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A Photoinduced Birefringent Film with a High Orientational Order Obtained from a Novel Polymer Liquid Crystal

N. Kawatsuki、Toru Kawakami、T. Yamamoto2001-09-01Advanced Materials

A novel photo-crosslinkable polymer liquid crystal (PCP-LC), in which a high molecular orientation has been achieved by irradiation with UV light and thermal treatment, is presented. Two types of optical birefringent film have been obtained whereby the orientational order is controlled by the irradiation angle and pol…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsSemiconductor Lasers and Optical Devices

Layer-by-Layer Self-Assembly of Polyelectrolyte and Low Molecular Weight Species into Capsules

Zhifei Dai、Andreas Voigt、Stefano Leporatti 等 6 位作者2001-09-01Advanced Materials

Composite capsules containing low molecular weight species together with charged macromolecules have been prepared both in aqueous and organic solutions. Dyes were used as building blocks to quantify the adsorption. The Figure shows a tapping mode scanning force microscopy image of capsules consisting of poly(styrene…

Polymer Surface Interaction StudiesDendrimers and Hyperbranched PolymersElectrostatics and Colloid Interactions

Origin of low dielectric constant of carbon-incorporated silicon oxide film deposited by plasma enhanced chemical vapor deposition

Jin Yong Kim、Moo Sung Hwang、Yoon-Hae Kim 等 5 位作者2001-09-01Journal of Applied Physics

Dielectric properties of carbon-incorporated silicon oxide (SiOC) films deposited by plasma enhanced chemical vapor deposition (PECVD), using a bis-trimethylsilylmethane precursor, were compared with the dielectric properties of silicon oxide thermally grown in a furnace (thermal oxide) and also with oxide deposited b…

ZnO doping and propertiesThin-Film Transistor TechnologiesCopper Interconnects and Reliability

Generation and Dynamic Behaviors of Oxygen Vacancies in Barium Strontium Titanate Ceramics

Tatsuo Fukami、Daisuke Agawa、Noriko Bamba2001-09-01Japanese Journal of Applied Physics

Oxygen vacancy behaviors in Ni-doped barium strontium titanate (BST) ceramics have been observed through thermally stimulated current (TSC) measurements up to 200°C. The set of observations confirmed that the vacancies drift due to a high electric field at an elevated temperature to pile up under the cathode electrode…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Quantitative XPS Analysis of Bimetallic Cu-Co Catalysts

Deborah Vargas César、C.A.C. P�rez、Martín Schmal 等 4 位作者2001-09-01physica status solidi (a)

The surfaces of bimetallic Cu–Co/SiO2 catalyst with 1 Cu:2 Co atomic ratio has been studied focusing on the determination of bimetallic phase thickness and its distribution using a mathematical formalism from X-ray photoelectron spectroscopy (XPS) intensities. X-ray diffraction analysis indicated a Cu–Co alloy formati…

Catalytic Processes in Materials ScienceElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Etching mechanism of Y2O3 thin films in high density Cl2/Ar plasma

Youngchan Kim、Chang-Il Kim2001-09-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

In this study Y2O3 thin films were etched with an inductively coupled plasma. The etch rate of Y2O3 and the selectivity of Y2O3 to YMnO3 were investigated by varying the Cl2/(Cl2+Ar) gas mixing ratio. The maximum etch rate of Y2O3 and the selectivity of Y2O3 to YMnO3 were 302 Å/min and 2.4, respectively, at a Cl2/(Cl2…

ZnO doping and propertiesAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Synthesis and Properties of Highly Oriented (Sr, Ba)(Nb, Ta)2O6 Thin Films by Chemical Solution Deposition

Wataru Sakamoto、Yu-saku Horie、Toshinobu Yogo 等 4 位作者2001-09-01Japanese Journal of Applied Physics

Transparent and highly oriented (Sr, Ba)(Nb, Ta) 2 O 6 (SBNT) thin films have been synthesized by a chemical solution deposition method. A homogeneous and stable SBNT precursor solution was prepared by controlling the reaction of metal alkoxides in solution and by optimizing the additive as a stabilizing agent. Tantal…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Experimental data and model simulations of beam spread in the environmental scanning electron microscope

Scott A. Wight2001-09-01Scanning

This work describes the comparison of experimental measurements of electron beam spread in the environmental scanning electron microscope with model predictions. Beam spreading is the result of primary electrons being scattered out of the focused beam by interaction with gas molecules in the low-vacuum specimen chambe…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Use of n-Propyl Bromide Solvents for Extraction and Recovery of Asphalt Cements

Mary Stroup-Gardiner、JW Nelson2001-09-01Journal of Testing and Evaluation

Abstract Centrifuge extraction and Rotavapor recovery were used to determine the effect of solvent type (trichloroethylene and four n-propyl bromide products) on recovered asphalt binder properties. Mix variables included three binders mixed with each of two aggregate sources (one gradation). When recovered binder pro…

Asphalt Pavement Performance EvaluationInfrastructure Maintenance and MonitoringEngineering and Material Science Research

Hot Isostatic Pressing of Chromium Nitrides (Cr 2 N and CrN) Prepared by Self‐Propagating High‐Temperature Synthesis

Ken Hirota、Yoshihiko Takano、Masaru Yoshinaka 等 4 位作者2001-09-01Journal of the American Ceramic Society

Cr 2 N, CrN, and their mixtures (with desired fractions) have been prepared via self‐propagating high‐temperature synthesis (SHS) under a controlled nitrogen pressure, followed by hot isostatic pressing at 1300°C and 196 MPa under an atmosphere of argon gas. The combustion temperature increased as the nitrogen pressur…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Effects of Vacuum Ultraviolet Radiation on Thin Polyimide Films

Joyce A. Dever、Russell Messer、Charles E. Powers 等 5 位作者2001-09-01High Performance Polymers

This paper describes the vacuum ultraviolet (VUV) radiation durability screening testing of thin (12.7–25.4 μm) polyimide films proposed for use on the Next Generation Space Telescope (NGST) sunshield. Materials included in this screening test were Kapton®E, Kapton®HN, Upilex®S, CP1, CP1 with vapour deposited aluminiu…

Synthesis and properties of polymersSilicone and Siloxane ChemistrySpacecraft Design and Technology

Comparison of canonical and grand canonical models for selected multifragmentation data

Chinmay Das、S. Das Gupta、X. Liu 等 4 位作者2001-09-01Physical Review C

Calculations for a set of nuclear multifragmentation data are made using a canonical and a grand canonical model. The physics assumptions are identical but the canonical model has an exact number of particles, whereas the grand canonical model has a varying number of particles, hence, is less exact. Interesting differ…

Geochemistry and Geologic MappingX-ray Diffraction in CrystallographyChemical Thermodynamics and Molecular Structure

Point Defect Concentrations in Barium Titanate Revisited

Yoed Tsur、Clive A. Randall2001-09-01Journal of the American Ceramic Society

An analytic link between the oxygen partial pressure and the concentrations of the point defects for given temperatures and A/B conditions is presented for perovskites. A clear distinction between three different conditions is made. These are the sintering conditions, an intermediate metastable state, and a low‐temper…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Study of Related Poly(1,3,4-Oxadiazole-Amide)s Containing Silicon or Hexafluoroisopropylidene Groups in the Main Chain

Mariana Dana Iosip、Maria Brumă、Jenifer Robison 等 5 位作者2001-09-01High Performance Polymers

Two series of related poly(oxadiazole-amide)s have been synthesized by solution polycondensation reaction of aromatic diamines containing preformed 1,3,4-oxadiazole rings with diacid chlorides having silicon or hexafluoroisopropylidene groups. All these polymers were soluble in polar amidic solvents, such as N-methylp…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchSynthesis and properties of polymers

Fire retardance in polyamide‐6. The effects of red phosphorus and radiation‐induced cross‐links

A.I. Balabanovich、G.F. Levchik、Sergei V. Levchik 等 4 位作者2001-09-01Fire and Materials

Abstract Red phosphorus contained in non‐irradiated polyamide‐6 at concentrations up to 12.5 does not significantly improve the fire resistance of the polymer. It weakens the thermal stability of the polymer as reflected by a decrease in the onset temperature for mass loss from 407°C to 363°C, but causes char formatio…

Polymer crystallization and propertiesFlame retardant materials and propertiesFiber-reinforced polymer composites

Comparison of Crystallization Fouling in Plate and Double-Pipe Heat Exchangers

Bipan Bansal、Hans Müller‐Steinhagen、Xiao Dong Chen2001-09-01Heat Transfer Engineering

The selection of fouling resistances to design plate-and-frame heat exchangers is usually based on experience or guesswork. The primary aim of this study was to compare fouling resistances for plate heat exchangers with values obtained in a parallel double-pipe heat exchanger under comparable operating conditions. The…

Calcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic EffectsFreezing and Crystallization Processes

Effect of Short Glass Fiber on Structure and Mechanical Behavior of an Ethylene-1-Octene Copolymer

María L. Cerrada、Rosario Benavente、Ernesto Pérez2001-09-01Macromolecular Chemistry and Physics

Several composites with short glass fiber of a copolymer of ethylene and 1-octene, synthesized with a metallocene catalyst, have been prepared, up to a fiber content of 60 wt.-%. The effect of the fiber on the structure and mechanical behavior has been analyzed. Though the peak melting and crystallization temperatures…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Aspectos Morfológicos e Relação Estrutura-Propriedades de Poliestireno de Alto Impacto

Vinícius Galhard Grassi、Maria M.C. Forte、Marcus Fernando Dal Pizzol2001-09-01Polímeros

A tenacificação da matriz vítrea de poliestireno (PS) pela adição de borracha polibutadiênica, que tem como conseqüência um aumento de sua resistência ao impacto, origina um polímero com características singulares, o Poliestireno de Alto Impacto (HIPS). Durante a polimerização in situ de estireno em uma solução de bor…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Visualization of Mesostructures and Organic Guest Inclusion in Molecular Sieves with Confocal Microscopy

Christian Seebacher、J. Rau、F. W. Deeg 等 7 位作者2001-09-01Advanced Materials

The visualization of mesopores and defects in porous molecular sieves, as well as of the incorporation dynamics and spatial distribution of guest molecules, is achieved by optical confocal microscopy of single crystals immersed in solutions of fluorescent dyes. The Figure shows a fluorescence image of a silicalite cry…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisClay minerals and soil interactions

Bending martensite needles in Ni65Al35 investigated by two-dimensional elasticity and high-resolution transmission electron microscopy

Philippe Boullay、D. Schryvers、Robert V. Kohn2001-09-01Physical review. B, Condensed matter

The bending and tapering of microtwin needles at the interface between two martensite laminates in ${\mathrm{Ni}}_{65}{\mathrm{Al}}_{35}$ are addressed. A theory is presented, based on the assumption that the microstructure is essentially stress-free; it predicts a linear relationship between the bending and tapering…

Shape Memory Alloy TransformationsForce Microscopy Techniques and ApplicationsNonlocal and gradient elasticity in micro/nano structures