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Molecular dynamics of star‐shaped poly(L‐lactide)s in tetrahydrofuran as solvent monitored by fluorescence spectroscopy

Martin Danko、Jan Libiszowski、Tadeusz Biela 等 5 位作者2005-08-24Journal of Polymer Science Part A Polymer Chemistry

Abstract Linear telechelic, α,ω‐ditelechelic, and star‐shaped tri‐, tetra‐, penta‐, and hexa‐arm poly( L ‐lactide)s (PLAs) fitted at every arm with pyrene end group have been prepared. Internal dynamics and mobility of the PLA chains in tetrahydrofuran solution at 25 °C, with regard to the number of PLA arms in one ma…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Medical and welfare applications of shape memory alloy microcoil actuators

Yoichi Haga、Masaru Mizushima、Takuya Matsunaga 等 4 位作者2005-08-24Smart Materials and Structures

We have successfully developed several mechanisms using Ti–Ni shape memory alloy (SMA) microcoil actuators, for example, a bending mechanism, an extension/contraction mechanism, a torsional mechanism and a stiffness control mechanism. The principles involved in these mechanisms and the structure of each mechanism are…

Shape Memory Alloy Transformations

Mechanical behavior of gold nanowires with a multishell helical structure

Jenn-Sen Lin、Shin‐Pon Ju、Wen‐Jay Lee2005-08-24Physical Review B

Mechanical behavior of multishell gold nanowires has been carried out by molecular dynamics simulation. This work studies the mechanical properties of three types of multishell helical structure, i.e., 7-1, 11-4, and 14-7-1. The results reveal that the Young's modulus increases as the radius of the nanowire decreases.…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsAnodic Oxide Films and Nanostructures

Structural phase transition in [NH3(CH2)5NH3]BiCl5: thermal and vibrational studies

H. Jeghnou、A. Ouasri、A. Rhandour 等 7 位作者2005-08-24Journal of Raman Spectroscopy

Abstract An x‐ray diffraction study carried out on the pentylenediammonium pentachlorobismuthate (III) compound [NH 3 (CH 2 ) 5 NH 3 ]BiCl 5 indicated that it is orthorhombic with a P 2 1 2 1 2 1 (Z = 4) space group. Differential scanning calorimetry (DSC), differential thermal analysis (DTA) and thermogravimetric ana…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Micro-Optics for Liquid Crystal Displays Applications

H.-P.D. Shieh、Y.-P. Huang、Kai-Ting Chien2005-08-24Journal of Display Technology

Micro-optics have become the key technology in liquid crystal display systems due to its capabilities of miniaturization and design flexibility. Design consideration and experimental results of microoptical components for enhancing the image quality, providing better functions, increasing light efficiency, and generat…

Photonic and Optical DevicesAdvanced optical system designOptical Coatings and Gratings

Core−Shell Polymer Nanoparticles for Baroplastic Processing

Juan A. González-León、Sang‐Woog Ryu、Sheldon Hewlett 等 5 位作者2005-08-24Macromolecules

Core−shell polymer nanoparticles consisting of a low glass transition temperature ( T g ) core of poly( n -butyl acrylate) or poly(2-ethylhexyl acrylate) and a glassy polystyrene shell were synthesized by two-stage emulsion polymerization. The obtained materials exhibit pressure-induced mixing of their components and…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

Quantitative analysis of fibrosis formation on the microcapsule surface with the use of picro‐sirius red staining, polarized light microscopy, and digital image analysis

Hua'an Zhang、Lin Sun、Wei Wang 等 4 位作者2005-08-24Journal of Biomedical Materials Research Part A

Transplantation of microencapsulated cells shows potential to treat a variety of diseases. To improve the quality of microcapsules, efficient methods need to be established and standardized for the evaluation of biocompatibility of microcapsules. To this end, a microscopical method was developed to analyze quantitativ…

Electrospun Nanofibers in Biomedical ApplicationsPancreatic function and diabetesTissue Engineering and Regenerative Medicine

Supercritical Fluid Processing of Thermally Stable Mesoporous Titania Thin Films with Enhanced Photocatalytic Activity

Kaixue Wang、Baodian Yao、Michael A. Morris 等 4 位作者2005-08-24Chemistry of Materials

Employing triblock copolymers as structural directing agents, high-quality mesostructured titania thin films have been prepared on silicon substrates by spin coating. Post-treatment of the films in supercritical carbon dioxide, in the presence of small amounts of either tetraisopropoxide, tetramethoxysilane, or other…

TiO2 Photocatalysis and Solar CellsCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Structural, Optical, and Photophysical Properties of Nickel(II) Alkylthioporphyrins: Insights from Experimental and DFT/TDDFT Studies

Angela Rosa、Giampaolo Ricciardi、Evert Jan Baerends 等 7 位作者2005-08-24Inorganic Chemistry

The ground- and excited-state properties of a Ni(II) porphyrin bearing peripheral alkylthio group, NiOMTP (OMTP = 2,3,7,8,12,13,17,18-octakis methylthio porphyrinate) have been investigated by steady-state and time-resolved absorption spectrometry and DFT/TDDFT theoretical methods. Several conformations corresponding…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesMetal-Catalyzed Oxygenation Mechanisms

On the effect of aging on martensitic transformations in Ni-rich NiTi shape memory alloys

Gunther Eggeler、Jafar Khalil‐Allafi、S. Gollerthan 等 6 位作者2005-08-24Smart Materials and Structures

We investigate the effect of 450 °C aging on the microstructure and on the martensitic transformations in a Ni-rich (50.8 at.% Ni) NiTi shape memory alloy using transmission electron microscopy (TEM), x-ray diffraction (XRD), neutron diffraction (ND) and differential scanning calorimetry (DSC). On cooling from the hig…

Shape Memory Alloy Transformations

Hydrogen-induced magnetism in carbon nanotubes

Yuchen Ma、Pekka Lehtinen、Adam S. Foster 等 4 位作者2005-08-24Physical Review B

Spin-polarized density functional theory is used to investigate hydrogen-induced magnetism in single-walled carbon nanotubes (SWNTs). Hydrogen trapped at a carbon vacancy can trigger delocalized $\ensuremath{\pi}$ electron spin polarization on semiconducting zigzag SWNTs. Hydrogen pinned by a carbon adatom on the surf…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced NMR Techniques and Applications

Magnetostrictive and shape memory properties of Fe–Pd alloys with Co and Pt additions

David Vokoun、Y W Wang、Tomasz Goryczka 等 4 位作者2005-08-24Smart Materials and Structures

Fe?~30?at.%?Pd is well known as a ferromagnetic shape memory alloy. The influence of Co and Pt additions on the shape memory and magnetostrictive behavior of Fe?Pd has been examined in the present investigation.

Shape Memory Alloy TransformationsMagnetic Properties and Applications

Brownian dynamics simulation of orientational behavior, flow-induced structure, and rheological properties of a suspension of oblate spheroid particles under simple shear

Takehiro Yamamoto、Takanori Suga、Noriyasu Mori2005-08-24Physical Review E

Brownian dynamics (BD) simulations were carried out for suspensions of oblate spheroid particles interacting via the Gay-Berne (GB) potential. The oblate spheroid particles were applied as a model of disc-like particles and the system of suspension of the particles was considered. Numerically analyzed were both the ch…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

Ferroelectricity in the guanidinium compound[C(NH2)3]4Cl2SO4: Synthesis and characterization

Marek Szafrański2005-08-24Physical Review B

A guanidinium compound, ${[\mathrm{C}{(\mathrm{N}{\mathrm{H}}_{2})}_{3}]}_{4}{\mathrm{Cl}}_{2}\mathrm{S}{\mathrm{O}}_{4}$, has been synthesized and characterized by x-ray diffraction, calorimetric, dilatometric, and dielectric measurements, and by optical examination in polarized light. At room temperature the initial…

Crystallography and molecular interactionsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Shape recovery of NiTi shape memory alloy under various pre-strain and constraint conditions

Kiyohide Wada、Yan Liu2005-08-24Smart Materials and Structures

The thermally induced shape recovery behavior of NiTi shape memory alloy (SMA) wire under constraint conditions and variable pre-strain conditions was investigated. Two kinds of deformation procedures have been performed: test (1), fixed pre-strain with variable constrained stress; and test (2), fixed constrained stre…

Shape Memory Alloy Transformations

How Far Has the Molecular Alignment of Liquid Crystals Been Elucidated?

Shoichi Ishihara2005-08-24Journal of Display Technology

Liquid crystal displays (LCDs) - born in late 1960s - have become a 45 billion-dollar industry in 2004. Today's LCD panels cover a wide range of sizes from 0.2 to 82 in diagonal. The electro-optical characteristics of any field effect LCD are determined by the orientation of its liquid crystal (LC) molecules at the di…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsForce Microscopy Techniques and Applications

New π-Extended Water-Soluble Squaraines as Singlet Oxygen Generators

Luca Beverina、Alessandro Abbotto、Mirko Landenna 等 8 位作者2005-08-24Organic Letters

[graph: see text] Condensation of squaric acid with a number of differently substituted 2-pyrrolyl derivatives afforded three new classes of squaraines. Their sharp and intense absorption bands in the biological window (700-900 nm), inherent singlet oxygen generation capabilities, together with proper functionalizatio…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Electronic structure and charge-density wave formation inLaTe1.95andCeTe2.00

K. Y. Shin、V. Brouet、N. Ru 等 5 位作者2005-08-24Physical Review B

Results are presented of complementary measurements that probe the electronic structure and charge-density wave (CDW) modulation in the quasi-two-dimensional compounds $\mathrm{La}{\mathrm{Te}}_{1.95}$ and $\mathrm{Ce}{\mathrm{Te}}_{2}$. Transmission electron micrographs show that the modulation wave vectors associate…

Rare-earth and actinide compoundsOrganic and Molecular Conductors ResearchIron-based superconductors research

Ultrawide-View Liquid Crystal Displays

Renguo Lü、Xinyu Zhu、Shin‐Tson Wu 等 5 位作者2005-08-24Journal of Display Technology

The wide viewing angle technologies for liquid crystal displays (LCDs) are reviewed. The most promising liquid crystal modes for wide view technologies, such as in-plane switching, multidomain vertical alignment, patterned vertical alignment, and advanced-super-view are compared. By optimizing the phase-compensation f…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Optical Imaging Technologies

Studies on the effect of grain refinement and thermal processing on shape memory characteristics of Cu–Al–Ni alloys

V. Sampath2005-08-24Smart Materials and Structures

Though Ni–Ti shape memory alloys are used extensively in a variety of engineering and medical applications because of their attractive shape memory characteristics, they still suffer from certain drawbacks, such as low transformation temperatures, difficulty in production and processing and high cost of raw materials.…

Shape Memory Alloy Transformations