Materials Literature
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The reaction of LnI(3) x xMeCN (Ln = Gd, Dy) and TCNE (tetracyanoethylene) in acetonitrile forms Ln(2)[C(4)(CN)(8)](3) x xMeCN. These paramagnetic light-colored solids contain the S = 0 octacyanobutandiide dianion, [C(4)(CN)(8)](2-), which upon desolvation of these products forms dark green Ln(TCNE)(3). In these compo…
While aromatic polyimides have found widespread use as high-performance polymers, the present work addressed the need for organosoluble pre-imidized materials through the use of a hyperbranching scheme. The AB 2 monomer, N -[3,5-bis(4-hydroxybenzoyl)benzene]-4-fluorophthalimide, was prepared from 4-fluoroisophthalic a…
The adsorption of l -cysteine ( l -Cys) onto a polycrystalline silver electrode surface was investigated by in situ spectroelectrochemical methods. Surface-enhanced Raman spectroscopy (SERS) and surface-enhanced second-harmonic generation (SESHG) measurements were performed in a 0.2 M KCl solution in the presence and…
A tethered triblock copolymer has been synthesized by sequential monomer addition to a self-assembled monolayer of (11-(2-bromo-2-methyl)propionyloxy)undecyltrichlorosilane. Si/SiO 2 //polystyrene- b -poly(methyl acrylate)- b -polystyrene (PS- b -PMA- b -PS) and Si/SiO 2 //PMA- b -PS- b -PMA were prepared by the “graf…
Multiwalled as well as single-walled carbon nanotubes are conveniently prepared by the pyrolysis of organometallic precursors such as metallocenes and phthalocyanines in a reducing atmosphere. More importantly, pyrolysis of organometallics alone or in mixture with hydrocarbons yields aligned nanotube bundles with usef…
An asymmetric double cantilever beam (ADCB) was utilized to determine the ability of a series of styrene and methyl methacrylate copolymers with varying architectures to compatibilize the polystyrene/poly(methyl methacrylate) interface. Diblock, triblock, pentablock, and heptablock multiblock copolymers with similar m…
Starting from a multipole expansion of intra- molecular Coulomb interactions, we present configuration interaction calculations of the molecular energy terms of the hole configurations hu^m, m=2-5, of C60^{m+} cations, of the electron configurations t1u^n, n=2-4, of the C60^{n-} anions, and of the exciton configuratio…
The path probability method (PPM) in the tetrahedron-cactus approximation is applied to the Slater-Takagi model with dipole-dipole interaction for KH2PO4-type hydrogen-bonded ferroelectric crystals in order to derive a small dip structure in the real part of dynamical susceptibility observed at the transition temperat…
We examine the alignment of thin film diblock copolymers subject to a perpendicular electric field. Two regimes are considered separately: weak segregation and strong segregation. For weakly segregated blocks and below a critical value of the field, E c, surface interactions stabilize stacking of lamellae in a directi…
The effect of the addition of CeO 2 on the structural and textural properties of TiO 2 and TiO 2 −CuO samples calcined at different temperatures was analyzed. The structural and textural transformation when the temperature of calcination was varied was followed by X-ray diffraction, Raman spectroscopy, and N 2 adsorpt…
We prepared novel transition-metal (Ti, Ta, V) oxide fibers with chiral, helical, and nanotubular structures. The nanostructured metal oxide materials were provided by the sol-gel polymerization of metal alkoxides using chiral self-assemblies of organogelators as structure-directing agents. The chiral structures of th…
The effects of strain rate, temperature and stress triaxiality on strength and ductility are studied for the three structural steels Weidox 460 E, Weldox 700 E and Weldox 900 E. The material properties are obtained from three types of tensile tests: quasi-static tests with smooth and notched specimens, quasi-static te…
Brushes of poly(ε-caprolactone) are grown by ring-opening polymerization from initiators immobilized on gold surfaces with nanometer-scale topography. Control of the thicknesses of the brushes can be exploited to tune the effect of the underlying nanometer-scale topography on the orientations of supported liquid cryst…
Abstract Blends of isotactic (natural) poly(3‐hydroxybutyrate) (PHB) and poly(methyl methacrylate) (PMMA) are partially miscible, and PHB in excess of 20 wt % segregates as a partially crystalline pure phase. Copolymers containing atactic PHB chains grafted onto a PMMA backbone are used to compatibilize phase‐separate…
The behavior of a solution of equilibrium polymers (or living polymers) at an interface is studied, using a Bethe-Guggenheim lattice model for molecules with orientation dependent interactions. The density profile of polymers and the chain length distribution are calculated. For equilibrium polymers at a nonadsorbing…
Conventional reflective displays based on either color filter/polarizer or stacked color layers suffer from their marginal performance in terms of brightness, color, and cost. In this paper, we will present new full-color reflective display architecture: Electrically Tunable Color (ETC). In this display architecture,…
A simple synthetic route to a new poly(diallylammonium) salt functionalized by a styrene group is presented. This reactive polymer was employed for polyelectrolyte multilayer films using electrostatical layer-by-layer self-assembly, together with an inorganic polyanion, namely an exfoliated hectorite clay. To enhance…
Reaction enthalpies are calculated for the hydrogenation reactions of main group hydrides with the potential for multiple bonding, and thus the unsaturated character of these species is determined. In addition to the global minimum structures, which leave in some cases no hope for even a single E-E bond (E=Group 13, 1…
Abstract A pure unsaturated cyclic ester, 6,7‐dihydro‐2(3 H )‐oxepinone (DHO2), was prepared by a new synthetic route. The copolymerization of DHO2 with ϵ‐caprolactone (ϵCL) was initiated by aluminum isopropoxide [Al(O i Pr) 3 ] at 0 °C as an easy way to produce unsaturated aliphatic polyesters with nonconjugated CC…
One of the most important reactions used for room temperature vulcanization of elastomers, hydrosilylation, was investigated by end-linking samples of vinyl-terminated poly(dimethylsiloxane) (PDMS) with silanes having number-average functionalities of 3, 4, and 40−50. The reaction was monitored through SiH consumption…