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Preparation and surface modification of electrospun aligned poly(butylene carbonate) nanofibers

Meiling Shao、Lu Chen、Qing Yang2013-03-18Journal of Applied Polymer Science

Abstract In this study, aligned poly(butylene carbonate) nanofibers were fabricated by electrospinning with a high‐speed transfer roller as the receiving device. Cold plasma treatment technology was applied to improve its hydrophilicity and activity to expand its application in biological materials. The morphology of…

Advanced Sensor and Energy Harvesting Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Optical nonlinearity and photoinduced anisotropy of an azobenzene‐containing ionic liquid crystalline polymer

Fuli Zhao、Changshun Wang、Yi Zeng 等 4 位作者2013-03-18Journal of Applied Polymer Science

Abstract The nonlinear optical properties of an azobenzene‐containing ionic liquid crystalline polymer were investigated using single‐beam Z ‐scan and optical Kerr effect (OKE). The polymer film exhibited large nonlinear absorption (∼10 −6 cm W −1 ) and nonlinear refraction (∼10 −11 cm 2 W −1 ) under 532 nm ps excitat…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Epitaxial graphene on step bunching of a 6H-SiC(0001) substrate: Aromatic ring pattern and Van Hove singularities

M. Ridene、Tobias Wassmann、Emiliano Pallecchi 等 6 位作者2013-03-18Applied Physics Letters

We report on scanning tunneling microscopy and spectroscopy (STM/STS) investigations of graphene grown on a 6H-SiC(0001) substrate. Our STM images of a graphene layer on a step bunching of the SiC feature a (√3 × √3)R30° pattern of aromatic rings and well developed, sharp Van Hove singularities in the corresponding ST…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Low hysteresis and large room temperature magnetocaloric effect of Gd5Si2.05−xGe1.95−xNi2x (2x = 0.08, 0.1) alloys

Xichun Zhong、J.X. Min、Z. W. Liu 等 7 位作者2013-03-18Journal of Applied Physics

Gd5Si2.05−xGe1.95−xNi2x (2x = 0.08, 0.1) alloys were prepared by arc melting followed by annealing at 1273 K for 96 h. Mixed monoclinic Gd5Si2Ge2-type phase, orthorhombic Gd5Si4-type phase, and a small amount of Gd5Si3-type phase were obtained in these alloys. Gd5Si2.01Ge1.91Ni0.08 alloy undergoes a second-order trans…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsThermal Expansion and Ionic Conductivity

Photochemical properties and shape evolution of CdSe QDs in a non-injection reaction

Eun‐Jung Park、Ji Young Ryu、Youngseon Choi 等 5 位作者2013-03-18Nanotechnology

Highly monodispersed CdSe quantum dots (QDs) were prepared without an injection procedure. A series of Cd salts of long chain fatty acids, including Cd-myristate (C14), Cd-palmitate (C16) and Cd-stearate (C18) was prepared, and all metallic precursors and surfactants were mixed together followed by increasing the temp…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Self-assembled perovskite-spinel heterostructure on a highly distorted substrate

Yuanmin Zhu、DaoMing KE、Rong Yu 等 8 位作者2013-03-18Applied Physics Letters

The pattern configuration and interface structure in epitaxial BiFeO3-CoFe2O4 heterostructures grown on (010)pc NdGaO3 substrates have been investigated systematically by transmission electron microscopy and chemical analysis. The crystal orientation of CoFe2O4 variants was tuned to [111]CFO, while BiFeO3 kept [010]pc…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Plasmon excitation in single-walled carbon nanotubes probed using charged particles: comparison of calculated and experimental spectra

Silvina Seguí、Z. L. Mišković、J.L. Gervasoni 等 4 位作者2013-03-18Journal of Physics Condensed Matter

We study ' the excitation of plasmons due to the incidence of a fast charged particle that passes through a single-wall carbon nanotube. We use a quantized hydrodynamic model, in which the σ and π electron systems are depicted as two interacting fluids moving on a cylindrical surface. Calculations of the average numbe…

Carbon Nanotubes in CompositesAdvanced Electron Microscopy Techniques and ApplicationsNanopore and Nanochannel Transport Studies

Maltose-Containing Polyurethane Films: Synthesis, Characterization, and Their Use for Determination of Dopamine in the Presence of the Electroactive and Nonelectroactive Interferents

Aziz Paşahan、Süleyman Köytepe、Mahmut Alper Cengiz 等 4 位作者2013-03-18International Journal of Polymeric Materials

A series of polyurethanes were prepared from the maltose-ethylene glycol-diphenylmethane diisocyanate and used to construct a novel polyurethane electrode for the detection of dopamine. The polyurethanes were characterized by FT-IR, differential scanning calorimetry, and thermogravimetric analysis. The intrinsic visco…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

SERS signal response and SERS/SERDS spectra of fluoranthene in water on naturally grown Ag nanoparticle ensembles

Robert Ossig、Anna Kolomijeca、Yong‐Hyok Kwon 等 5 位作者2013-03-18Journal of Raman Spectroscopy

We present experimental results of the time‐dependent Raman signal response of fluoranthene adsorbed on a naturally grown Ag nanoparticle ensemble, which serves as surface enhanced Raman scattering (SERS) substrate. In addition, SERS characteristics such as the concentration‐dependent calibration curves and the limit…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchBiosensors and Analytical Detection

Synthesis of Silicon Quantum Dots Functionalized Chemically with Monosaccharides and Their Use in Biological Fluorescence Imaging

Yoshio Nakahara、Kazuki Machiya、Toshiyuki Sato 等 7 位作者2013-03-18Chemistry Letters

Abstract Novel water-dispersible, pH-stable, and biocompatible quantum dots were synthesized through the surface modification of silicon quantum dots (SiQDs) with monosaccharides. The presence of the monosaccharide on the surface of the SiQDs was recognized by fluorescence measurements using its complementary lectin (…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

An investigation on actuation behavior of polyacrylonitrile gel fibers as a function of microstructure and stabilization temperature

Hamideh Mirbaha、Shahram Arbab、Ahmad Zeinolebadi 等 4 位作者2013-03-18Smart Materials and Structures

Polyacrylonitrile (PAN) gel fibers show great potential to be used as actuators due to their mechanical response to chemical stimuli. In this work the response of PAN gel fibers to pH variation is studied. Three commercial grade PAN fibers with different chemical composition are investigated. Fibers are stabilized at…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsFiber-reinforced polymer composites

Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide

I. A. Ronova、Maria Brumă、А. А. Кузнецов 等 4 位作者2013-03-18Polymers for Advanced Technologies

The swelling with supercritical carbon dioxide (sc‐CO 2 ) of thin films of polyimides having various structures was investigated. It was shown that the degree of swelling is significantly influenced by the solvent which was used for the synthesis of those polyimides, by the solvent which was used for the preparation o…

Epoxy Resin Curing ProcessesCarbon dioxide utilization in catalysisSynthesis and properties of polymers

Effect of CO on Ru Nucleation and Ultra-Smooth Thin Film Growth by Chemical Vapor Deposition at Low Temperature

Wen Liao、John G. Ekerdt2013-03-18Chemistry of Materials

Ruthenium was deposited on SiO 2 /Si(001) substrates at 473 K by chemical vapor deposition (CVD) using triruthenium dodecacarbonyl with and without an overpressure of CO. Carbon monoxide was employed to inhibit the growth of previously nucleated islands to allow the formation of additional nuclei. Carbon monoxide also…

Semiconductor materials and devicesCopper Interconnects and ReliabilitySemiconductor materials and interfaces

Novel poly(ester amide)s from glycine and L ‐lactic acid by an easy and cost‐effective synthesis

Ana C. Fonseca、Arménio C. Serra、Jorge F. J. Coelho 等 5 位作者2013-03-18Polymer International

Abstract Novel low molecular weight poly(ester amide)s based on glycine and l ‐lactic acid with interest for the biomedical field were successfully prepared by interfacial polymerization, which is an easy and fast polymerization method. Preparation of the α‐amino acid based diamine, the l ‐lactic acid based diacyl chl…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Study of electrospun nanofibre formation process and their electrostatic analysis

Saeed Hamzeh、Mohsen Miraftab、Ata Yoosefinejad2013-03-18Journal of Industrial Textiles

Electrospinning generates nanofibres at speeds that often surpass those of conventional man-made fibre production. This makes control and manipulation of these nanofibres that much more difficult and challenging. However, to take full advantage of the superior properties of electrospun nanofibres, their production pro…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

Eco‐friendly conductive polymer nanocomposites (CPC) for solar absorbers design

Zied Antar、Jean‐François Feller、Guillaume Vignaud2013-03-18Polymers for Advanced Technologies

To reduce both the cost and the environmental impact of copper‐based thermal solar absorbers, we have investigated their possible substitution by bio‐based conductive polymer nanocomposite (CPC) elements. Our results show that carbon nanotubes (CNT) have no significant influence on polymers’ calorimetric properties su…

Supercapacitor Materials and FabricationThermal properties of materialsDielectric materials and actuators

Structural Tailoring Effects on the Magnetic Behavior of Symmetric and Asymmetric Cubane‐Type Ni complexes

Alexey Ponomaryov、Nam‐Seok Kim、Jaewon Hwang 等 11 位作者2013-03-18Chemistry - An Asian Journal

Using two kinds of carboxylate ligands with small but significant differences in steric size, symmetric and asymmetric Fe(II) and Ni(II) cubanes have been synthesized in a controlled fashion. Fast sweeping pulsed field measurements showed magnetization hysteresis loops for two cubane-type molecular complexes, [Ni4(μ-O…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Magnetic control of relaxor features in BaZr0.5Ti0.5O3 and CoFe2O4 composite

Muhammad Usman、Arif Mumtaz、Sobia Raoof 等 4 位作者2013-03-18Applied Physics Letters

We report the effect of magnetic field on the dielectric response in a relaxor ferroelectric and ferromagnetic composite (BaZr0.5Ti0.5O3)0.65-(CoFe2O4)0.35. Relaxor characteristics such as dielectric peak temperature and activation energy show a dependence on applied magnetic fields. This is explained in terms of incr…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Coupled vibrational modes in multiple-filled skutterudites and the effects on lattice thermal conductivity reduction

Liang Guo、Xianfan Xu、James R. Salvador 等 4 位作者2013-03-18Applied Physics Letters

The influence of guest atoms on thermal conduction in filled skutterudites was studied using ultrafast reflectance spectroscopy. Different filling species cause coupled vibrational modes between the guest atoms and the host lattice at different frequencies, which scatter phonons in different spectral spans. Using a De…

Advanced Thermoelectric Materials and DevicesAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Strain-mediated electric-field control of multiferroic domain structures in ferromagnetic films

N. A. Pertsev2013-03-18Applied Physics Letters

The converse magnetoelectric effect resulting from the electric-field-induced motion of 90° domain walls in a ferromagnetic film coupled to a single-domain ferroelectric substrate is described theoretically. To that end, the volume fractions of 90° domains with differently oriented in-plane magnetizations are calculat…

Magnetic properties of thin filmsFerroelectric and Piezoelectric MaterialsMultiferroics and related materials