Materials Literature
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We report the controlled adsorption of individual multi- and single-walled carbon nanotubes from purified aqueous dispersions onto chemically modified silicon oxide surfaces as well as on predefined electrode patterns (100 nm electrode separation). Detailed structural investigations were performed using scanning force…
ABSTRACT Depectinized control (CTJ) and ascorbic acid treated (AAJ) apple juices were filtered through microfiltration (MF, 0.2 m) and ultrafiltration (UF, 0.02 m) ceramic tubular membranes. Under optimal conditions (8 m/s, 414 kPa and 50°C), the UF membrane resulted in higher steady state flux and less fouling than t…
An amphiphilic iron(II) complex [Fe II L 2 (NCS) 2, where L is a substituted bipyridine] exhibiting a thermal spin-crossover phenomenon around room temperature is chemically unstable at the gas−water interface. However, it forms a perfectly stable Langmuir film when formamide−water mixtures are used as a subphase. Aft…
Using a high-quality barium titanate single crystal grown by a top-seeded solution growth method, its microscopic and macroscopic symmetries were investigated by Raman scattering measurement and polarizing microscopy, respectively. Moreover, their temperature dependences through Curie temperature were also studied. As…
The pressure‐sensitive equilibrium among anorthite, quartz and the Ca‐tschermak component in clinopyroxene (CaAl 2 SiO 6 ; CaTs), CaAl 2 SiOCpx6+SiOQtz2=CaAl 2 Si 2 OPl8 (SCAn) ,can be used as a geobarometer in granulites with the proper assemblage, and has been calibrated using mineral composition data from partial m…
Mussel byssal threads contain unusual block copolymer-like proteins that combine collagen with flanking domains that resemble silk-fibroin (preCol-D) or elastin (preCol-P). These are distributed in complementary gradients along the length of the threads and as precursors in the mussel foot. We discuss a 76-kDa precurs…
We report on a laboratory study of the atmospheric corrosion of NaCl‐treated zinc in air containing different concentrations of carbon dioxide (<l, 100, 350, 1000, and 40,000 ppm). Each sample was exposed individually to synthetic atmospheres with careful control of CO 2 concentration and flow conditions. The relative…
The monotonic tension, creep, and fatigue behavior of an enhanced SiC/SiC composite was investigated at a temperature of 1300°C in air and argon. The improved creep and fatigue resistances were determined and compared to those of the standard SiC/SiC composite. The effects of additives (glass‐forming, boron‐based part…
The theoretical mechanical response of 12 cubic metals (Al, Cu, Mo, Na, Li, K, Rb, Nb, Fe, Ni, Au, and Ag) to unconstrained uniaxial loadings, coaxial with each of the three principal symmetry directions, is analyzed, at finite strain, in the framework of the embedded-atom method model calculations. The models have be…
Partial discharge tests can determine which motor and generator stator windings are experiencing insulation problems. A deteriorated winding has a PD activity which can be 30 times or more higher than a winding in good condition. This great difference in PD activity enables even nonspecialized maintenance personnel to…
The interfacial properties of SiC/SiC composites with interphases that consist of (C‐SiC) sequences deposited on the fibers have been determined by single‐fiber push‐out tests. The matrix has been reinforced with either as‐received or treated Nicalon fibers. The measured interfacial properties are correlated with the…
The chief principles and properties of optical reflection and transmission guided-mode resonance (GMR) filters are presented. These devices are based on GMR effects in dielectric structures comprising gratings and homogeneous thin films. Detailed characteristics are calculated using rigorous coupled-wave analysis for…
The behavior of piezoelectric, dielectric, and elastic characteristics of soft piezoelectric lead zirconate titanate (PZT) ceramics was investigated under sinusoidal electric field E applied along the poling direction and under mechanical stress-free conditions for a frequency range 10 Hz–10 kHz. Electrical displaceme…
Polypyrrole-based solid-state redox supercapacitors have been constructed using proton and lithium ion conducting polymer electrolytes: poly(vinyl alcohol) (PVA)–H3PO4, and poly(ethylene oxide) (PEO)–LiCF3SO3 plasticized with poly(ethylene glycol) (PEG). The capacitors have been characterized using a.c. impedance, cyc…
Resistivity measurements have been performed on single-crystalline ${\mathrm{La}}_{0.7}{\mathrm{Ca}}_{0.3}{\mathrm{MnO}}_{3\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$ thin films with control of \ensuremath{\delta} in order to study the influence of the ${\mathrm{Mn}}^{3+}$ content on the polaronic conduction…
We consider a system of spherical particles interacting by means of a pair potential equal to a finite constant for interparticle distances smaller than the sphere diameter and zero outside. The model may be a prototype for the interaction between micelles in a solvent [C. Marquest and T. A. Witten, J. Phys. (France)…
Alkali metal ion extraction was carried out using photochromic dithienylethene having two benzo-12-crown-4 ethers ( 1 ), benzo-15-crown-5 ethers ( 2 ), or benzo-18-crown-6 ethers moieties ( 3 ) and bis(benzothienyl)ethene having two benzo-18-crown-6 ether moieties ( 4 ). Two crown ether moieties of the open-ring form…
Corrosion inhibition of a mild steel in acid solutions by alkylamines (ALK-AM) and aniline hydrochloric (ANL-HCl) salts was investigated in the presence of sodium sulfate (Na2SO4) and sodium chloride (NaCl) using a potentiostat, a contact-angle goniometer, a scanning electron microscope (SEM), a Fourier transform infr…
A new way to synthesize trans-disubstituted cyclam tetraazamacrocycles 1 is reported. The synthesis proceeds in three steps via the tricyclic 1,4,8,11-tetraazatricyclo[9.3.1.14,8]hexadecane system 2, which can be selectively dialkylated and hydrolyzed under basic conditions to give the final product 1. An understandin…
The efficiency of various imidazole derivatives as corrosion inhibitors for copper in hydrochloric and sulfuric acids (HCl and H2SO4) was investigated. Electrochemical measurements showed the organic compounds investigated have fairly good inhibiting properties, except for 4-methyl-5-imidazolecarbaldehyde in HCl. Prot…