Materials Literature
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Abstract Two dinuclear manganese(II) complexes, [Mn2(Ph2MeCCOO)3(bpy)2](PF6) (1) and [Mn2(C6H5COO)3(CH3OH)(bpy)2](NO3) (2), have been prepared. X-Ray structural analyses have revealed that complexes 1 and 2 have a different bridging mode in triple carboxylato-bridges between two manganese(II) ions each other.
The effect of the preparation conditions for amorphous including aniline on its discharge and charge characteristics as a cathode material for a rechargeable lithium battery was investigated to improve the discharge and charge characteristics. The was prepared in solutions containing different concentrations of anilin…
Silicon‐based structural ceramics , such as silicon carbide, silicon nitride and SiAlON exhibit an attractive range of properties, i.e. high strength, stiffness, and good wear and corrosion resistance, and are considered very appropriate materials for high‐temperature applications. Recent progress in the synthesis of…
Abstract Der elektrochemische Test zur Bestimmung des Bedeckungsgrades von phosphatiertem Stahl [1] wird auf verzinkten Stahl übertragen. Der Bedeckungsgrad wird aus Stromdichte‐Potentialmessungen, Kapazitäts‐sowie Impedanzmessungen bestimmt. Die freie Metalloberfläche nimmt bei elektrolytisch verzinktem Stahl nach 60…
Both KNbO3 and BaTiO3 systems, in their cubic, tetragonal or orthorhombic phases, were reported to show two-dimensional (2D) diffuse scattering intensity sheets in the reciprocal space, thus indicating the presence of one-dimensional correlation in the real space. Two models have been proposed to explain the origin of…
Transformation sequences in a NiTi shape memory alloy after deformation and subsequent annealing were studied using various methods. Low temperature annealing of the deformed alloy caused that the R-phase preceeded the martensitic transformation. The R-phase formation during both cooling and heating depends strongly o…
Abstract We report scanning Auger microscopy (SAM) and x‐ray photoemission spectroscopy (XPS) analysis of a Roman lead pipe ‘flstula’, the main emphasis being placed on the comparison between the surface and interface chemical composition of the joint and of the rest of the pipe. We find that the ‘tertiarium,’ a Pb–Sn…
The Structure of Semiconductors. The Technology of Semiconductor Devices. The Assessment of Semiconductors by Electrical Techniques. The Assessment of Semiconductors by Diffraction. Optical Assessment of Semiconductors. Assessment of Semiconductors by Ion Beam Techniques. Assessment of Microscopy and Imaging.
Abstract Poly(ethylene oxide)‐grafted butyl rubbers (IIR‐ g ‐PEOs), which were synthesized from potassium salt of polyethylene glycol monomethyl ether (PEGM) and chlorinated butyl rubber, were found to behave like thermoplastic elastomers. The poly(ethylene oxide) (PEO) content of these amphiphilic polymers was ca. 10…
Four major sol gel or metallorganic decomposition routes for the processing of lead zirconate have been established. The requirements and criteria for successful processing are reviewed, and the concept of a characteristic volume over which the gel is stoichiometric is introduced. The need for solution species of comp…
Rutile-phase TiO 2 films were epitaxially grown on Si(100) substrates by oxidizing epitaxial TiN films grown by KrF pulsed excimer laser deposition. The TiO 2 film was (110)-oriented and composed of two domains perpendicular to each other in the plane. The electrical resistivity at 2.5 V and the dielectric constant at…
Abstract To graft polymers with controlled molecular weight and narrow molecular weight distribution, the grafting of polymers onto ultrafine silica surface by the termination of living polymer cation with amino groups introduced onto the surface was investigated. The introduction of amino or N ‐phenylamino groups ont…
Abstract The chemical reaction at high temperature (above 200°C) between PC and PMMA has been very recently highlighted. However, no clear reaction mechanism has been proposed to explain this phenomenon. We suggest a reaction mechanism following two steps. The first step consists of hydrolysis of the ester bonds of th…
Abstract A study was made of miscible polymer blends of deuterated polystyrene (d‐PS) and tetramethylbisphenol‐A polycarbonate (TMPC). The Flory interaction parameter χ was obtained from the relation between mutual and tracer diffusion coefficients, D̃ and D * , which were measured by forward recoil spectrometry. The…
Structural characteristics and electrooptical properties of Sn-doped In 2 O 3 (ITO) films were investigated in terms of Sn concentrations from 5.34 to 8.99 (Sn/In at.%) with changing oxygen partial pressure and substrate temperature during deposition, in spite of using an ITO target with the same Sn concentration ( 7.…
Octahedral liquid crystals based upon diketonate complexes of Fe+3, Mn+3, and Cr+3 are reported. These materials display columnar phases with ≥12 sidechains and an ordered smectic phase with 6 sidechains.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBoron Nitride Matrixes and Coatings Obtained from Tris(methylamino)borane. Application to the Protection of Graphite against OxidationB. Bonnetot, F. Guilhon, J. C. Viala, and H. MongeotCite this: Chem. Mater. 1995, 7, 2, 299–303Publication Date (Print):February 1, 1995Publi…
A method is described for the measurement of the rotational viscosity y 1 in nematic liquid crystal cell assemblies. Theoretical formulas to determine y 1 from transient current are developed by considering both director rotation and conduction of impurity ions. The pretilt angle and the product of the drift mobility…
In this time-resolved study of vibrational dynamics of deuterated surface hydroxyls at acid sites in the zeolite Mordenite, we investigate the O–D T1 vibrational lifetime and transient band shifts. It is shown that after infrared excitation of the stretching mode of a surface hydroxyl, the excess energy is rapidly dis…
In order to provide biodegradable poly(hydroxy acid)s by a simple process, fundamental studies on the polycondensation of α-hydroxy acids by enzymes and polyethylene glycol (PEG)-modified enzymes in organic media were carried out. The oligomer formation by unmodified hog liver esterase proceeded well using glycolic ac…