Materials Literature
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4-Azidoproline (Azp) can tune the stability of the polyproline II (P(II)) conformation in collagen. The azido group in the 4R and 4S configurations stabilizes and destabilizes the P(II) conformation, respectively. To obtain insights into the dependence of the conformational stability on the azido configuration, we car…
This paper presents studies on the use of carbon nanotubes dispersed in an insulating fluid to serve as an automaton for healing open-circuit interconnect faults in integrated circuits. The physics behind the repair mechanism is the electric-field-induced diffusion limited aggregation. On the occurrence of an open fau…
We report on the fabrication and characterization of planar waveguides in an Er-doped tungsten-tellurite glass by implantation of 3.5 MeV N+ions. Implantations were carried out in a wide fluence range of 1·1016÷8 ·1016ions/cm2. Waveguides were characterized by m-line spectroscopy and spectroscopic ellipsometry. Irradi…
SBA-15 silica supported rhenium catalysts were synthesized using solution-based atomic layer deposition method, and their activity and stability were studied in the acid-catalyzed 2-butanol dehydration. We find that ReO x /SBA-15 exhibited an extremely high initial activity but a fast deactivation for 2-butanol dehydr…
A surface plasmon resonance (SPR) sensor using a molecularly imprinted polymer (MIP) film as a recognition element for detection of 2,4,6-trinitrotoluene (TNT) was developed. The TNT-imprinted polymer film was prepared by thermo initiated polymerization on the bare Au surface of an SPR sensor chip. Template TNT molecu…
This study concerns single-site heterogeneous photocatalysts, composed of isolated transition metals ions (single-sites) dispersed on silica-based supports, which can be used as photocatalysts. The first part gives the definition of single-site heterogeneous catalysts. The main difficulty to prepare the latter resides…
Carbon nanotube (CNT) transistor arrays were fabricated on plastic films by printing. All the device elements were directly patterned by maskless printing without any additional patterning process, and minimum materials were used. During fabrication, the morphology of the CNT random network was controlled by an adsorp…
Ribose-1,5-bisphosphate isomerase (R15Pi) is a novel enzyme recently identified as a member of an AMP metabolic pathway in archaea. The enzyme converts d-ribose 1,5-bisphosphate into ribulose 1,5-bisphosphate, providing the substrate for archaeal ribulose-1,5-bisphosphate carboxylase/oxygenases. We here report the cry…
Onaka has shown (2010) that the Hencky equivalent strain is the appropriate quantity to represent the degree of severe plastic deformation based on simple-shear deformation. In a recent paper, Shrivastava et al. have criticized (2011) the Onaka paper and stated that the Hencky formulation does not apply to large simpl…
We demonstrate the first optical parametric oscillator (OPO) based on chalcogenide glass. The parametric gain medium is an As(2)Se(3) chalcogenide microwire coated with a layer of polymer. The doubly-resonant OPO oscillates simultaneously at a Stokes and an anti Stokes wavelength shift of >50 nm from the pump waveleng…
Structures and field emission (FE) properties of exfoliated multilayered graphene have been investigated by in situ transmission electron microscopy (TEM) and field emission microscopy (FEM). TEM revealed that edges of multilayered graphene, which were open before FE measurement, became closed after FE under high emis…
The elemental composition of thin Fe‐Ni alloy films deposited on silicon substrates were determined by electron probe microanalysis with an energy dispersive spectrometer using the STRATAGem software. The work was part of ample inter‐laboratory comparisons organized in the frame of CCQM/SAWG (Consultative Committee fo…
Photoremovable protecting groups (PPGs) when conjugated to biological effectors forming "caged compounds" are a powerful means to regulate the action of physiologically active messengers in vivo through 1-photon excitation (1PE) and 2-photon excitation (2PE). Understanding the photodeprotection mechanism is important…
Abstract The tensile and impact performance of intimately mixed (IM) hybrid composites based on glass fiber (GF) and pineapple leaf fiber (PALF) was investigated. The composite was fabricated at constant volume fraction of fiber 0.3 V f (fiber 0.3 and matrix 0.7). Keeping the volume fraction of matrix a constant (0.7…
Abstract This study presented a new way to prepare expandable graphite (EG), which is one kind of halogen‐free flame retardant using the H 2 O 2 ‐hydrothermal process. Natural graphite was immersed in H 2 O 2 and then put in autoclave to proceed the hydrothermal process. The EG was called as H 2 O 2 ‐HEG from the H 2…
Abstract The crystal growth process is modeled considering the concentration of solvent and solute in the solution. Molecular dynamics (MD) is performed to model the solvent effect on crystal morphology. Molecular modeling is used as tool to estimate the face growth rates of a crystal. Investigations on the liquid pha…
The discovery of high temperature superconductivity in FeAs and FeSe based compounds has once again focused the condensed matter community on the need to systematically explore compounds containing chalcogens and pnictogens. Whereas some solution growth techniques have been developed to handle P and As, and Sb and Bi…
ABSTRACT A moth‐eye anti‐reflective structure was fabricated by hot‐embossing and UV nanoimprint lithography on a solar cell protective film to suppress the reflection of incident light. Moreover, a superhydrophobic surface was developed by reducing the surface energy by forming a hydrophobic self‐assembled monolayer…
Abstract Using a two-step fabrication technique (pulsed laser deposition (PLD) and H 2 surface treatment), we fabricated ZnO thin films that could emit ultra-strong green emission with coexistence of random lasing phenomenon. After PLD deposition, the as-prepared undoped ZnO thin films (200–500 nm) were annealed in Ar…
Two new one-dimensional heterometallic complexes, [Mn(3)Na(L)(4)(CH(3)CO(2))(MeOH)(2)](ClO(4))(2)·3H(2)O (1), [Mn(3)Na(L)(4)(CH(3)CH(2)CO(2))(MeOH)(2)](ClO(4))(2)·2MeOH·H(2)O (2) [LH(2) = 2-methyl-2-(2-pyridyl)propane-1,3-diol], have been synthesized and characterized by X-ray crystallography. Both complexes feature M…