Materials Literature
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Psychrobacter 273-4 was isolated from a 20,000-40,000-year-old Siberian permafrost core, which is characterized by low temperature, low water activity, and high salinity. To explore how 273-4 survives in the permafrost environment, proteins in four 273-4 samples cultured at 4 and 22 degrees C in media with and without…
Abstract The mechanical behavior of layered silicate/starch polycaprolactone blend nanocomposites was evaluated. Three different clays (Cloisite Na + , Cloisite 30B and Cloisite 10A) were used as reinforcement. Nanocomposites were prepared by melt intercalation followed by compression molding. These nanocomposites wer…
A complex with triple-stranded helices, {[Cu(mtz)]3(CuI)}n, was obtained under hydrothermal conditions. The complex possesses an unprecedented non-interpenetrated (12(3))(12(2).14)3 network, which represents the first example of the largest gon value of the smallest ring for the Archimedean net reported so far.
CdSe and CdSe/ZnSe core shell nanocrystals were prepared via the inverse micelle technology with TOP/TOPO/HDA surfactants, and their high crystallinity was confirmed by using X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) analyses. Ostwald ripening behavior of the nanocrystals was…
Polymers with a low molecular weight derived from soybean oil have been prepared in a supercritical carbon dioxide medium by cationic polymerization. Boron trifluoride diethyl etherate was used as an initiator. Influences of polymerization temperature, amount of initiator, and carbon dioxide pressure on the molecular…
Atoms on the move: NO2 lifts the Au{111} herringbone surface reconstruction at 78 K through a massively cooperative restructuring step, which involves on the order of 600 NO2 molecules (blue; see STM image) and 80–100 Au atoms. Mesoscopic island ordering is a precursor to the process, and Au nanoclusters (green/yellow…
We report a microscopic investigation of multipolar order parameters in the ordered state of NpO2 conducted via 17O NMR on a single crystal. From the angular dependence of hyperfine fields at 17O nuclei, we have obtained clear evidence for the appearance of field-induced antiferro-octupolar as well as field-induced an…
A bottoming 275kW planar solid oxide fuel cell (SOFC) gas turbine (GT) hybrid system control approach has been conceptualized and designed. Based on previously published modeling techniques, a dynamic model is developed that captures the physics sufficient for dynamic simulation of all processes that affect the system…
Abstract Crosslink density (CLD) is an important characteristic for elastomeric polymer networks. The mechanical and viscoelastic properties of the elastomers are critically dependant on the CLD. Several methods have been adopted for its determination, but swelling and stress–strain methods continue to be more popular…
The aim of this paper is to evaluate the effect of the alkali treatment on the mechanical properties of jute fibers and its composites. The effect on the processing conditions was also analyzed. Woven jute preforms were used to prepare the composites using the vacuum infusion technique. The fibers were treated with Na…
Hydrophobic interactions play an important role in assembly processes in aqueous environments. In case of peptide amphiphiles, hydrophobicity is combined with hydrogen bonding to yield well-defined peptide-based aggregates. Here, we report a systematic study after the role of hydrophobic interactions on both stabiliza…
To explore the effect of surface contaminants on water chemistry at metallic surfaces, adsorption and decomposition of water monomers on clean and X/Pd(111)(X = C, N and O) surfaces are investigated based on density functional theory calculations. It is revealed that H(2)O binds to Pd(111) surface primarily through th…
Abstract The relationship between the contact angles, surface tension, and surface roughness is reviewed. Numerical formulas related to the superhydrophobic rough surfaces of polymers are predicted with two approaches, the Wenzel and Cassie–Baxter models. With these models as a guide, an artificial superhydrophobic su…
The first artificial double helix composed of achiral synthetic polymers have been constructed by twisting of a supramolecular ladders from poly(trimethylene imine) salts and porphyrin-bridged BisPYBOXs through hydrogen bonds between the PYBOX groups and secondary ammonium cations in the polymer.
The 1H and 2H NMR spectra of porphycene (1), 2,3,6,7,12,13,16,17-octaethylporphycene (2), 2,7,12,17-tetra-n-propylporphycene (3), and 2,7,12,17-tetra-(tert-butyl)-3,6-13,16-dibenzo[cde;mno]porphycene (4) partially deuterated in the mobile proton sites are reported. These compounds exhibit two intramolecular NHN hydrog…
Abstract In this paper we investigate cobalt doped ZnO thin films prepared via different sol–gel methods. XRD shows only the diffraction peaks from wurtzite ZnO without secondary phase, as widely reported in literature, for the Co contents of our samples of 3 to 12%. Raman spectroscopy reveals the existence of antifer…
Composites based on ferrite powders Ni0.95-xZnxCo0.05Fe1.90Mn0.02O4with x=0-0.25, with a volume concentration of 50%, were fabricated and characterized. Dielectric and magnetic properties of the composites were measured over 0.01-16.5 GHz. The permeability of the composites at low frequency increases from ~4.18 to ~7.…
In this work, it has been shown that, through a highly controlled process, the chemical etching of the anodic aluminum oxide membrane barrier layer can be performed in such a way as to achieve nanometer-scale control of the pore opening. As the barrier layer is etched away, subtle differences revealed through AFM phas…
Accurate structure factors of silicon and diamond have been experimentally determined from powder diffraction data measured at the third-generation synchrotron-radiation source SPring-8, BL02B2. The accuracy of the obtained structure factors has been evaluated by comparing with structure factors in the literature meas…
${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ thin films having different thicknesses were grown by pulsed laser deposition with in situ reflection high energy electron diffraction diagnostics on $\mathrm{La}\mathrm{Al}{\mathrm{O}}_{3}$ substrates. The mismatch between film and substrate gives ri…