Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The self-corrosion and galvanic corrosion of magnesium based alloys Mg–10Gd–3Y–0·5Zr (GW103) and AZ91D coupled to carbon steel and Cu in ethylene glycol (EG) solution with and without inorganic–organic inhibitor packages Na3PO4+SDBS and Na3PO4+benzoate were investigated through measuring their open circuit potentials,…
Abstract Microcellular injection‐molding technology is capable of producing lightweight polymeric products. The foam morphology is determined by the injection‐molding parameters, and it has been observed that depending on the parameter variations, the cell structure may exhibit substantial morphological differences th…
The reversible "catch-and-release" of small molecules from the surface of monolayer-protected gold nanoparticles is described. The valency of the system (i.e., the number of molecules bound to the surface) can be controlled through the addition and removal of metal ions from the monolayer. Both the change in valency a…
This is a personal account of the development of the title subject which is the broader field encompassing surface photochemistry. It describes the early times when the main interest centered on desorption induced by slow electrons, follows its evolution in experiment (use of synchrotron radiation and connections to e…
This paper proposes a model for the computation of core losses and excitation current, in a lamination by lamination method, for wound core distribution transformers. The model was developed based on the finite-element method (FEM). The results obtained by applying the proposed model were compared with the FEM results…
A cationic, copper(II)-containing ligand, derived from bulky 5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrin, Cu(T4), and two sterically friendlier forms, [trans-5,15-di(N-methylpyridinium-4-yl)porphyrinato]copper(II), Cu(tD4), and [cis-5,10-di(N-methylpyridinium-4-yl)porphyrinato]copper(II), Cu(cD4), bind to DN…
The lowest excited triplet (T(1)) ππ* states of gallium (Ga) and various rhodium (Rh) 5,10,15-trispentafluorophenyl corroles (Cors) were studied in the liquid crystal (LC) E-7 and in rigid glasses by time-resolved electron paramagnetic resonance (TR-EPR) spectroscopy. The triplet sublevel energies were experimentally…
Abstract The light‐driven reduction of protons for the production of molecular hydrogen in multicomponent systems depends on electron relays such as viologens. We describe here the effect of viologens appended with guest moieties (adamantane or bile acid) on the efficiency of a system composed of a cyclodextrin‐append…
We examine strain-induced quantized Landau levels in graphene. Specifically, arc-bend strains are found to cause nonuniform pseudomagnetic fields. Using an effective Dirac model which describes the low-energy physics around the nodal points, we show that several of the key qualitative properties of graphene in a strai…
Ca(9)Lu(PO(4))(7):Ce (3+) and Ca (9)Lu (PO (4))(7):Pr (3+) polycrystalline materials were synthesized by solid state reaction at high temperature. The materials were characterized by powder x-ray diffraction (XRPD). The luminescence spectroscopy and the excited state dynamics of these compounds were investigated upon…
In this Letter, an entropic model recently formulated by Mauro et al. for the temperature dependence of viscosity in glass-forming materials is generalized to describe the temperature-volume dependences of viscosities and structural relaxation times near the glass transition. It is found that the generalization shows…
Abstract This study proposes a new method to generate positive contrast in magnetic resonance imaging (MRI) using superparamagnetic contrast agents. Superparamagnetic nanostructures consisting of octahedron manganese ferrite nanoparticles embedded in spherical nanogels are fabricated using a bottom‐up approach. The co…
Thiol-ene chemistry was harnessed to enable production of thermochemically stable thermoset fibers containing 50-87 wt % acrylated epoxidized soybean oil and 49-72% biobased carbon without using solvent or heat. In this demonstration, the fibers were made by simultaneous electrospinning and photocuring of a liquid mon…
UNLABELLED: In this paper, the toluene adsorption/desorption properties of modified 13X molecular sieves (M-13X) are discussed. M-13X molecular sieves were prepared by acidic and steam treatments of 13X molecular sieves. The structural parameters of M-13X were evaluated and compared with those of other molecular sieve…
Metal ion migration in a bis-strapped porphyrin ligand with overhanging carboxylate groups has been investigated in solution. Two types of homobimetallic complexes are generated with Pb(II) and Bi(III) cations, which stand on both sides of the macrocycle: (i) a dissymmetric complex with one cation bound to the porphyr…
A coordination polymer based on an unprecedented Fe(20) core has been constructed by in situ ligand conversion, including trapping of an intermediate.
We have devised new diketopyrrolopyrrole dyes soluble in polar solvents. The colors of the dyes have been changed by substituting the 3,6-phenyl residues for thiophene groups. The solubility in polar solvents has been improved by alkylation of a dimethylaminopropyne fragment with a 1,3-sultone giving rise to sulfobeta…
A new fluorescence enhancement technical platform based on anodic aluminum oxide (AAO) nanostructure substrate is reported for the first time. Several fluorophores have been examined on the AAO nanostructure substrates. Systematic experiments found that the enhancement factor can be up to two orders of magnitude compa…
Most life-cycle studies have found that a reduction of greenhouse gas emissions can be achievable by replacing petroleum-based plastics with bioplastics made from renewable feedstock, but these analyses have failed to count the carbon emissions that occur as farmers worldwide convert forest and grassland to new cropla…
The first use of triethylene glycol (H(2)teg) in Fe/Ln chemistry affords two series of tetranuclear {Fe(III)(2)Ln(III)(2)} coordination clusters possessing defect-dicubane cores. A change in the synthetic procedure results in a different arrangement of the relative positions of the 3d and 4f elements offering a means…