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On the slow dynamics for the Cahn–Hilliard equation in one space dimension

Lia Bronsard、Dorothea Hilhorst1992-12-08Proceedings of the Royal Society of London Series A Mathematical and Physical Sciences

Abstract We study the limiting behaviour of the solution of the Cahn-Hilliard equation using ‘energy-type methods'. We assume that the initial data has a ‘transition layer structure’, i.e. uϵ ≈ ± 1 except near finitely many transition points. We show that, in the limit as ϵ → 0, the solution maintains its transition l…

Nonlinear Partial Differential EquationsSolidification and crystal growth phenomenaAdvanced Mathematical Modeling in Engineering

Sol-gel-processed inorganic oxides: organic polymer composites for second-order nonlinear optical applications

Jaroslaw Zieba、Yue Zhang、Paras N. Prasad 等 5 位作者1992-12-07Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A new class of promising composite materials consisting of sol-gel processed inorganic oxides and organic polymers has been developed over the last several years. These materials have been shown to be homogeneous, mechanically stable and have excellent optical properties. Second-order nonlinear optical properties are…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Scratch-resistant single-layer antireflective coating by a low-temperature sol-gel route

Hervé G. Floch、Philippe Belleville1992-12-07Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A novel quarterwave-thick narrow-bandwidth antireflective coating has been developed for both plastic and vitreous substrates by a sol-gel route. This coating has revealed pronounced scratch- and climatic-resistances under adverse conditions. The single-layer coating consists basically of a composite material made of…

Surface Modification and SuperhydrophobicityOptical Coatings and GratingsSilicone and Siloxane Chemistry

Theory of energy loss in scanning transmission electron microscopy of supported small particles

A. Rivacoba、Nerea Zabala、P. M. Echenique1992-12-07Physical Review Letters

A general expression for the energy loss probability in scanning transmission electron microscopy (STEM) is derived. The method uses a Green's function for the incident and scattered electrons and then folds the specimen into a local response function. Our expression is appropriate to any target geometry and dielectri…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Temperature and hydrostatic pressure dependences of the b40spin-Hamiltonian parameter for Gd3+in fluoroperovskite single crystals

T. Rewaj、M. Krupski、J. Kuriata 等 4 位作者1992-12-07Journal of Physics Condensed Matter

Both the temperature and the pressure dependences of the b 4 0 spin-Hamiltonian parameter for RbCaF 3 , CsCaF 3 , RbCdF 3 and TlCdF 3 doped with Gd 3+ have been reported. On the assumption that b 4 0 depends on the metal-ligand distance according to a law b 4 0 approximately r k the following values of k were obtained…

Solid-state spectroscopy and crystallographyInorganic Fluorides and Related CompoundsThermal Expansion and Ionic Conductivity

Magnetic structure of the Laves phase compound TiFe2

P. J. Brown、J. Déportes、B. Ouladdiaf1992-12-07Journal of Physics Condensed Matter

The magnetic structure of TiFe 2 which crystallizes with the C15 Laves phase structure has been determined from neutron diffraction measurements made on both single-crystal and polycrystalline samples. In the antiferromagnetic structure the Fe2 atoms in the (6h) sites with the same z coordinate are coupled ferromagnet…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Growth of a self-assembled monolayer by fractal aggregation

Daniel K. Schwartz、Suzi Steinberg、Jacob N. Israelachvili 等 4 位作者1992-12-07Physical Review Letters

Atomic force microscope images show that self-assembled monolayers of octadecyltrichlorosilane form on mica by nucleating isolated, self-similar domains. With increasing coverage, the fractal dimension of the growing domains evolves from 1.6 to 1.8. At higher coverage, continued growth is limited by adsorption from so…

Molecular Junctions and NanostructuresBlock Copolymer Self-Assemblynanoparticles nucleation surface interactions

Investigation of Dynamics of Faradaic Processes in Polypyrrole Films by Electrochemical Impedance and Color Admittance Spectroscopies

Takashi Amemiya、Kazuhito Hashimoto、Akira Fujishima1992-12-05Denki Kagaku oyobi Kogyo Butsuri Kagaku

Dynamics of faradaic processes in polypyrrole(PPy)fims depending on the thickness of the films and on applied dc potentials have been investigated by ac electromodulation spectroscopy techniques The comparison of the capacitance plots derived from the impedance plots with the modulated transmittance (color admittanceT…

Conducting polymers and applications

Transmittance and mechanical properties of PMMA‐fumed silica composites

Bennet Abramoff、J. Covino1992-12-05Journal of Applied Polymer Science

Abstract The transmittance, flexure strength, Young's modulus, and Vickers hardness of poly(methyl methacrylate) (PMMA), filled with fumed silica, was measured. Transmittance decreased with increasing content of filler. At 2 vol % filler content, composites had a higher transmittance with a lower surface area of fumed…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Solvent effect on the curing of polyimide resins

Tzu‐Chien Hsu、Zu‐Ling Liu1992-12-05Journal of Applied Polymer Science

Abstract The effect of the solvent 1‐methyl‐2‐pyrrolidinone (NMP) on the curing of polyimide resins synthesized from pyromellitic dianhydride (PMDA) and 4,4′‐oxydianiline (ODA) has been investigated. Three polyimide precursors, i.e., the polyamic acid (PAA), with controlled amount of NMP were prepared. The study was a…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersThermal and Kinetic Analysis

Terrestrial Carbon and Nitrogen Isotopic Ratios from Cretaceous-Tertiary Boundary Nanodiamonds

I. Gilmour、S. S. Russell、J. W. Arden 等 6 位作者1992-12-04Science

One hypothesis for the origin of the nanometer-size diamonds found at the Cretaceous-Tertiary (K-T) boundary is that they are relict interstellar diamond grains carried by a postulated asteroid. The (13)C/(12)C and (15)N/(14)N ratios of the diamonds from two sites in North America, however, show that the diamonds are…

Geological and Geochemical AnalysisAstro and Planetary ScienceDiamond and Carbon-based Materials Research

Opportunities for Lignocellulosic Materials and Composites

Roger M. Rowell1992-12-04ACS symposium series

High performance lignocellulosic composites with uniform densities, durability in adverse environments, and high strength can be produced by using fiber technology, bonding agents, and fiber modification to overcome dimensional instability, biodegradability, flammability, and degradation caused by ultraviolet light, a…

Natural Fiber Reinforced CompositesLignin and Wood Chemistry

The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2

E. Cannillo、G. Giuseppetti、F. Mazzi 等 4 位作者1992-12-01Zeitschrift für Kristallographie - Crystalline Materials

Article The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2 was published on December 1, 1992 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 202, issue 1-4).

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds

Poly (methyl methacrylate) by XPS

J. F. Moulder、William F. Stickle、P. E. Sobol1992-12-01Surface Science Spectra

XPS measurements are presented for poly (methyl methacrylate). The data include the valence band region and the principal core levels.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Poly (ethyl methacrylate) by XPS

J. F. Moulder、William F. Stickle、P. E. Sobol1992-12-01Surface Science Spectra

XPS measurements for poly (ethyl methacrylate). The data include the valence band region and the principal core levels.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Coquandite, Sb6O8(SO4).H2O, a new mineral from Pereta, Tuscany, Italy, and two other localities

C. Sabelli、Paolo Orlandi、Giovanna Vezzalini1992-12-01Mineralogical Magazine

Abstract Coaquandite, a new antimony oxy-sulphate hydrate, occurs as spheroidal knobs of silky fibres or, rarely, as tiny transparent colourless lamellar crystals on stibnite at the Pereta mine, Tuscany, Italy; it is associated with klebelsbergite, peretaite, valentinite, sulfur, gypsum, stibiconite, and senarmontite.…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Pyroelectric properties of lead zirconate titanate based ceramics with a rhombohedral ferroelectric phase transition

Jingyu Lian、Tadashi Shiosaki1992-12-01Ferroelectrics

The lead zirconate rich lead zirconate titanate based ceramics present high pyroelectric coefficient as well as low dielectric constant in their rhombohedral ferroelectric phase transitions, and therefore possess many desirable properties for potential applications in pyroelectric devices. The dielectric, pyroelectric…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Production of unusual bacterial polyesters by Pseudomonas oleovorans through cometabolism

Robert W. Lenz1992-12-01FEMS Microbiology Letters

Pseudomonas oleovorans is an adaptable, aerobic bacterium that can produce a wide range of storage polyesters (poly-β-hydroxyalkanoates, PHAs). With few exceptions, the PHAs obtained when this bacterium is grown with single organic substrates capable of polymer production are generally copolymers. With two different p…

Bacterial biofilms and quorum sensingbiodegradable polymer synthesis and propertiesAntimicrobial agents and applications

NONDESTRUCTIVE MEASUREMENT OF MOISTURE DIFFUSION COEFFICIENT IN WOOD DRYING

Yasushi KANAGAWA1992-12-01Drying Technology

The computer tomography(CT image of wood was analyzed to estimate the moisture content from CT number. Comparing moisture contents, densities and CT numbers, moisture distributions were nondestructively determined by CT numbers detected with the scanner. By periodically measuring CT images of the same cross section of…

Wood Treatment and PropertiesTextile materials and evaluations

Chemical Vapor Deposition of Cu Film on SiO2 Using Cyclopentadienylcoppertriethylphosphine

Shigefusa F. Chichibu、Nobuhide Yoshida、Hirofumi Higuchi 等 4 位作者1992-12-01Japanese Journal of Applied Physics

Chemical vapor deposition of Cu film on SiO 2 has been studied using cyclopentadienylcoppertriethylphosphine (C 5 H 5 CuP(C 2 H 5 ) 3 ), which contains no oxygen atom itself. The deposited Cu films had complete (111) preferred orientation for deposition temperatures below 450°C. From Auger electron spectroscopy measur…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability