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GPC studies on the cationic polymerization of cardanol initiated by borontrifluoridediethyletherate

Rosy Antony、C. K. S. Pillai、K. J. Scariah1990-01-01Journal of Applied Polymer Science

Abstract The cationic polymerization of cardanol using borontrifluoridediethyletherate as initiator has been investigated by gel permeation chromatographic techniques. The molecular weight and molecular weight distribution of the polymer at different temperatures and various initiator concentrations were studied, and…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Science and PVC

Neutron powder investigation of CuI*

Yude Yu、H. Boysen、H. Schulz1990-01-01Zeitschrift für Kristallographie

CuI is known to undergo two phase transitions at T 1 = 367°C and T 2 = 407°C. The structural changes involve a rearrangement of the anions and disordered distributions of the cations. The low temperature γ -phase has zincblende structure, space group F [unk]3 m [ a = 6.0337(3) Å, Z = 4]. The intermediate β -phase belo…

Quasicrystal Structures and PropertiesCopper-based nanomaterials and applicationsX-ray Diffraction in Crystallography

Bacterial iron enhances oxygen radical-mediated killing of Staphylococcus aureus by phagocytes

I. M. Hoepelman、W. A. Bezemer、Christina M. J. E. Vandenbroucke‐Grauls 等 5 位作者1990-01-01Infection and Immunity

It has been shown that increasing bacterial iron concentration enhances killing by hydrogen peroxide (H2O2) but not by polymorphonuclear granulocytes (PMN). It is possible that owing to the multiple bactericidal mechanisms of the PMN, differences in the killing rate of iron-loaded bacteria and control bacteria are obs…

Nanoparticles: synthesis and applicationsBacterial biofilms and quorum sensingGraphene and Nanomaterials Applications

Insulation Materials, Testing and Applications

D. L. McElroy、J. F. Kimpflen1990-01-01OpenAlex

Description STP 1030 provides the insulation community with an update on residential, commercial, and industrial application. Includes 50 papers on new materials assessments and properties of foams, properties and models, loose-fill behavior, systems performance testing, building applications and user interests, and i…

High voltage insulation and dielectric phenomena

The formation of hydroxy monocarboxylic acids and dicarboxylic acids by alkaline thermochemical degradation of cellulose

Klaus Niemelä1990-01-01Journal of Chemical Technology & Biotechnology

Abstract Treatment of cotton cellulose with 3 M sodium hydroxide solution at 260°C and 280°C gave a mixture of carboxylic acids with a yield of > 95%. The identified 50 carboxylic acids included both hydroxy monocarboxylic acids and dicarboxylic acids; their routes of formation are discussed. Among the main compoun…

Advanced Cellulose Research StudiesDyeing and Modifying Textile Fibers

Styrene-based plastics and their modification

Petr Švec1990-01-01E. Horwood eBooks

Polystrene modification of chemical resistance modification of impact properties - of average density and thermoinsulating properties - of durability - of flammability - of electrical conductivity - of rheological properties - of strength characteristics - of heat resistance.

Material Properties and Applications

Plasticity of MGSIO3 perovskite: The results of microhardness tests on single crystals

Shun‐ichiro Karato、Kiyoshi Fujino、Eiji Ito1990-01-01Geophysical Research Letters

The Plasticity of single crystals of MgSiO 3 perovskite was studied (at room temperature) by the microhardness tests using a Vickers and a Knoop indenter. The Vickers hardness, H v , of MgSiO 3 perovskite was determined to be 18 +/− 2 GPa, about a factor of two larger than the hardness of either enstatite or olivine,…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsElectronic and Structural Properties of Oxides

Changes in secondary structure follow the dissociation of human insulin hexamers: A circular dichroism study

Steen Melberg、W. Curtis Johnson1990-01-01Proteins Structure Function and Bioinformatics

Vacuum UV circular dichroism spectra measured down to 178 nm for hexameric 2-zinc human insulin, zinc-free human insulin, and the two engineered and biologically active monomeric mutants, [B/S9D] and [B/S9D,T27E] human insulin, show significant differences. The secondary structure analysis of the 2-zinc human insulin…

DNA and Nucleic Acid ChemistryCarbohydrate Chemistry and SynthesisEnzyme Structure and Function

Di-and tri-palladium( II ) polyazacycloalakane complexes. A case of deprotonated secondary nitrogen in solution and in solid state

Andrea Bencini、Antonio Bianchi、Paolo Dapporto 等 7 位作者1990-01-01Journal of the Chemical Society Chemical Communications

Crystal structures of di- and tri-nuclear palladium(II) complexes with the azamacrocycles[18]aneN6 and [21]aneN7 have been solved by X-ray analysis; in the case of the trinuclear complex deprotonation of a secondary amino group occurs, both in solution and in the solid state.

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesSynthesis and Characterization of Heterocyclic Compounds

Selection and Application of Magnesium and Magnesium Alloys

Susan E. Housh、Barry A. Mikucki、Archie Stevenson1990-01-01ASM International eBooks

Abstract Magnesium and magnesium alloys are used in a wide variety of structural and nonstructural applications. This article provides information on selection and application of magnesium and magnesium alloys, mainly, casting alloys and wrought alloys. It also provides tabulated data for the composition, properties o…

Magnesium Alloys: Properties and Applications

Synthesis of Poly(Methacrylic Acid‐)Starch Graft Copolymers Using Mn‐IV‐Acid System

M. I. Khalil、Khaled Mostafa、A. Hebeish1990-01-01Starch - Stärke

Abstract When starch was treated with KMnO 4 solution, MnO 2 was deposited overall the starch. The amount of MnO 2 deposited relied on the KMnO 4 concentration. Subjecting the MnO 2 ‐containing starch to a solution consisting of monomer (methacrylic acid, MAA) and acid (citric, tartaric, oxalic or sulphuric acid) resu…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Polyesters Based on Glyceric Acid Derivatives as Potential Biodegradable Materials

Emo Chiellini、Simonetta Faggioni、Roberto Solaro1990-01-01Journal of Bioactive and Compatible Polymers

The preparation of racemic and optically active glyceric acid de rivatives as suitable precursors for the formulation of a new class of bioerodible and/or biodegradable polymers is described. Details are provided for the prepa ration of chiral 3-0-alkyl substituted methyl glycerates and on their potential to form the…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Thermogravimetric Analysis of Minerals

D. L. Bish、C.J. Duffy1990-01-01Clay Minerals Society eBooks

Abstract Thermogravimetric analysis (TGA), in which the mass of a sample is monitored as a function of temperature, is one of the oldest analytical techniques used in clay mineralogy. One of the first applications to the study of minerals was reported in 1903 by Nernst and Riesenfeld. Since then, TGA has been used to…

Radioactive element chemistry and processingThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Infrared study of the adsorption of NO, NO2 and CO on Rh/Al2O3 catalysts

James A. Anderson、Graeme J. Millar、Colin H. Rochester1990-01-01Journal of the Chemical Society Faraday Transactions

Infrared spectra of NO, NO2 and CO adsorbed on Rh/Al2O3 have been recorded in order to identify the role of surface Rh—NO+ species in the reactions of NO and CO on Rh surfaces. Rh—NO+ was generated by thermally activated adsorption of NO, adsorption of NO on oxidised Rh or by adsorption of NO2. The latter also gave ad…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Synthesis, electrochemistry, and magnetic properties of binuclear cobalt complexes containing the Co 2 (µ-X)(µ-carboxylato) 2 n+ core (X = OH, Cl, or Br; n= 1–3). The crystal structures of [Co 2 II (µ-ClH 2 CCO 2 ) 2 (µ-Cl)L 2 ]PF 6 and [Co II Co III (µ-MeCO 2 ) 2 (µ-OH)L 2 ][ClO 4 ] 2 ·0.5H 2 O (L =N,N′,N″-trimethyl-1,4,7-triazacyclononane)

Phalguni Chaudhuri、Jürgen Querbach、Karl Wieghardt 等 5 位作者1990-01-01Journal of the Chemical Society Dalton Transactions

A series of novel binuclear cobalt(II) complexes containing the µ-hydroxo-bis(µ-carboxylato)-dicobalt(II) core have been prepared where each cobalt(II) centre is capped by the tridentate macrocycle N,N′,N″-trimethyl-1,4,7-triazacyclononane (L, C9H21N3): [CoII2(µ-RCO2)2L2(µ-OH)]PF6[R = Me (1); ClH2C (2), or Cl2HC (3)].…

Metal complexes synthesis and propertiesMagnetism in coordination complexesCO2 Reduction Techniques and Catalysts

Excitation spectrum, extended states, gap closing : some exact results for codimension one quasicrystals

Clément Sire、Rémy Mosseri1990-01-01Journal de physique

In this paper, we study a tight-binding Hamiltonian for codimension one quasicrystals by means of a new numbering which orders the sites according to their environment. This includes the general 1D quasiperiodic chain. We exhibit exact extended wave functions on approximants for the general quasiperiodic chain, for wh…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Effect of Hydrogen on the Shape Memory Effect and Transformation Behavior of Ti-Ni Alloy

Yoshitaka Adachi、Noboru Wade、Yuzo Hosoi1990-01-01Journal of the Japan Institute of Metals and Materials

A study has been made of the effect of hydrogen on the shape memory effect and transformation behavior of Ti-Ni alloy. The material was evaluated in the temperature range from 300 to 473 K using a bent specimen. The transformation behavior was analyzed by differential scanning calorimetry (DSC) and X-ray diffraction t…

Hydrogen Storage and Materials

ESR, XRD, and DRS studies of paramagnetic titanium(3+) ions in a colloidal solid of titanium oxide prepared by the hydrolysis of titanium trichloride

Akira Ookubo、Eiji Kanezaki、Kenta Ooi1990-01-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTESR, XRD, and DRS studies of paramagnetic titanium(3+) ions in a colloidal solid of titanium oxide prepared by the hydrolysis of titanium trichlorideAkira Ookubo, Eiji Kanezaki, and Kenta OoiCite this: Langmuir 1990, 6, 1, 206–209Publication Date (Print):January 1, 1990Publi…

Radioactive element chemistry and processingThermal and Kinetic AnalysisChemical Synthesis and Characterization

Mechanisms of hydrogen-induced losses in silica-based optical fibers

Akira Iino、M. Kuwabara、K. Kokura1990-01-01Journal of Lightwave Technology

The mechanisms of hydrogen-induced losses in silica-based fibers due to reaction are analyzed, and novel experimental results are presented. The mechanisms of hydrogen reaction with a glass structure were studied and found to be divided into two groups. One was responsible for the reaction with glass networks, not def…

Glass properties and applicationsPhotonic Crystal and Fiber OpticsMagneto-Optical Properties and Applications