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Synthesis of Hydrotalcite and its Anion Exchange Properties

Norihiro Murayama、Hideki Yamamoto、Junji Shibata2004-01-01Resources Processing

As one of effective usages of the wastes in an aluminum regeneration process, the syntheses of hydrotalcite (HT), which is a functional inorganic material having layered structure of complex hydroxide, were carried out by using aluminum dross and MgCl2 waste solution as raw materials. Various physical properties such…

Layered Double Hydroxides Synthesis and ApplicationsPhosphorus and nutrient managementMagnesium Oxide Properties and Applications

Tilting structures in perovskites

В. Б. Широков、V. I. Torgashev2004-01-01Crystallography Reports

Thirty five low-symmetry tilting phases of the octahedra in which the atoms located at the initial octahedral position remain equivalent are derived for the perovskite structure at the k 10 ( X ), k 11 ( M ), and k 13 ( R ) points of the Brillouin zone. For each low-symmetry phase, structural data are presented and a…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Benthic Diatom Assemblages in an Abalone ( Haliotis spp.) Habitat in the Baja California Peninsula

David Alfaro Siqueiros Beltrones、Guillermina Valenzuela Romero2004-01-01Pacific Science

Diatom assemblages from an abalone (rocky) habitat were sampled in April and November 1999 and in April 2000 on the western side of Isla Magdalena, RCS., Mexico. Overall 236 taxa were recorded, including 10 new records, and 56 species that have been observed exclusively in this type of habitat in the Baja California p…

Diatoms and Algae Research

Selective synthesis of U-shaped terpyridines. Versatile ligands for the preparation of platinum complexes

Dirk Sielemann、Andreas Winter、Ülrich Flörke 等 4 位作者2004-01-01Organic & Biomolecular Chemistry

The development of a simple and highly selective method for the preparation of substituted U-shaped terpyridines is described. The treatment of imine 5 with ternary iminium salts 2 leads to the terpyridines 4. A possible mechanism is discussed. The terpyridine derivatives are used for the preparation of several platin…

Metal complexes synthesis and propertiesDNA and Nucleic Acid ChemistryPorphyrin and Phthalocyanine Chemistry

Dislocation interaction with hydrides in titanium containing a low hydrogen concentration

C. Q. Chen、S. X. Li、K. Lu2004-01-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The dislocation configurations and their interactions with γ-hydrides were investigated in cyclically strained titanium containing 77 ppm hydrogen. At least three sets of dislocations could be activated in hydride precipitates. To accommodate the inhomogeneous strain between the matrix and the hydrides a crystal rotat…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Synthesis and characterization of biodegradable aliphatic copolyesters with hydrophilic soft segments

Danijela Jovanović、Marija S. Nikolić、Jasna Djonlagić2004-01-01Journal of the Serbian Chemical Society

segmented poly(ester-ether)s based on poly(butylene succinate) and two different types of polyethers were investigated. The poly(ester-ether)s were synthesized by transesterification reaction of dimethyl succinate 1,4-butanediol and poly(ethylene oxide) (PEO, Mn = 1000 g/mol) in the first series, and poly(tetramethyle…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Synchrotron Small‐Angle X‐Ray Scattering Studies on Flow‐Induced Gyroid to Cylinder Transition in an Elastomeric SBS Triblock Copolymer

Shinichi Sakurai、Takuya Kota、Daisuke Isobe 等 8 位作者2004-01-01Journal of Macromolecular Science Part B

We report elongational flow‐induced morphological transition from double gyroid (DG) to hexagonal cylinders in polystyrene‐block‐polybutadiene‐block‐polystyrene triblock copolymer (SBS). First, the SBS sample was fully annealed at 190°C for 24 hr to prepare a DG structure. Then the sample was subjected to planar elong…

Advanced Numerical Methods in Computational MathematicsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Preparation and Structural Analysis of Actinidain-processed Atelocollagen of Yellowfin Tuna (Thunnus albacares)

Koichi Morimoto、Saori Kunii、Kaori Hamano 等 4 位作者2004-01-01Bioscience Biotechnology and Biochemistry

Pepsin-hydrolyzed collagen (atelocollagen) is a trimer, consisting of alpha 1 and alpha 2 monomers, and shows molecular species corresponding to a monomer, dimer (beta chain), and trimer (gamma chain) by SDS-polyacrylamide gel electrophoresis. Atelocollagen was purified from yellowfin tuna (Thunnus albacares) by salt…

Meat and Animal Product QualityProtein Hydrolysis and Bioactive PeptidesCollagen: Extraction and Characterization

Raman Characterization of Oxidation Behavior of Free Carbon in Silicon Oxycarbide Ceramics

Manabu Fukushima、Eiichi Yasuda、Yoshikazu Teranishi 等 5 位作者2004-01-01Journal of the Ceramic Society of Japan

Tantalum and niobium containing silicon oxycarbide ceramics were prepared from hybrid gels through cohydrolysis with methyltriethoxysilane and pentaethoxyniobium/tantalum, and pyrolysis at 1000°C. To investigate the behavior of free carbon in Si-Nb-C-O and Si-Ta-C-O ceramics, Raman spectroscopy was used. The spectra o…

Graphene research and applicationsAdvanced ceramic materials synthesisDiamond and Carbon-based Materials Research

Development of Intermediate-Temperature SOFC Module Using Doped Lanthanum Gallate

Takashi Yamada、Norihisa Chitose、Jun Akikusa 等 19 位作者2004-01-01Journal of The Electrochemical Society

Development of Intermediate-Temperature SOFC Module Using Doped Lanthanum Gallate , Yamada, T., Chitose, N., Akikusa, J., Murakami, N., Akbay, T., Miyazawa, T., Adachi, K., Hasegawa, A., Yamada, M., Hoshino, K., Hosoi, K., Komada, N., Yoshida, H., Kawano, M., Sasaki, T., Inagaki, T., Miura, K., Ishihara, T., Takita, Y.

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Discotic Multipodes with Nematic Mesophases

Paul H. J. Kouwer、Georg H. Mehl、Stephen J. Picken2004-01-01Molecular Crystals and Liquid Crystals

Various core materials have been introduced at the terminal end of a discotic mesogen (based on a pentakis(methylphenylethynyl) phenoxy core), resulting in the formation of liquid crystalline ‘monomers’ and ‘dimers.’ The mesomorphic properties of this series of derivatives were investigated as a function of the attach…

Liquid Crystal Research AdvancementsDendrimers and Hyperbranched PolymersAdvanced Materials and Mechanics

Oxidative Coupling of Methane in the LSM/YSZ/LaAlO SOFC Reactor

Worapon Kiatkittipong、Tomohiko Tagawa、Shigeo Goto 等 5 位作者2004-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Oxidative coupling of methane was studied in a solid oxide fuel cell (SOFC) tube type reactor. La0.85Sr0.15MnO3/8 mol% Y2O3-ZrO2/La1.8Al0.2O3 (abbreviated as LSM/YSZ/LaAlO) were used as a cathode, electrolyte and anode. The C2 selectivity and the methane conversion were 91.7% and 23.7% at 1273 K, respectively. The kin…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Solid state coordination chemistry: organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains

Gündoğ Yücesan、V. Golub、Charles J. O’Connor 等 4 位作者2004-01-01CrystEngComm

The hydrothermal reactions of Na3VO4, tetrapyridylporphyrin (tpypor), phenylphosphonic acid and the appropriate M(II) salt yielded the three-dimensional oxide frameworks [Cu(tpypor){Cu2V2O2(O3PC6H5)4}]·2H2O (1·2H2O) and [Ni(tpypor){V4O4(O3PC6H5)4}]·2H2O (2·2H2O), which are constructed from {X2V2O2(O3PC6H5)4}n chains […

Metal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

Measurement of the Density of Binary Ni-X (X=Co, W, Ta, Al) Alloys

Kusuhiro Mukai、Liang Fang、Zushu Li 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

The modified sessile drop method (MSDM) and modified pycnometric method (MPM) have been employed to measure the densities of liquid Ni-Co, Ni-W, Ni-Ta and Ni-Al alloys precisely. In the case of Ni-Al alloys measurements were also made in the “mushy” state where both solid and liquid coexist. There was a good agreement…

Metallurgical Processes and ThermodynamicsAdvancements in Materials EngineeringMetallurgical and Alloy Processes

Influence of Fuel Composition on Solid Oxide Fuel Cell Hybrid System Layout and Performance

Francesco Marsano、Loredana Magistri、Michele Bozzolo 等 4 位作者2004-01-01OpenAlex

The design of Solid Oxide Fuel Cell (SOFC) Hybrid Systems (HS) is usually based on the use of natural gas as fuel. However, the possibility of using other fuels such as biomass gasification, pyrolysis, fermentation, and coal gasification could potentially increase the market for SOFC Hybrid Systems. In this paper, the…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Comparison of Theoretical and Experimental switching curves for a zenithally bistable nematic liquid crystal device

C. V. Brown、L. A. Parry‐Jones、Steve J. Elston 等 4 位作者2004-01-01Molecular Crystals and Liquid Crystals

Zenithally bistable nematic liquid crystal devices have been fabricated from a interferometrically defined microgrooved surface and a flat substrate treated with homeotropic surfactant. Two stable states are observed in the devices, one where the liquid crystal is aligned homeotropically (VAN) and the other where the…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationAdvanced Materials and Mechanics

Effect of Microstructure on the Cold Headability of a Medium Carbon Steel

Xiaoyu Ma、A. O. Humphreys、Jim Nemes 等 6 位作者2004-01-01ISIJ International

Cold headability is the ability of a cylindrical metallic specimen to be shaped at high strain rate into the head of a bolt, screw or other cold-formed part without cracking. This property is material dependent and can be influenced by many factors such as chemical composition, surface condition, and microstructure. T…

Microstructure and Mechanical Properties of SteelsHigh-Velocity Impact and Material BehaviorMetal Alloys Wear and Properties

Donor strength of π-extended tetrathiafulvalenes: ionisation energies vs. oxidation potentials. A joint theoretical and experimental study

Katrine Qvortrup、Marianne Thuen Jakobsen、Jean‐Paul Gisselbrecht 等 7 位作者2004-01-01Journal of Materials Chemistry

The π-donor strength of extended tetrathiafulvalenes (TTFs) has been investigated as a function of the electronic character and length of the spacer between the two dithiole rings. First and second ionisation energies were calculated with B3LYP/6-311++G(2d,p)//B3LYP/6-31+G(d) and B3LYP/6-311++G(2d,p)//PM3 computationa…

Perovskite Materials and ApplicationsAdvanced battery technologies researchOrganic and Molecular Conductors Research

The Effect of Polymer Molecular Weight on the Structure of a Honeycomb Patterned Thin Film Prepared by Solvent Evaporation

Hideto Matsuyama、Kazuhiro Ohga、Taisuke Maki 等 4 位作者2004-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Honeycomb patterned polystyrene film was prepared from a polystyrene chloroform solution including polyion complexes by solvent evaporation under high atmospheric humidity. Formation of the honeycomb pattern was owing to the hexagonally packed water droplets which condensed onto the polymer solution. The pore diameter…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsBlock Copolymer Self-Assembly

The Effect of Warm Equal Channel Angular Extrusion on Ductility and Twinning in Magnesium Alloy ZK60

Rimma Lapovok、P.F. Thomson、R. Cottam 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

Tensile ductility of magnesium alloy ZK60 pre-strained by warm equal channel angular extrusion (ECAE) was investigated at 300°C. It was shown that a significant ductility (262%) is achievable with this technique for a fairly high strain rate of 3·10−3 s−1. The effect of pre-straining by warm ECAE on twinning under roo…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties