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Identification of Substitution Mechanism in Group VIII Metal Oxides Doped Pb ( Zn 1/3 Nb 2/3 ) O 3 – PbZrO 3 – PbTiO 3 Ceramics with High Energy Density and Mechanical Performance

Mupeng Zheng、Yudong Hou、Sai Wang 等 6 位作者2013-04-19Journal of the American Ceramic Society

Group VIII metal oxides, that is, Fe 2 O 3 , Co 2 O 3 , and NiO have been introduced to 0.2 Pb ( Zn 1/3 Nb 2/3 ) O 3 –0.8 Pb ( Zr 0.50 Ti 0.50 ) O 3 ( PZN – PZT ) to deterministically identify the substitution mechanism and meantime to tailor mechanical and piezoelectric properties in obtaining energy harvesting mater…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric properties of ceramics

Band Gap Engineering of BN Sheets by Interlayer Dihydrogen Bonding and Electric Field Control

Qing Tang、Zhen Zhou、Pan‐Wen Shen 等 4 位作者2013-04-19ChemPhysChem

An unconventional bonding: The presence of interlayer B-H⋅⋅⋅H-N dihydrogen bonds in hydrogenated bilayer BN nanosheets reduces the intrinsic large band gap of the chair-type BN conformation owing to interlayer charge transfer. In contrast, the insulating properties of the thermodynamically more stable stirrup-type bil…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Synthesis and Functionalization of Triply Fused Porphyrin Dimers

Aoife A. Ryan、Mathias O. Senge2013-04-19European Journal of Organic Chemistry

Abstract Current applications of porphyrins in medicine and optics, such as photodynamic therapy or nonlinear absorption, increasingly require the use of far‐red absorbing dyes. Modification of the porphyrin structure to accommodate these conditions can be achieved by extending the conjugation of the porphyrin π syste…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Heterobimetallic Lantern Complexes That Couple Antiferromagnetically through Noncovalent Pt···Pt Interactions

Frederick G. Baddour、Stephanie R. Fiedler、Matthew P. Shores 等 6 位作者2013-04-19Inorganic Chemistry

A series of Pt-based heterobimetallic lantern complexes of the form [PtM(SAc)4(OH2)] (M = Co, 1; Ni, 2; Zn, 3) were prepared using a facile, single-step procedure. These hydrated species were reacted with 3-nitropyridine (3-NO2py) to prepare three additional lantern complexes, [PtM(SAc)4(3-NO2py)] (M = Co, 4; Ni, 5; Z…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Strong Visible‐Light Absorption and Hot‐Carrier Injection in TiO2/SrRuO3 Heterostructures

Sungki Lee、Brent A. Apgar、Lane W. Martin2013-04-19Advanced Energy Materials

Abstract Correlated electron oxides prove a diverse landscape of exotic materials' phenomena and properties. One example of such a correlated oxide material is strontium ruthenate (SrRuO 3 ) which is known to be a metallic itinerant ferromagnet and for its widespread utility as a conducting electrode in oxide heterost…

Advanced Photocatalysis TechniquesAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

The effect of quantum size confinement on the optical properties of PbSe nanocrystals as a function of temperature and hydrostatic pressure

Esteban Pedrueza‐Villalmanzo、A. Segura、Rafael Abargues 等 6 位作者2013-04-19Nanotechnology

A study based on photoluminescence and absorption measurements as a function of temperature and pressure for PbSe nanocrystals with sizes in the range 3-13 nm reveals the influence of size quantum confinement on the observed variation. In the case of the temperature variation, the effective bandgap changes from showin…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Rationally Designed Calix[4]arene–Pyrrolotetrathiafulvalene Receptors for Electron-Deficient Neutral Guests

Matthias H. Düker、Hannes Schäfer、Mat­thias Zeller 等 4 位作者2013-04-19The Journal of Organic Chemistry

Four upper rim bis-monopyrrolotetrathiafulvalene-calix[4]arene conjugates 2a,b and 3a,b have been efficiently synthesized using a modular construction approach. The new compounds feature a molecular tweezer architecture with a quasi-parallel arrangement of redox-active tetrathiafulvalene (TTF) arms, which serve as the…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesOrganic and Molecular Conductors Research

Development of a stochastic constitutive model for prediction of postyield softening in glassy polymers

Grigori A. Medvedev、James M. Caruthers2013-04-19Journal of Rheology

A stochastic constitutive model has been developed that explicitly acknowledges the nanometer size dynamic heterogeneity of glassy materials, where the distribution of the viscoelastic relaxation times emerges naturally as a result of the dynamic heterogeneity. A set of stochastic differential equations for local stre…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesStructural Analysis of Composite Materials

Ferromagnetism in Mn half-doped LaCrO3 perovskite

Petrucio Barrozo、Jeffery A. Aguiar2013-04-19Journal of Applied Physics

In this work, we present results on the structural, electrical, and magnetic properties of pure and half-doped LaCrO3 compounds. It is observed that including Mn the lattice structure changes from orthorhombic to rhombohedral. The electrical transport in LaCrO3 can be described by a band gap model, whereas in La2CrMnO…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Poly(N-isopropyl acrylamide) Brush Topography: Dependence on Grafting Conditions and Temperature

Byun Chan Choi、Sungwook Choi、Deborah Leckband2013-04-19Langmuir

The topography of poly (N-isopropyl acrylamide) brushes end-grafted from initiator-terminated monolayers was imaged by atomic force microscopy, as a function of the area per chain and of solvent quality. Measurements were done in air and in water, below and above the lower critical solution temperature. At low graftin…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Ultrafast formation and decay dynamics of trions inp-doped single-walled carbon nanotubes

Takeshi Koyama、Satoru Shimizu、Yasumitsu Miyata 等 5 位作者2013-04-19Physical Review B

We present the formation and decay dynamics of a trion (charged exciton) and exciton system in chemically $p$-doped single-walled carbon nanotubes (SWNTs) investigated by time-resolved photoluminescence measurements at 300 K. In (6,5) SWNTs with hole densities in the range of 0.27--1.05 nm${}^{\ensuremath{-}1}$, a tri…

Carbon Nanotubes in CompositesSilicon Nanostructures and PhotoluminescenceMechanical and Optical Resonators

Applications of Biomaterials to Liquid Crystals

Kazuki Iwabata、Urara Sugai、Yasutaka Seki 等 5 位作者2013-04-19Molecules

Nowadays, chemically synthesized proteins and peptides are attractive building blocks and have potential in many important applications as biomaterials. In this review, applications of biomaterials to thermotropic liquid crystals are discussed. The review covers the improvement of the performance of liquid crystal dis…

Liquid Crystal Research AdvancementsLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Optical Active Nano‐Glass‐Ceramics

Takayuki Komatsu、Tsuyoshi Honma2013-04-19International Journal of Applied Glass Science

This paper reviews the synthesis and characterization of several transparent glass‐ceramics with optical active nanocrystals. Glass‐ceramics containing ferroelectric S r x B a 1‐x N b 2 O 6 nanocrystals with an ellipsoidal shape show optical phase modulations in the presence of alternative electric fields. In the glas…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Mixed protein-templated luminescent metal clusters (Au and Pt) for H2O2 sensing

Min Li、Da‐Peng Yang、Xiansong Wang 等 5 位作者2013-04-19Nanoscale Research Letters

A simple and cost-effective method to synthesize the luminescent noble metal clusters (Au and Pt) in chicken egg white aqueous solution at room temperature is reported. The red-emitting Au cluster is used as fluorescent probe for sensitive detection of H2O2.

Advanced biosensing and bioanalysis techniquesNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Nondestructive Characterization of Graphene Defects

Thuc Hue Ly、Dinh Loc Duong⧫、Huy Q. Ta 等 8 位作者2013-04-19Advanced Functional Materials

Abstract An effective method is reported for oxidizing graphene/copper film in which air oxidation of the underlying copper film occurs through the grain boundary lines of graphene without oxidizing graphene. This oxidation is realized by partially immersing the graphene/copper film in sodium chloride solution. Electr…

Graphene research and applicationsSemiconductor materials and devicesIon-surface interactions and analysis

Bio-fabrication of gold nanoparticles using aqueous extract of red tomato and its use as a colorimetric sensor

Gadadhar Barman、Swarnali Maiti、Jayasree Konar Laha2013-04-19Nanoscale Research Letters

In this work, we report a green method for the synthesis of gold nanoparticles (GNP) using the aqueous extract of red tomato (Lycopersicon esculentum). We believe that citric acid and ascorbic acid present in tomato juice are responsible for the reduction of gold ions. This biosynthesized GNP in the presence of sodium…

Nanoparticles: synthesis and applications

Theoretical Study of the Local Surface Plasmon Resonance Properties of Silver Nanosphere Clusters

Ye-Wan Ma、Zhao-Wang Wu、Lihua Zhang 等 6 位作者2013-04-19Plasmonics

The local surface plasmon resonance properties in systems consisting of silver nanosphere clusters are studied by Green's function. The extinction, absorption, and scattering efficiencies band of two, three, and more silver nanospheres clusters are discussed in detail. The clusters show new types of the local surface…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanocluster Synthesis and Applications

Modification on Single-Layer Graphene Induced by Low-Energy Electron-Beam Irradiation

Li Tao、Caiyu Qiu、Yu Fang 等 7 位作者2013-04-19The Journal of Physical Chemistry C

In this work, we present studies of the effects of electron-beam irradiation on the modification of single-layer graphene. Micro-Raman spectra show that the D, D′, and D + G Raman bands, which are invisible for pristine graphene, appear after the graphenes are irradiated by low-energy electron-beam irradiation (10 keV…

Advancements in Battery MaterialsGraphene research and applicationsIon-surface interactions and analysis

A Modulated Helical Nanofilament Phase

Ethan Tsai、Jacqueline M. Richardson、Eva Körblová 等 9 位作者2013-04-19Angewandte Chemie International Edition

A new liquid crystal phase, denoted modulated helical nanofilament (HNF(mod)), is formed from a very simple class of biphenyl carboxylates lacking the benzylidene aniline moieties typically found in HNF mesogens. The HNF(mod) phase represents a novel kind of nanoparticle possessing stacked aromatic rings, with potenti…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPlant Reproductive Biology

Chiroptical Activity in Silver Cholate Nanostructures Induced by the Formation of Nanoparticle Assemblies

Muriel E. Layani、Assaf Ben‐Moshe、Maxim Varenik 等 7 位作者2013-04-19The Journal of Physical Chemistry C

We report on an interesting mechanism of inducing chiroptical response at plasmonic silver nanoparticles (NPs) through the formation of plasmonic hot spots in small metal-NP–chiral-surfactant assemblies. Circular dichroism (CD) was measured at the surface plasmon resonance of cholate-coated silver nanostructures (AgCT…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Quantum Chemical StudiesMolecular spectroscopy and chirality