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Rheological, thermal, and morphological properties of low‐density polyethylene/ultra‐high‐molecular‐weight polyethylene and linear low‐density polyethylene/ultra‐high‐molecular‐weight polyethylene blends

Zhengguang Heng、Huawei Zou、Mei Liang 等 4 位作者2012-09-28Journal of Applied Polymer Science

Abstract The dynamic rheological behavior of low‐density polyethylene (LDPE)/ultra‐high‐molecular‐weight polyethylene (UHMWPE) blends and linear low‐density polyethylene (LLDPE)/UHMWPE blends was measured in a parallel‐plate rheometer at 180, 190, and 200°C. Analysis of the log–additivity rule, Cole–Cole plots, Han cu…

Polymer Nanocomposites and PropertiesRheology and Fluid Dynamics StudiesPolymer crystallization and properties

Direct Imaging of Complex Nano- to Microscale Interfaces Involving Solid, Liquid, and Gas Phases

Konrad Rykaczewski、Trevan Landin、Marlon L. Walker 等 5 位作者2012-09-28ACS Nano

Surfaces with special wetting properties not only can efficiently repel or attract liquids such as water and oils but also can prevent formation of biofilms, ice, and clathrate hydrates. Predicting the wetting properties of these special surfaces requires detailed knowledge of the composition and geometry of the inter…

nanoparticles nucleation surface interactionsIon-surface interactions and analysisSurface Modification and Superhydrophobicity

Extrusion of humidity‐resistant starch foam sheets

Zhiguan Yang、Daniel Graiver、Ramáni Narayan2012-09-28Polymer Engineering and Science

Abstract An annular die is used to extrude cylindrical starch foams which are then sliced to yield foam sheets suitable for cushioning protection and insulation of shipping containers. Although starch foams, as a possible replacement of petroleum‐based foams, have been prepared in the past, their sensitivity to humidi…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Foaming and Composites

Electrical conductivity of poly(ethylene terephthalate)/expanded graphite nanocomposites prepared by in situ polymerization

Sandra Paszkiewicz、Anna Szymczyk、Zdenko Špitálský 等 7 位作者2012-09-28Journal of Polymer Science Part B Polymer Physics

Abstract Nanocomposites based on poly(ethylene terephthalate) (PET) and expanded graphite (EG) have been prepared by in situ polymerization. Morphology of the nanocomposites has been examined by electronic microscopy. The relationship between the preparation method, morphology, and electrical conductivity was studied.…

Carbon Nanotubes in CompositesAdvancements in Battery MaterialsGraphene research and applications

EFFECT OF DEGREE OF DEACETYLATION OF CHITOSAN ON THERMAL STABILITY AND COMPATIBILITY OF CHITOSAN-POLYAMIDE BLEND

Zainoha Zakaria、Zatil Izzah、Mohammad Jawaid 等 4 位作者2012-09-28BioResources

The effect of the degree of deacetylation of chitosan on the chemical structure, thermal properties, and compatibility of chitosan/polyamide66 (CS/PA66) blends were investigated. Blends of CS with PA66 were prepared via the solution casting technique by using 85% formic acid. Structural interaction between PA66, CS, a…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsNanocomposite Films for Food Packaging

Onset Mechanism of Strain-Rate-Induced Flow Stress Upturn

Yue Fan、Yuri N. Osetsky、Sidney Yip 等 4 位作者2012-09-28Physical Review Letters

The strain-rate response of flow stress in a plastically deforming crystal is formulated through a stress-sensitive dislocation mobility model that can be evaluated by atomistic simulation. For the flow stress of a model crystal of bcc Fe containing a 1/2[111] screw dislocation, this approach describes naturally a non…

Erosion and Abrasive MachiningHigh-Velocity Impact and Material BehaviorLaser-Plasma Interactions and Diagnostics

Glucan Adsorption on Mesoporous Carbon Nanoparticles: Effect of Chain Length and Internal Surface

Po‐Wen Chung、Alexandre Charmot、Oz M. Gazit 等 4 位作者2012-09-28Langmuir

The adsorption of cellulose-derived long-chain (longer than ten glucose repeat units on size) glucans onto carbon-based acid catalysts for hydrolysis has long been hypothesized; however, to date, there is no information on whether such adsorption can occur and how glucan chain length influences adsorption. Herein, in…

Biofuel production and bioconversionSupercapacitor Materials and FabricationCatalysis for Biomass Conversion

Low Energy Neutron Production by Inverse-beta decay in Metallic Hydride Surfaces

S. Ciuchi、L. Maiani、A. D. Polosa 等 6 位作者2012-09-28arXiv

It has been recently argued that inverse-beta nuclear transmutations might occur at an impressively high rate in a thin layer at the metallic hydride surface under specific conditions. In this note we present a calculation of the transmutation rate which shows that there is little room for such a remarkable effect.

Materials Sciencenucl-th

Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain

X. Moya、L. E. Hueso、F. Maccherozzi 等 14 位作者2012-09-28arXiv

Large thermal changes driven by a magnetic field have been proposed for environmentally friendly energy efficient refrigeration, but only a few materials which suffer hysteresis show these giant magnetocaloric effects. Here we create giant and reversible extrinsic magnetocaloric effects in epitaxial films of the ferro…

Materials Science

Influence of monolayer contamination on electric-field-noise heating in ion traps

A. Safavi-Naini、E. Kim、P. F. Weck 等 5 位作者2012-09-28arXiv

Electric field noise is a hinderance to the assembly of large scale quantum computers based on entangled trapped ions. Apart from ubiquitous technical noise sources, experimental studies of trapped ion heating have revealed additional limiting contributions to this noise, originating from atomic processes on the elect…

Materials Sciencequant-ph

Oxygen Vacancy-Assisted Coupling and Enolization of Acetaldehyde on CeO2(111)

Florencia Calaza、Ye Xu、David R. Mullins 等 4 位作者2012-09-28Journal of the American Chemical Society

The temperature-dependent adsorption and reaction of acetaldehyde (CH(3)CHO) on a fully oxidized and a highly reduced thin-film CeO(2)(111) surface have been investigated using a combination of reflection-absorption infrared spectroscopy (RAIRS) and periodic density functional theory (DFT+U) calculations. On the fully…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Novel high performance tough hyperbranched epoxy by an A 2 + B 3 polycondensation reaction

Bibekananda De、Niranjan Karak2012-09-28Journal of Materials Chemistry A

High performance tough epoxy thermoset with excellent adhesive strength is one of the most in demand materials for advanced engineering applications. In the present investigation three hyperbranched epoxy resins with varying compositions were synthesized by a single step controlled polycondensation reaction using an A…

Synthesis and properties of polymersEpoxy Resin Curing ProcessesDendrimers and Hyperbranched Polymers

Piezochromic Luminescence Based on the Molecular Aggregation of 9,10‐Bis((E)‐2‐(pyrid‐2‐yl)vinyl)anthracene

Yujie Dong、Bin Xu、Jibo Zhang 等 12 位作者2012-09-28Angewandte Chemie

Ein Chamäleon unter Druck: Das beobachtete piezochrome Verhalten der Titelverbindung (BP2VA) hängt von ihrem molekularen Aggregationszustand ab, insbesondere von der Stärke der π-π-Wechselwirkung zwischen den Anthracenringen benachbarter Moleküle. Beim Zermahlen von BP2VA oder bei der Einwirkung von Druck ändert die V…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Radiation effects on the electronic properties of bilayer graphene

Eric Suárez Morell、L E F Foa Torres2012-09-28Physical Review B

We report on the effects of laser illumination on the electronic properties of bilayer graphene. By using Floquet theory combined with Green's functions, we unveil the appearance of laser-induced gaps not only at integer multiples of $\ensuremath{\hbar}\ensuremath{\Omega}/2$ but also at the Dirac point with features w…

Topological Materials and PhenomenaGraphene research and applicationsMetamaterials and Metasurfaces Applications

Topological insulators from the Perspective of first-principles calculations

Haijun Zhang、Shou-Cheng Zhang2012-09-28arXiv

Topological insulators are new quantum states with helical gapless edge or surface states inside the bulk band gap.These topological surface states are robust against the weak time-reversal invariant perturbations, such as lattice distortions and non-magnetic impurities. Recently a variety of topological insulators ha…

Mesoscale and Nanoscale PhysicsMaterials Science

Two Distinct Phases of Bilayer Graphene Films on Ru(0001)

Marco Papagno、Daniela Pacilé、Dinesh Topwal 等 17 位作者2012-09-28ACS Nano

By combining angle-resolved photoemission spectroscopy and scanning tunneling microscopy we reveal the structural and electronic properties of multilayer graphene on Ru(0001). We prove that large ethylene exposure allows the synthesis of two distinct phases of bilayer graphene with different properties. The first phas…

Topological Materials and PhenomenaSurface and Thin Film PhenomenaGraphene research and applications

Pseudo-potentials based first-principles approach to the magneto-optical Kerr effect: from metals to the inclusion of local fields and excitonic effects

Davide Sangalli、Andrea Marini、Alberto Debernardi2012-09-28arXiv

We propose a first-principles scheme for the description of the magneto-optical kerr effect within density functional theory (DFT). Though the computation of Kerr parameters is often done within DFT, starting from the conductivity or the dielectric tensor, there is no formal justification to this choice. As a first st…

Materials ScienceStrongly Correlated Electrons

Multiple Quantum Phase Transitions at the superconducting LaTiO3/SrTiO3 interface

J. Biscaras、N. Bergeal、S. Hurand 等 9 位作者2012-09-28arXiv

We study the magnetic field driven Quantum Phase Transition (QPT) in electrostatically gated superconducting LaTiO3/SrTiO3 interfaces. Through finite size scaling analysis, we show that it belongs to the (2+1)D XY model universality class. The system can be described as a disordered array of superconducting islands co…

Materials ScienceStrongly Correlated ElectronsSuperconductivity

The formation of Er-oxide nanoclusters in SiO$_2$ thin films with excess Si

Annett Thøgersen、Jeyanthinath Mayandi、Terje Finstad 等 7 位作者2012-09-28arXiv

The nucleation, distribution and composition of erbium embedded in a SiO$_2$-Si layer were studied with High Resolution Transmission Electron Microscopy (HRTEM), Electron Energy Loss Spectroscopy (EELS), Energy Filtered TEM (EFTEM), Scanning Transmission Electron Microscopy (STEM) and X-ray Photoelectron Spectroscopy…

Materials ScienceMesoscale and Nanoscale Physics