Materials Literature
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We introduce a statistical mechanical model for the physical properties of water. Each water molecule is a two-dimensional disk with three radial hydrogen-bonding arms. Energetic interactions are based on water triplets, a central water molecule interacting with two neighbors via hydrogen bonds, van der Waals attracti…
Because of the high global warming potential of SF 6 gas, research on alternative gases for electrical insulation with a lower environmental impact is essential. Gas mixtures composed of electronegative gases and N 2 gas have the advantage of the reduction of the amount of SF 6 gas and of utilizing the synergistic eff…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTPolyphophazene Containing Indole-Based Dual Chromophores: Synthesis and Nonlinear Optical CharacterizationZhen Li, Jingui Qin, Shaojun Li, Cheng Ye, Jie Luo, and Yong CaoView Author Information Department of Chemistry, Wuhan University, Wuhan 430072, China; Center for Molecular…
We present the development of both steady-state and dynamic models for a slurry HDPE process using fundamental chemical engineering principles and advanced software tools, Polymers Plus and Aspen Dynamics. The discussion includes thermodynamic properties, phase equilibrium, reaction kinetics, polymer properties, and o…
Six permutations of 4-fold donor and/or acceptor substitution of paracyclophane at the 4, 7, 12, and 15 positions were synthesized to probe the phenomenon of three-dimensional delocalization on the nonlinear optical properties of organic materials. The interplay between through-bond intramolecular charge transfer (ICT…
The Raman spectra of strunzite, ferristrunzite and ferrostrunzite have been obtained at 298 and 77K using a combination of a thermal stage and Raman microscopy. These spectra are compared with their infrared spectra. The vibrational spectra of the two minerals are different, in line with differences in crystal structu…
We identify the physics behind the results of recent measurements [W. Kang et al., Nature 403, 59 (2000)] of electron transfer between the edges of two two-dimensional electron systems (2DES). We find that a consistent explanation of all of the observed phenomena is possible if the barrier between the 2DES is surround…
We present the magnetotransport properties of very thin (5 to 15 nm) single (Ga,Mn)As layers grown by low temperature molecular beam epitaxy. A lower (Ga,Mn)As thickness limit of 5 nm for the ferromagnetic phase and the dependence of the Curie temperature on (Ga,Mn)As thickness are determined from electrical transport…
Electronic transport in semiconducting single-wall carbon nanotubes is studied by combined scanning gate microscopy and scanning impedance microscopy (SIM). Depending on the probe potential, SIM can be performed in both invasive and non-invasive mode. High-resolution imaging of the defects is achieved when the probe a…
We carry out a self-consistent analytical theory of unipolar current and noise properties of metal-semiconductor-metal structures made of highly resistive semiconductors in the presence of an applied bias of arbitrary strength. By including the effects of the diffusion current we succeed to study the whole range of ca…
The anisotropy of MgB2 is still under debate: its value, strongly dependent on the sample and on the measuring method, ranges between 1.2 and 13. In this work we present our results on a MgB2 c-oriented superconducting thin film. To evaluate the anisotropy, we followed two different approaches. Firstly, magnetoresisti…
Quantum Monte Carlo (QMC) calculations of the optical gaps of silicon quantum dots ranging in size from 0 to 1.5 nm are presented. These QMC results are used to examine the accuracy of density functional (DFT) and empirical pseudopotential based calculations. The GW approximation combined with a solution of the Bethe-…
ZnO thin films have been deposited on Corning 7059 glass at room temperature using r.f. magnetron sputtering. Strong monochromatic blue emission located at 446 nm is observed when excited with 270 nm light. The photoluminescence intensity of the blue emission peak decreases with increasing oxygen pressure and substrat…
Single amine functionalized CdSe quantum dots were coupled to individual acid-chloride modified single-walled carbon nanotubes via amide bond formation. The quantum dot−nanotube conjugates were characterized by atomic force and transmission electron microscopies. For single-walled nanotubes with lengths of < 200 nm, b…
Electrogenerated chemiluminescence (ECL) was observed from TOPO-capped CdSe nanocrystals dissolved in CH 2 Cl 2 containing 0.1 M TBAP. The solution of monodisperse nanocrystals with an absorption maximum at 537 nm was synthesized at 330 °C using TOPO (trioctylphosphineoxide) and TOP (trioctylphosphine) as capping agen…
<div class="htmlview paragraph">NO<sub>2</sub> is an effective soot oxidizer operating at lower temperatures than O<sub>2</sub>. The effect of pure NO<sub>2</sub> on soot oxidation was evaluated and compared with the gas treated by plasma, which initially consisted of NO, O<…
We report on the changes in the defect structure of ZnO particles that take place during the grinding of pure ZnO powders and mixtures ZnO–SnO2 and ZnO–TiO2 powders. The qualitative differences in the electron paramagnetic resonance spectra for different specimens were discussed in the context of the hyper-rapid high-…
Abstract We used readily available commercial reagents and well‐known procedures to synthesize a series of aromatic imine mesogenic diglycidylester compounds with dimeric architectures. The compounds obtained were characterized by spectroscopic techniques. Their liquid‐crystalline behavior was examined by differential…
In situ synchrotron x-ray scattering is used in conjunction with a novel annular cone and plate shear cell to study the nonequilibrium structure factor of a polymer bicontinuous microemulsion within the flow-gradient plane. At equilibrium the scattering is well described by the Teubner-Strey structure factor. In stead…
Bi 4 Ti 3 O 12 – SrBi 4 Ti 4 O 15 (BT–SBTi) thin film was fabricated successfully on Pt/TiO2/SiO2/Si(110) substrates by the pulsed laser deposition technique. Films annealed at 650 °C by the rapid temperature process (RTP) have Pr=12 μC/cm2. But, the fatigue behavior has been observed although no obvious decrease in P…