlores and Bournonite-Seligmannite Solid Solutions

Richard O. Sack、D. S. Ebel1993-12-01Mineralogical Magazine

Abstract Reversed brackets on As and Sb partitioning between tetrahedrite-tennantite fahlores {∼CU 10 (Fe,Zn) 2 (Sb,As) 4 S 13 } and bournonite-seligmannite solid solutions {CuPb(Sb,As)S 3 } (400°C evacuated silica tubes, NH 4 Cl flux) indicate that the maximum nonidealities associated with the As-Sb substitution are…

Glass properties and applicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Preparation, characterization, and reactions of novel iron(III) porphyrin dication complexes

H. Tsurumaki、Yoshihito Watanabe、Isao Morishima1993-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation, characterization, and reactions of novel iron(III) porphyrin dication complexesHiroshi Tsurumaki, Yoshihito Watanabe, and Isao MorishimaCite this: J. Am. Chem. Soc. 1993, 115, 25, 11784–11788Publication Date (Print):December 1, 1993Publication History Published…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

An Efficient Method for The Preparation of w, w′-bis-Urethane Protected Arginine Derivatives

Youling Wu、Gary R. Matsueda、Michael S. Bernatowicz1993-12-01Synthetic Communications

Fmoc-Argw, w′(Boc)2-OH and Boc-Argw, w′(Cbz)2-OH were prepared in two steps: Guanylation of Cu(II)-ornithine complex at Nδ with N, N′bis-urethane protected derivatives of 1-guanylpyrazole, followed by Nα-protection using either 9-fluorenylmethyl succinimidylcarbonate or di-t-butyl-dicarbonate in the presence of EDTA.…

biodegradable polymer synthesis and propertiesChemical Synthesis and AnalysisAntimicrobial agents and applications

Surface Modification of Polypropylene Fabrics by Acrylonitrile Cold Plasma

A. Majid Sarmadi、Ting‐Ting Ying、Ferencz S. Denes1993-12-01Textile Research Journal

Polypropylene fabrics were extracted with carbontetrachloride and acetone by Soxhlet extraction, and then PPAN ( plasma polymerized acrylonitrile ) was grafted to the surface of the extracted fabrics using a ground pressure of 0.05 mm Hg, 0.3 mm Hg pressure in the reactor, 60 W and 100 W RF power, and reaction times o…

Graphene research and applicationsSurface Modification and SuperhydrophobicityDiamond and Carbon-based Materials Research