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Effect of filler size on thermophysical and electrical behavior of nanocomposites based on expanded graphite nanoparticles filled in low‐density polyethylene matrix

J Kratochvíla、Abderrahim Boudenne、Igor Krupa2012-12-27Polymer Composites

Abstract Various aspects of electrical and thermophysical properties of nanocomposites based on low‐density polyethylene matrix filled with nanostructuralized expanded graphite (EG) and standard, microsized graphite are presented in this article. A periodical method developed in the laboratory was used to measure simu…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Terahertz optical properties of multilayer graphene: Experimental observation of strong dependence on stacking arrangements and misorientation angles

I-Tan Lin、Jia-Ming Liu、Kai-Yao Shi 等 7 位作者2012-12-27Physical Review B

The optical conductivity of monolayer and multilayer graphene in the terahertz spectral region is experimentally measured using terahertz time-domain spectroscopy. The stacking arrangement and the misorientation angle of each sample are determined by Raman spectroscopy. The chemical potential of each sample is measure…

Graphene research and applicationsTopological Materials and PhenomenaTerahertz technology and applications

Finite Element Analysis of a Natural Fiber (Maize) Composite Beam

D. Saravana Bavan、G. C. Mohan Kumar2012-12-27Journal of Engineering

Natural fiber composites are termed as biocomposites or green composites. These fibers are green, biodegradable, and recyclable and have good properties such as low density and low cost when compared to synthetic fibers. The present work is investigated on the finite element analysis of the natural fiber (maize) compo…

Natural Fiber Reinforced CompositesTribology and Wear AnalysisMechanical Engineering and Vibrations Research

Correct Spectral Conversion between Surface‐Enhanced Raman and Plasmon Resonance Scattering from Nanoparticle Dimers for Single‐Molecule Detection

Kyuwan Lee、Joseph Irudayaraj2012-12-27Small

Simultaneous measurement of surface-enhanced Raman scattering (SERS) and localized surface plasmon resonance (LSPR) in nanoparticle dimers presents outstanding opportunities in molecular identification and in the elucidation of physical properties, such as the size, distance, and deformation of target species. SERS-LS…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesProtein Interaction Studies and Fluorescence Analysis

Dendron‐Stabilized Liquid Crystalline Blue Phases with an Enlarged Controllable Range of the Photonic Band for Tunable Photonic Devices

Seishi Shibayama、Hiroki Higuchi、Yasushi Okumura 等 4 位作者2012-12-27Advanced Functional Materials

Abstract Liquid crystalline blue phases (BPs) show excellent potential for application in tunable photonic devices because they possess the unique optical property that the selective 3D Bragg diffraction in a visible wavelength region can be continuously shifted using an electric field. A new approach to simultaneousl…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Anthranilamides as Bioinspired Molecular Electrets: Experimental Evidence for a Permanent Ground-State Electric Dipole Moment

Bing Xia、Duoduo Bao、Srigokul Upadhyayula 等 5 位作者2012-12-27The Journal of Organic Chemistry

As electrostatic equivalents of magnets, organic electrets offer unparalleled properties for impacting energy conversion and electronic applications. While biological systems have evolved to efficiently utilize protein α-helices as molecular electrets, the synthetic counterparts of these conjugates still remain largel…

Conducting polymers and applicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Theoretical Characterization of X-ray Absorption, Emission, and Photoelectron Spectra of Nitrogen Doped along Graphene Edges

Xianlong Wang、Zhufeng Hou、Takashi Ikeda 等 6 位作者2012-12-27The Journal of Physical Chemistry A

K-edge X-ray absorption (XAS), emission (XES), and photoelectron (XPS) spectra of nitrogen doped along graphene edges are systematically investigated by using first-principles methods. In this study we considered pyridinium-like, pyridine-like, cyanide-like, and amine-like nitrogens at armchair and zigzag edges and py…

Advancements in Battery MaterialsAdvanced Photocatalysis TechniquesGraphene research and applications

Magnetic and Electrical Transport Properties of LaBaCo2O5.5+δ Thin Films on Vicinal (001) SrTiO3 Surfaces

Chunrui Ma、Ming Liu、Gregory Collins 等 10 位作者2012-12-27ACS Applied Materials & Interfaces

Highly epitaxial LaBaCo(2)O(5.5+δ) thin films were grown on the vicinal (001) SrTiO(3) substrates with miscut angles of 0.5°, 3.0°, and 5.0° to systemically study strain effect on its physical properties. The electronic transport properties and magnetic behaviors of these films are strongly dependent on the miscut ang…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Synthesis, Structure, and Single‐Molecule Magnetic Properties of Rare‐Earth Sandwich Complexes with Mixed Phthalocyanine and Schiff Base Ligands

Hailong Wang、Wei Cao、Tao Liu 等 5 位作者2012-12-27Chemistry - A European Journal

Double- and quadruple-decker complexes of rare-earth metals with mixed phthalocyanine and Schiff base ligands have been synthesized and structurally and magnetically characterized. These complexes (see picture: Dy pink, Ca green, N blue, C black) extend the scope of sandwich-type tetrapyrrole-based rare-earth molecula…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Synthesis of Hierarchically Porous Hydrogen Silsesquioxane Monoliths and Embedding of Metal Nanoparticles by On‐Site Reduction

Nirmalya Moitra、Kazuyoshi Kanamori、Toyoshi Shimada 等 7 位作者2012-12-27Advanced Functional Materials

Abstract A facile synthesis of a new class of reactive porous materials is reported: hierarchically porous hydrogen silsesquioxane (HSiO 1.5 , HSQ) monoliths with well‐defined macropores and mesopores. The HSQ monoliths are prepared via sol‐gel accompanied by phase separation in a mild condition, and contain micromete…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Prediction of high efficiency ZnMgO/Si solar cells suppressing carrier recombination by conduction band engineering

Knut Erik Knutsen、R. Schifano、Erik Stensrud Marstein 等 5 位作者2012-12-27physica status solidi (a)

Abstract A significant conduction band offset appearing in n‐ZnO/p‐Si heterojunction solar cells is recognized as a serious roadblock to obtain high efficiency solar cells. By alloying with Mg, the conduction band in Zn 1– x Mg x O can be raised above that of Si, so that the influence of recombination centers at the i…

ZnO doping and propertiesThin-Film Transistor TechnologiesSilicon and Solar Cell Technologies

Functionalization of electrospun poly(ε-caprolactone) scaffold with heparin and vascular endothelial growth factors for potential application as vascular grafts

Zhexiang Wang、Bin Sun、Min Zhang 等 7 位作者2012-12-27Journal of Bioactive and Compatible Polymers

In this study, a heparin-conjugated poly(ε-caprolactone) electrospun fiber was constructed to develop a functional scaffold for controlled release of vascular endothelial growth factors. The immobilization of vascular endothelial growth factor was achieved through affinity binding between heparin and vascular endothel…

Electrospun Nanofibers in Biomedical ApplicationsCardiac and Coronary Surgery TechniquesTissue Engineering and Regenerative Medicine

Cavity QED of the Graphene Cyclotron Transition

David Hagenmüller、Cristiano Ciuti2012-12-27Physical Review Letters

We investigate theoretically the cavity quantum electrodynamics of the cyclotron transition for Dirac fermions in graphene. We show that the ultrastrong coupling regime characterized by a vacuum Rabi frequency comparable or even larger than the transition frequency can be obtained for high enough filling factors of th…

Graphene research and applicationsQuantum and electron transport phenomenaQuantum Electrodynamics and Casimir Effect

Characterization of kaolin intercalates of oleochemicals derived from rubber seed (Hevea brasiliensis) and tea seed (Camelia sinensis) oils

Chinedum Ogonna Mgbemena、Naboth O. Ibekwe、Rugmini Sukumar 等 4 位作者2012-12-27Journal of King Saud University - Science

Kaolin intercalates were prepared by employing derivatives of oleochemicals namely rubber seed oil (SRSO) and tea seed oil (STSO) and characterized by employing powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption–desorption (NAD) techniques. Intercalation was achieve…

Polymer Nanocomposites and PropertiesClay minerals and soil interactionsPickering emulsions and particle stabilization

Graphene‐Coated Atomic Force Microscope Tips for Reliable Nanoscale Electrical Characterization

Mario Lanza、A. Bayerl、Teng Gao 等 9 位作者2012-12-27Advanced Materials

Graphene single-layer films are grown by chemical vapor deposition and transferred onto commercially available conductive tips for atomic force microscopy. Graphene-coated tips are much more resistant to both high currents and frictions than commercially available, metal-varnished, conductive atomic force microscopy t…

Graphene research and applicationsForce Microscopy Techniques and ApplicationsSurface and Thin Film Phenomena

Bienzyme-Functionalized Monodispersed Biocompatible Cuprous Oxide/Chitosan Nanocomposite Platform for Biomedical Application

Jay Singh、Anamika Srivastava、Appan Roychoudhury 等 6 位作者2012-12-27The Journal of Physical Chemistry B

The ultrafine monodispersed cuprous oxide (Ufm-Cu(2)O) nanoparticles have been successfully synthesized by a facile wet chemical method using poly-N-vinylpyrrolidone (PVP) as a capping agent. This colloidal solution of Ufm-Cu(2)O and chitosan (CS) is electrophoretically deposited (EPD) onto the indium tin-oxide (ITO)…

Copper-based nanomaterials and applicationsNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

Modular ‘Click‐in‐Emulsion’ Bone‐Targeted Nanogels

Daniel A. Heller、Yair Levi、Jeisa M. Pelet 等 17 位作者2012-12-27Advanced Materials

A new class of nanogel demonstrates modular biodistribution and affinity for bone. Nanogels, ∼70 nm in diameter and synthesized via an astoichiometric click-chemistry in-emulsion method, controllably display residual, free clickable functional groups. Functionalization with a bisphosphonate ligand results in significa…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliverySupramolecular Self-Assembly in Materials

Electrophoretic Deposition of CdSe/ZnS Quantum Dots for Light‐Emitting Devices

Katherine Song、Ronny Costi、Vladimir Bulović2012-12-27Advanced Materials

The electrophoretic deposition of thin films of colloidal quantum dots is an alternative to spin-casting and printing for large-area, high-throughput processing of quantum-dot (QD) optoelectronics. In this study, QD light-emitting diodes (QD-LEDs) fabricated with electrophoretically deposited films of CdSe/ZnS core/sh…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsElectrophoretic Deposition in Materials Science

Description of Hysteresis in Lithium Battery by Classical Preisach Model

Vincenzo Franzitta、A. Viola、Marco Trapanese2012-12-27Advanced materials research

In this paper Preisach Model is applied to obtain a mathematical model of the hysteresis in lithium battery. Preisach Model allows to describe the hysteresis of charging and discharging cycles in a lithium battery. The identification of the model is obtained by using a neural network technique developed for magnetic s…

Microgrid Control and OptimizationElectric Motor Design and AnalysisMagnetic Properties and Applications

Mechanical, thermal and morphological properties of poly(lactic acid)/epoxidized natural rubber blends

Mohd Bijarimi、Sahrim Ahmad、Rozaidi Rasid2012-12-27Journal of Elastomers & Plastics

In this work, we report a melt blend of poly(lactic acid)(PLA)/epoxidized natural rubber (ENR) with liquid natural rubber (LNR). The LNR was synthesized by a photochemical degradation technique and used as a compatibilizer in the PLA/rubber binary blending systems. The PLA/ENR/LNR blends were melt-blended in a Haake i…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties