Materials Literature
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The new bio-branch of nanotechnology is considered to be one of the fastest emerging fields often called as Nanobiotechnology. Recent studies on exploitation of the natures secrets for the synthesis of inorganic materials are relatively new and exciting area of research with considerable potential for development. Amo…
A multilayer quasi-continuous density gradient centrifugation method for separating 20-250 nm metal colloids with high size resolution while maintaining particle stability is presented. Colloidal mixtures containing monodisperse gold nanospheres and clusters thereof, in particular, gold dimers, are purified with yield…
Mg and Mg alloys are of interest for biodegradable implants as they readily corrode in biological fluids, and dissolved Mg ions are nontoxic. Even though it is well known that Mg dissolution leads to pH increase in the surroundings, the effect of the corrosion-induced alkalization on the biological environment has not…
Abstract Raman spectroscopic studies are performed to probe the stress along the length of a bent ZnO nanowire. The zone‐centre E 2 high optical phonon shows a systematic red shift as the junction point of the two arms of the nanowire is approached. The mechanism of the red shift is discussed on the basis of the tensi…
Ab initio calculations of dielectric function and electron energy loss (EEL) function of periodically rippled armchair-edged graphene were performed in the framework of the random-phase approximation. The bending of graphene was found to remove restrictions on the electron transitions being forbidden in the flat graph…
Excitation of a semiconductor nanocrystal generates an electron–hole pair, which on recombination results in band edge excitonic emission. Insertion of impurity or dopant state capable of donating and/or accepting electrons can change the recombination process and leads to new emission called dopant emission. However,…
BACKGROUND: Ralstonia eutropha H16, found in both soil and water, is a Gram-negative lithoautotrophic bacterium that can utillize CO2 and H2 as its sources of carbon and energy in the absence of organic substrates. R. eutropha H16 can reach high cell densities either under lithoautotrophic or heterotrophic conditions,…
In the present work, we report on the performance of room temperature ammonia gas sensor based on polyaniline-titanium dioxide (PANi-TiO2) nanocomposite. The nanocomposite was fabricated using the spin coating method on glass substrates. PANi-TiO2(0%-50%) nanocomposite films were characterized for their structural as…
A hyperbranched conjugated polyelectrolyte (HCPE) with a core-shell structure is designed and synthesized via alkyne polycyclotrimerization and click chemistry. The HCPE has an emission maximum at 565 nm with a quantum yield of 12% and a large Stokes shift of 143 nm in water. By virtue of its poly(ethylene glycol) she…
Silicon nanocrystals have recently attracted significant attention for applications in electronics, optoelectronics, and biological imaging due to their size-dependent optical and electronic properties. Here a method for synthesizing luminescent silicon nanocrystals from silicon tetrachloride with a nonthermal plasma…
To improve the photocatalytic efficiency of TiO(2)-based nanomaterials, we demonstrate a facile, generalized, highly localized reduction approach to the decoration of TiO(2)-polyoxometalate composites with a range of metal nanoparticles including Cu, Ag, Pt, and Au. The synthesis of nanocomposite photococatalysts repo…
The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts po…
The topological insulating phase results from inversion of the band gap due to spin-orbit coupling at an odd number of time-reversal symmetric points. In Bi$_2$Se$_3$, this inversion occurs at the $Γ$ point. For bulk Bi$_2$Se$_3$, we have analyzed the effect of arbitrary strain on the $Γ$ point band gap using Density…
The electronic properties of heterojunction electron gases formed in GaN/AlGaN core/shell nanowires with hexagonal and triangular cross-sections are studied theoretically. We show that at nanoscale dimensions, the non-polar hexagonal system exhibits degenerate quasi-one-dimensional electron gases at the hexagon corner…
The magnetic properties of thin (Ga,Mn)As layers improve during annealing by out-diffusion of interstitial Mn ions to a free surface. Out-diffused Mn atoms participate in the growth of a Mn-rich surface layer and a saturation of this layer causes an inhibition of the out-diffusion. We combine high-resolution x-ray dif…
Density-functional theory is used to study the geometric and electronic structure of cationic Si(16)(+) clusters with a Ti, V, or Cr dopant atom. Through unbiased global geometry optimization based on the basin-hopping approach, we confirm that a Frank-Kasper polyhedron, with the metal atom at the center, represents t…
A new method was developed to coat hydroxyapatite (HAp) onto electrospun poly(lactic-co-glycolic acid) (PLGA) nanofibers for tendon-to-bone insertion site repair applications. Prior to mineralization, chitosan and heparin were covalently immobilized onto the surface of the fibers to accelerate the nucleation of bone-l…
AIM: This study explores the use of natural silica-based porous material from diatoms, known as diatomaceous earth, as a drug carrier of therapeutics for implant- and oral-delivery applications. MATERIALS & METHODS: To prove this concept, two drugs models were used and investigated: a hydrophobic (indomethacin) and hy…
We investigate the radiation rate of a dipole in close proximity to a hyperbolic metamaterial and confirm that both the radiation rate and its fraction directed into the metamaterial are greatly increased compared to bulk dielectric or metal. However, we find that the homogenized effective-medium approach greatly over…
The bandgap opening of graphene is extremely important for the expansion of the applications of graphene-based materials into optoelectronics and photonics. Current methods to open the bandgap of graphene have intrinsic drawbacks including small bandgap openings, the use hazardous/harsh chemical oxidations, and the re…