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Hydrocarbon Poisoning of Cu-Zeolite SCR Catalysts

Jinyong Luo、Aleksey Yezerets、Cary Henry 等 7 位作者2012-04-13SAE technical papers on CD-ROM/SAE technical paper series

<div class="section abstract"><div class="htmlview paragraph">The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and th…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Elucidating the Effects of a Rare-Earth Oxide Shell on the Luminescence Dynamics of Er3+:Y2O3Nanoparticles

James A. Dorman、Ju Hyeon Choi、Gregory Kuzmanich 等 4 位作者2012-04-13The Journal of Physical Chemistry C

Rare-earth (RE) (Er 3+ and Yb 3+, Er 3+ )-doped yttrium oxide (Y 2 O 3 ) core–shell particles were synthesized in this work using a two-step process where the cores were formed by molten salt synthesis while the shell was deposited by a sol–gel process. The cores were 100–150 nm, and a shell layer, up to 12 nm thick,…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Soot and Ash Deposition Characteristics at the Catalyst-Substrate Interface and Intra-Layer Interactions in Aged Diesel Particulate Filters Illustrated using Focused Ion Beam (FIB) Milling

Carl Justin Kamp、Alexander Sappok、Victor W. Wong2012-04-13SAE international journal of fuels and lubricants

<div class="section abstract"><div class="htmlview paragraph">The accumulation of soot and lubrication-derived ash particles in a diesel particulate filter (DPF) increases exhaust flow restriction and negatively impacts engine efficiency. Previous studies have described the macroscopic phenomenon and gener…

Catalytic Processes in Materials ScienceElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Dynamics of stress-induced domain wall motion

M. T. Bryan、Julian S. Dean、D. A. Allwood2012-04-13Physical Review B

Magnetic domain wall motion caused by nonuniform stress in a magnetostrictive nanowire was studied using a semianalytical model. The study reveals that the axial stress gradient is responsible for domain wall motion, even in the absence of an applied magnetic field or spin-polarized current, and agrees well with previ…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Plasmonic dimer antennas for surface enhanced Raman scattering

Katja Höflich、Michael Becker、Gerd Leuchs 等 4 位作者2012-04-13Nanotechnology

Electron beam induced deposition (EBID) has recently been developed into a method to directly write optically active three-dimensional nanostructures. For this purpose a metal-organic precursor gas (here dimethyl-gold(III)-acetylacetonate) is introduced into the vacuum chamber of a scanning electron microscope where i…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Electrically Heated Catalysts for Cold-Start Emissions in Diesel Aftertreatment

Chang Hwan Kim、Michael J. Paratore、Eugene Gonze 等 5 位作者2012-04-13SAE technical papers on CD-ROM/SAE technical paper series

<div class="section abstract"><div class="htmlview paragraph">With a tighter regulatory environment, reduction of hydrocarbon (HC) and NO<sub>x</sub> emissions during cold-start has emerged as a major challenge for diesel engines. In the complex diesel aftertreatment system, more than 90% of en…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Development of biodegradable composites based on wood waste flour and thermoplastic starch

E. Agnantopoulou、V. Tserki、Sotirios I. Marras 等 5 位作者2012-04-13Journal of Applied Polymer Science

Abstract Biodegradable composites were prepared from wood flour of sawmill residues and a thermoplastic starch (Mater‐Bi™ and glycerol). For the preparation of the composites flour from sawmills of four wood species (spruce, pine, beech and poplar), three particle sizes (<150, 150–250, and 250–750 μm) and in six pr…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Design and Evaluation of a Crystalline Hybrid of Molecular Conductors and Molecular Rotors

Cyprien Lemouchi、Cécile Meźière、Leokadiya V. Zorina 等 12 位作者2012-04-13Journal of the American Chemical Society

Combining recent concepts from the fields of molecular conductivity and molecular machinery we set out to design a crystalline molecular conductor that also possesses a molecular rotor. We report on the structures, electronic and physical properties, and dynamics of two solids with a common 1,4-bis(carboxyethynyl)bicy…

Magnetism in coordination complexesCrystallography and molecular interactionsOrganic and Molecular Conductors Research

Facile synthesis of superhydrophobic surface of ZnO nanoflakes: chemical coating and UV-induced wettability conversion

Lujun Yao、Maojun Zheng、Changli Li 等 5 位作者2012-04-13Nanoscale Research Letters

This work reports an oriented growth process of two-dimensional (2D) ZnO nanoflakes on aluminum substrate through a low temperature hydrothermal technique and proposes the preliminary growth mechanism. A bionic superhydrophobic surface with excellent corrosion protection over a wide pH range in both acidic and alkalin…

ZnO doping and propertiesSurface Modification and SuperhydrophobicityAerogels and thermal insulation

Physico-Chemical Modeling of an Integrated SCR on DPF (SCR/DPF) System

Friedemann Schrade、Miles Brammer、Jochen Schaeffner 等 5 位作者2012-04-13SAE International Journal of Engines

<div class="section abstract"><div class="htmlview paragraph">A physico-chemical model of a Cu-zeolite SCR/DPF-system involving NH₃ storage and SCR reactions as well as soot oxidation reactions with NO₂ has been developed and validated based on fundamental experimental investigations on synthetic gas test…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Development and Validation of a Pt-Pd Diesel Oxidation Catalyst Model

Timothy C. Watling、Mehrdad Ahmadinejad、Monica Ţuţuianu 等 5 位作者2012-04-13SAE International Journal of Engines

<div class="section abstract"><div class="htmlview paragraph">The Diesel Oxidation Catalyst (DOC) is an important technology for the removal of CO and hydrocarbons (HC) from the exhaust of diesel engines, as well as for generating exotherms for active regeneration, and for producing NO₂ used by downstream…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

The Use of Non‐Equilibrium Plasmas for the Synthesis of Heterogeneous Catalysts

Toon Witvrouwen、Sabine Paulussen、Bert F. Sels2012-04-13Plasma Processes and Polymers

Abstract A review of published works in the field of catalyst synthesis and treatment with the use of non‐equilibrium plasma techniques has been composed. Non‐equilibrium plasmas, also called low temperature plasmas, are known for their high reactivity (high electron temperature), while keeping the overall gas tempera…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesIron oxide chemistry and applications

Thermal conductivity and secondary porosity of single anatase TiO 2 nanowire

Xuhui Feng、Xiaopeng Huang、Xinwei Wang2012-04-13Nanotechnology

Single anatase TiO₂ nanowire is synthesized using the electrospinning technique with the sol-gel method and is suspended over a pre-processed 100 µm-wide TEM grid for further characterization. The diameters of the nanowires fall in the range of 250-400 nm. The transient electrothermal (TET) method is adopted to acquir…

TiO2 Photocatalysis and Solar CellsSupercapacitor Materials and FabricationConducting polymers and applications

Scaled-up commercial production of reactive magnesium cement pressed masonry units. Part I: Production

Martin Líška、Abir Al‐Tabbaa、Kneale Carter 等 4 位作者2012-04-13Proceedings of the Institution of Civil Engineers - Construction Materials

Reactive magnesia cements have recently emerged as a potentially more sustainable and technically superior alternative to Portland cement as they set by absorbing carbon dioxide and as a result gain significant strength. This two-part publication investigates the application of reactive magnesia alone as the cement co…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionMagnesium Oxide Properties and Applications

Hydrogen-induced ferromagnetism in ZnO single crystals investigated by magnetotransport

Muhammad Khalid、P. Esquinazi2012-04-13Physical Review B

We investigate the electrical and magnetic properties of low-energy H${}^{+}$-implanted ZnO single crystals with hydrogen concentrations up to $\ensuremath{\sim}$3 at% in the first 20-nm surface layer between 10 K and 300 K. All samples show clear ferromagnetic hysteresis loops at 300 K with a saturation magnetization…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Molecular Engineering of Elastic and Strong Supertough Polyurethanes

Borja Fernández–d’Arlas、José Ángel Ramos、Ainara Saralegi 等 6 位作者2012-04-13Macromolecules

Spider silk is an icon of supertough energy absorbing polymeric material which its macromolecular multiblock composition has been attributed to be responsible for such remarkable properties. As in spider silk, polyurethanes can be synthesized with two distinct block which can differ in nature, combining properties lik…

Bone Tissue Engineering MaterialsPolymer composites and self-healingSilk-based biomaterials and applications

Sulfonium Bis(trifluorosulfonimide) Plastic Crystal Ionic Liquid as an Electrolyte at Elevated Temperature for High-Energy Supercapacitors

Mérièm Anouti、Laure Timperman、M. Hilali 等 5 位作者2012-04-13The Journal of Physical Chemistry C

This study describes the use of the ionic liquid trimethylsulfonium bis(trifluorosulfonimide) [Me 3 S][TFSI] as an electrolyte for carbon-based supercapacitors at temperatures up to 80 °C. [Me 3 S][TFSI] is synthesized by a metathesis reaction, possesses a low melting point ( T m = 45.5 °C), and presents crystal plast…

Supercapacitor Materials and FabricationIonic liquids properties and applicationsAdvanced battery technologies research

Selective Etching Induces Selective Growth and Controlled Formation of Various Platinum Nanostructures by Modifying Seed Surface Free Energy

Nini Fan、Yun Yang、Wenfang Wang 等 7 位作者2012-04-13ACS Nano

We present a strategy to achieve heterogeneous seeded growth on nanoparticle (NP) surfaces and construct various Pt nanostructures (cage- and ring-like) by using selective etching as surface-free-energy-distribution modifier. Preprepared Au polyhedron NPs (octahedron, decahedron, nanorod, and nanoplate) are mixed with…

Electrocatalysts for Energy ConversionGold and Silver Nanoparticles Synthesis and ApplicationsSolar-Powered Water Purification Methods

N<sub>2</sub>O Formation and Mitigation in Diesel Aftertreatment Systems

Krishna Kamasamudram、Cary Henry、Neal W. Currier 等 4 位作者2012-04-13SAE International Journal of Engines

&lt;div class="section abstract"&gt;&lt;div class="htmlview paragraph"&gt;The high global warming potential of nitrous oxide (N₂O) led to its recent inclusion in the list of regulated pollutants under the emerging greenhouse gas regulations. While N₂O can be present in small quantities among the combustion products, i…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Nanoscale Compositionally Graded Thin‐Film Electrolyte Membranes for Low‐Temperature Solid Oxide Fuel Cells

Kian Kerman、Bo‐Kuai Lai、Shriram Ramanathan2012-04-13Advanced Energy Materials

Abstract Controllable fabrication of compositionally graded Gd 0.1 Ce 0.9 O 2‐δ and Y 0.16 Zr 0.84 O 2‐δ electrolytes using co‐sputtering is demonstrated. Self‐supported membranes were lithographically fabricated to employ the new electrolytes into thin film solid oxide fuel cells. Devices integrating such electrolyte…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides