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This article reviews published data on the mechanical properties of additively manufactured metallic materials. The additive manufacturing techniques utilized to generate samples covered in this review include powder bed fusion (e.g., EBM, SLM, DMLS) and ...Read More
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-driving-force electron transfer in metalloproteins: intramolecular oxidation of ferrocytochrome c by Ru(2,2'-bpy)2(im)(his-33)3+I Jy Chang, Harry B. Gray, and Jay R. WinklerCite this: J. Am. Chem. Soc. 1991, 113, 18, 7056–7057Publication Date (Print):August 1, 1991Publi…
The mechanism of diamond growth by hot-filament chemical vapor deposition (CVD) was investigated on the (100), (111), and (110) crystal faces of natural diamond by competition studies using carbon-13-labeled methane and carbon-12 acetylene. Homoepitaxial growth rates of 0.4, 0.5, and 1.3 μm/h were obtained for growth…
The reaction of NO and CO on Pt(100) exhibits two branches of steady state production of N2 and CO2 and the occurrence of kinetic oscillations. This system was studied under steady flow conditions in the 10−6 mbar total pressure range using low-energy electron diffraction-(LEED), work function measurement, and mass sp…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic and asymmetric epoxidation of olefins with iron complexes of twin-coronet porphyrins. A mechanistic insight into the chiral induction of styrene derivativesYoshinori Naruta, Fumito Tani, Nobuo Ishihara, and Kazuhiro MaruyamaCite this: J. Am. Chem. Soc. 1991, 113, 1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic asymmetric epoxidation of unfunctionalized alkenes using the first D4-symmetric metallotetraphenylporphyrinRonald L. Halterman and Shyi Tai JanCite this: J. Org. Chem. 1991, 56, 18, 5253–5254Publication Date (Print):August 1, 1991Publication History Published onlin…
Effects of aluminum, magnesium, and fluoride (AMF) on members of both the trimeric G protein and smaller (20-25 kDa) monomeric GTP-binding protein families were examined. The dissociation of GDP from G proteins was blocked by AMF but was unchanged with the addition of AMF to any of six of the monomeric GTP-binding pro…
Abstract Polymer networks which can be “de‐crosslinked” in a controlled way, i.e. at a given moment and under chosen experimental conditions, have a number of potential applications such as temporary protective coatings and erodable bio‐materials. If the de‐crosslinking occurs by scission of bonds which differ from th…
The cyclic-hardening behavior of polycrystalline Cu-16at.%Al alloy has been investigated with special reference to the back-stress and friction stress behavior and discussed in relation to the behavior of single crystals. The friction stress in the polycrystalline anlloy measured by thge Cottrell method (42 MPa) at th…
The structural genes of two homologous enzymes, 6-aminohexanoate-dimer hydrolase (EII; nylB) and its evolutionally related protein EII' (nylB') of Flavobacterium sp. KI72 have an open reading frame encoding a peptide of 392 amino acids, of which 47 are different, and conserved restriction sites. The specific activity…
Abstract Theoretical and experimental investigations are made of the band structure of proustite (Ag 3 AsS 3 ). The calculation is performed using the tight‐binding method. As scale factors in the corresponding secular equation the experimental results of VUV‐reflection are used in the spectral region 2 to 30 eV. The…
DSC and optical microscopic studies show that the mixtures of two nonmesogenic compounds, viz., cetyl alcohol and orthophosphoric acid, exhibit polymorphic smectic mesophases at different temperatures. With the help of phase diagrams of this binary mixture, the phase behavior is discussed. The X-ray studies at differe…
Computerised glow curve fitting, the variable heating rate method, Tm-Tstop procedure and the dose variation method are used to determine the number of peaks, the order of kinetics, the activation energy E and the attempt-to-escape frequency s associated with the glow peaks in single crystals of CaF2:Tm (TLD-300). Dos…
Abstract Thermal diffusivity D of filler‐polyimide composites was investigated using flash radiometry. The fillers used were: diamond, alumina, boron nitride, aluminium nitride, silicon carbide, and silicon carbide whiskers, Composite films were prepared by casting a polyamic acid solution with dispersed filler on a g…
Abstract The effect of electrolyte concentration, exchangeable sodium percentage (ESP), sodium adsorption ratio (SAR), and pH on the flocculation-dispersion behavior of 50/50 mixtures of reference illite with reference kaolinite or reference montmorillonite was investigated. The clays were Na- or Ca-saturated and free…
This is the second of two papers describing the method and application of numerical modeling of the galvanic corrosion problem. The first paper4 derived the partial differential equation and boundary conditions governing this phenomenon. This paper describes the formulation of the finite-element method to solve that b…
The temperature variation of the thermal conductivity of six samples of pitch-derived carbon fibers has been measured in the temperature range 3T300 K. The lattice thermal conductivity has been fitted, with boundary and point-defect scattering for the phonons taken into consideration. It is shown that the in-plane coh…
Abstract The extent of illite/smectite (I/S) reactions is linked with quantitative measurements of shale fabric in a suite of samples from a lower Frio Formation well. Greater illitization of the I/S clays is found in laminated shales that possess a larger pore surface area/pore volume (SA/V) of 3.21 × 10 6 cm −1 than…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPoly(hydroxybutyrate) in vivo: NMR and x-ray characterization of the elastomeric stateStuart R. Amor, Trevor Rayment, and Jeremy K. M. SandersCite this: Macromolecules 1991, 24, 16, 4583–4588Publication Date (Print):August 1, 1991Publication History Published online1 May 200…
This article reviews published data on the mechanical properties of additively manufactured metallic materials. The additive manufacturing techniques utilized to generate samples covered in this review include powder bed fusion (e.g., EBM, SLM, DMLS) and ...Read More