Materials Literature
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20 µm diameter spray-dried agglomerates made up of 210 nm zirconia particles have been individually tested by crushing between rigid plates using a modified nanoindenter. The results show that the agglomerates support considerable stress before deforming. Both the elastic and plastic deformations of the agglomerates h…
We study the adsorption of long, linear polymer chains from a melt or a semi-dilute solution onto a solid wall, the adsorption of a monomer on a surface site being irreversible. Using scaling arguments, we derive the concentration profile and the extension of the polymer layer, which has been washed out with pure solv…
UV absorption spectra of KCl:Sb 3+ crystals have been studied in detail. Six absorption bands are observed at 271.0, 210.8, 201.7, 199.4, 195.5 and 191.4 nm, the first five bands of which are attributable to the A, B, C 1 , C 2 and C 3 bands due to an s 2 to sp transition in the Sb 3+ ion, while the last is due to the…
Ni-Ti shape memory actuators respond to temperature changes with a shape change. Therefore, they are sensors and actuators. They combine large motion, rather high forces and small size, thus providing high work output. They usually consist of only a single piece of metal, e.g., a helical spring, and do not require sop…
The electron paramagnetic resonance (EPR) of an Mn 2+ (S=5/2) impurity in the ferroelastic and para-elastic phase of BiVO 4 crystals with a single domain, grown by the Czochralski method, has been investigated using an X-band spectrometer. The rotation patterns of the resonance fields measured on the crystallographic…
We report the room-temperature near-infrared emission (1.0–1.4 μm), the fluorescence lifetimes, and the gain measurements of the tetraoxo manganese specie MnO3−4(Mn5+,3d2) in single crystals of Sr5(PO4)3Cl and Ca2PO4Cl. The relatively long fluorescence lifetimes, 100 and 425 μs for MnO3−4 doped Ca2PO4Cl and MnO3−4 dop…
The diffusion of protons in the superionic phase of CsHSO 4 was investigated by quasielastic neutron scattering (QNS) on the IRIS spectrometer at the pulsed spallation neutron source ISIS, Rutherford Appleton Laboratory, UK. Two processes with different characteristic times could be distinguished: long-range translati…
Neutron diffraction experiments have been carried out in order to investigate the ordered structures of the high temperature phase of two different Cu-Zn-Al alloys. It has been confirmed that the alloys exhibit an L2 1 superstructure below a critical temperature T c2 ; a B2 superstructure between T c2 and T c1 , and a…
The temperature evolution of the frequencies and absorption cross section of the infrared-active phonons near 795 cm -1 and 695 cm -1 and the Raman-active mode near 355 cm -1 follow that of the symmetry-breaking order parameter of the alpha - beta phase transition in quartz. The IR signal at 695 cm -1 and the Raman si…
In the present paper, dielectric, polarization, and Raman results have been combined to identify the existence of a ferroelectric phase transition in the substitutionally disordered dipolar system, ${\mathrm{KTa}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Nb}}_{\mathit{x}}$${\mathrm{O}}_{3}$, for low Nb concentra…
The elasticity and hardness of a-C and a-C:H are related to their mean network coordinations. It is shown that ${\mathit{sp}}^{2}$ sites contribute no rigidity if they form graphitic clusters, as suggested by experiment and electronic structure calculations, despite their having coordinations above the critical value…
Superconductors are considered in which there occur fluctuations of one crystallographic structure inside another. The role of these heterostructural fluctuations on superconducting properties are analysed. The occurrence of these fluctuations explains anomalous saggings of Mössbauer factor at phase transition in high…
An optical architecture is proposed that uses two modified liquid-crystal televisions (LCTV's) to control amplitude and phase modulation independently. Two applications in pattern recognition are discussed.
A number of unnatural amino acids and amino acid analogs with modified backbone structures were substituted for alanine-82 in T4 lysozyme. Replacements included alpha,alpha-disubstituted amino acids, N-alkyl amino acids, and lactic acid, an isoelectronic analog of alanine. The effects of these electronic and structura…
Preface 1. Shape and growth of crystals P. Nozieres 2. Instabilities of planar solidification fronts B. Caroli, C. Caroli and B. Roulet 3. An introduction to the kinetics of first-order phase transition J. S. Langer 4. Dendritic growth and related topics Y. Pomeau and M. Ben Amar 5. Growth and aggregation far from equ…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
A simple density functional theory for the various liquid-crystalline phases of parallel hard spherocylinders is formulated on the basis of Pynn's ansatz for the direct correlation function of the spherocylinders. Fair agreement with the computer simulations is found.
The geometrical structure associated with visible points in a lattice is investigated. It appears to be the Mobius transform of the original lattice. The related symmetry group and structure factor are explicitly derived.
We present electronic-structure calculations for various rational approximants to icosahedral quasi-crystals. We show that structure-induced minima in the electronic DOS exist in all phases. This pseudogap leads to a lowering of the structural energy by a Hume-Rothery-like mechanism.
The photovoltaic (PV) power system for Space Station Freedom (SSF) uses solar array blankets which provide structural support for the solar cells and house the electrical interconnections. In the low Earth orbital (LEO) environment where SSF will be located, surfaces will be exposed to potentially damaging environment…