Materials Literature
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This paper describes the use of surface plasmon resonance (SPR) spectroscopy to measure the rates and extents of association of four detergents sodium dodecyl sulfate (SDS), β-octyl glucoside, Triton X-100, and Tween 20 to self-assembled monolayers (SAMs) of alkanethiolates on gold. SAMs presenting hexaethylene glycol…
A series of novel polymers have been prepared by free radical solution polymerization of a variety of hydrocarbon monomers with the (perfluoroalkyl)ethyl methacrylate monomer H 2 C C(CH 3 )CO 2 (CH 2 ) 2 (CF 2 ) n F, 1 ( n̄ ≈ 7.7). Polymers prepared using two different methods of feeding 1 into the reaction mass are d…
We discuss examples of designs for all-dielectric reflection gratings that tolerate high intensity and are potentially capable of placing up to 99% of the incident light into a single diffraction order, such as are needed for contemporary high-power lasers utilizing chirped-pulse amplification. The designs are based o…
(111) textured Au films were oxidized under UHV conditions by exposing them to UV radiation and ozone. The Au films were characterized by x-ray photoelectron spectroscopy. The gold surface becomes heterogeneous upon oxidation: approximately 0.8 monolayer (ML) of the adsorbed oxygen is present as chemisorbed species. T…
We examine the shear flow of hexadecane confined between plates with separation of 1–10 nm using molecular dynamics simulations. We also performed non-equilibrium molecular dynamics (NEMD) simulations of bulk hexadecane to compare with the simulations in the confined geometry. The stiffness of hexadecane and its high…
We consider the effects of Coulomb interactions on single-wall carbon nanotubes using an on-site Hubbard interaction, u. For the (N,N) armchair tubes the low-energy theory is shown to be identical to a two-chain Hubbard model at half-filling, with an effective interaction ${\mathrm{u}}_{\mathrm{N}}$=u/N. Umklapp scatt…
Thermoplastic poly(ester−urethanes) were polymerized in a two-step process: a condensation copolymerization of lactic acid (LA) and ε-caprolactone (CL), using stannous octoate as catalyst, followed by an increase in the molecular weight through urethane linking. The use of 1,4-butanediol results in oligomer molecules…
Transparent unplasticized zein films were prepared in aqueous ethanol or acetone. Tensile properties indicated that films prepared in acetone were stronger but less flexible than those prepared in ethanol. Both types of films, however, were too brittle for most applications. Films containing a glycerol:poly(propylene…
High-frequency planar magnetic components, employing thin film and thick film technology, have become important components in applications, such as filters and switching converters, due to their ease of manufacture and reliability. In a previous paper, the authors established a frequency dependent impedance formula fo…
Using a two-dimensional Scheutjens and Fleer self-consistent field calculation, we determine the equilibrium morphology of thin films of symmetric AB diblock copolymers confined between hard, smooth plates. A lamellar phase is established with the stripes either perpendicular or parallel to the walls. With neutral wal…
Nitronyl nitroxide derivatives carrying a hydroquinone or a resorcinol moiety 2-(2‘,5‘-dihydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1 H -imidazolyl-1-oxyl-3-oxide (HQNN) and 2-(3‘,5‘-dihydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1 H -imidazolyl-1-oxyl 3-oxide (RSNN)) have been designed and prepared. These compo…
We present specific-heat, elastic constants, and magnetic susceptibility measurements in a ferromagnetic ${\mathrm{Ni}}_{2}$MnGa Heusler alloy, in a temperature range where partial condensation of the [110]${\mathrm{TA}}_{2}$ phonon at q=0.33, accompanied by the development of a micromodulated structure has been repor…
Electrodeposition of amorphous electrochromic tungsten trioxide was studied. Good quality films were deposited cathodically onto tin‐doped indium oxide (ITO) from a water/isopropanol solution containing dissolved tungsten(VI) species. Three reducible species are present in this solution: unbound , polytungstate ions,…
The magnetic ac susceptibility \ensuremath{\chi} of oriented ${\mathrm{Mn}}_{12}$Ac crystallites has been measured as a function of temperature, field, and frequency. The field has been applied at different values of the angle \ensuremath{\theta} with respect to the sample easy axis. For T=5tK, the isothermal and adia…
Abstract We synthesized substituted pyrazolylpyridine ligands to examine their donor properties by spectroscopic (IR, NMR) and computational (AM 1) methods. The influence of the substitution patterns on spectroscopic and thermodynamic features of molybdenum oxobisperoxo complexes [(L–L)MoO(O 2 ) 2 ] (L–L=2‐(1‐alkyl‐3‐…
The temperature-dependent thermoelectric power (TEP) and resistivity of ${\mathrm{La}}_{1\mathrm{\ensuremath{-}}\mathrm{x}}$${\mathrm{Ca}}_{\mathrm{x}}$${\mathrm{MnO}}_{3+\mathrm{\ensuremath{\delta}}}$ polycrystals (0\ensuremath{\leqslant}x\ensuremath{\leqslant}0.45) are reported. The TEP data are analyzed within an a…
Anthracenebisresorcinol derivative 1 as an organic network material shows a novel catalysis in the solid state for the acrolein−cyclohexadiene Diels−Alder reaction. The suggested mechanism involves a catalytic cycle composed of sorption of the reactants in the cavities of polycrystalline host 1, preorganized intracavi…
Abstract Because of its low chemical reactivity Si 3 N 4 has hardly been used as a starting material for the preparation of multinary silicon nitrides or nitridosilicates, but has gained increasing importance as a nonoxidic material for high‐performance applications. A novel synthetic approach is presented, which star…
Lipase-catalyzed ring-opening bulk polymerizations of ω-pentadecalactone (PDL) were investigated. Screening of selected commercial lipases as catalysts for PDL polymerization at 80 °C was carried out. The results of this work showed that polymerizations catalyzed by lipases PS-30, AK, Lipozyme-IM and Novozym-435 gave…
The miscibility and crystallization behavior of poly(β-hydroxybutyrate) (PHB) and poly( p -vinylphenol) (PVPh) blends were studied by differential scanning calorimetry and optical microscopy (OM). The blends exhibit a single composition-dependent glass transition temperature, characteristic of miscible systems. A depr…