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The unified interaction model applied to the gamma ray induced supralinearity and sensitization of peak 5 in LiF:Mg,Ti (TLD-100)

S. Mahajna、Y.S. Horowitz1997-09-21Journal of Physics D Applied Physics

We describe the development of a comprehensive theory of thermoluminescence (TL) supralinearity and sensitization, the unified interaction model (UNIM), based on both radiation absorption stage and recombination stage mechanisms. The UNIM incorporates both the track interaction model (TIM) for heavy charged particles…

Solid-state spectroscopy and crystallographyLuminescence Properties of Advanced MaterialsRadiation Detection and Scintillator Technologies

Optical properties of GeO_2 glass and optical fibers

Shigeki Sakaguchi、Shin‐ichi Todoroki1997-09-20Applied Optics

The optical properties of GeO(2) glass were investigated to clarify its potentiality as an optical fiber material. Glass samples were prepared by the flame hydrolysis and the melting techniques, and their Rayleigh scattering and infrared absorption properties were examined. Optical fibers composed of a pure GeO(2) cor…

Photonic and Optical DevicesGlass properties and applicationsLaser Material Processing Techniques

Toward millions of laser pulses with pyrromethene- and perylene-doped xerogels

Mohammed Faloss、Michael Canva、Patrick Georges 等 6 位作者1997-09-20Applied Optics

Significant improvements have been obtained for solid-state dye lasers with doped xerogels. By using longitudinal pumping with a frequency-doubled Q-switched Nd: YAG laser, we obtained as much as 86% slope efficiency and 5 x 10(5) pulses lifetime. Furthermore, newly prepared deoxygenated samples exhibited even greater…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSilicone and Siloxane Chemistry

Microscopic Viscoelasticity: Shear Moduli of Soft Materials Determined from Thermal Fluctuations

F. Gittes、B. Schnurr、P. D. Olmsted 等 5 位作者1997-09-20arXiv

We describe a high-resolution, high-bandwidth technique for determining the local viscoelasticity of soft materials such as polymer gels. Loss and storage shear moduli are determined from the power spectra of thermal fluctuations of embedded micron-sized probe particles, observed with an interferometric microscope. Th…

Soft Condensed MatterMaterials Science

Determining Microscopic Viscoelasticity in Flexible and Semiflexible Polymer Networks from Thermal Fluctuations

B. Schnurr、F. Gittes、F. C. MacKintosh 等 4 位作者1997-09-20arXiv

We have developed a new technique to measure viscoelasticity in soft materials such as polymer solutions, by monitoring thermal fluctuations of embedded probe particles using laser interferometry in a microscope. Interferometry allows us to obtain power spectra of fluctuating beads from 0.1 Hz to 20 kHz, and with sub-…

Materials ScienceSoft Condensed Matter

Theory of Hysteresis Loop in Ferromagnet

Igor F. Lyuksyutov、Thomas Nattermann、Valery Pokrovsky1997-09-20arXiv

A theory of the hysteresis loop in ferromagnets controlled by the domain wall motion is presented. Domain walls are considered as plane or linear interfaces moving in a random medium under the action of the external ac magnetic field $H=H_0\sinωt$. We introduce important characteristics of the hysteresis loop, such as…

Materials Science

Morphology control of polyester-polyolefin blends by transesterification during processing operations in the presence of dibutyltin oxide

I. Pesneau、Marie‐France Llauro、M. Gr�goire 等 4 位作者1997-09-19Journal of Applied Polymer Science

PE and PBT are known to be incompatible polymers. A grafted copolymer PBT-EVA has been generated as a compatibilizer in situ during the processing operation by redistributive transesterification between PBT and EVA in the presence of dibutyl tin oxide (DBTO). This copolymer has been isolated by selective extractions f…

Polymer Nanocomposites and PropertiesPolymer crystallization and propertiesRecycling and Waste Management Techniques

Hydrophobic hybrid inorganic-organic thin film prepared by sol-gel process for glass protection and strengthening applications

Amir Ershad‐Langroudi、C. Maï、Gérard Vigier 等 4 位作者1997-09-19Journal of Applied Polymer Science

Hybrid systems based on 3-trimethoxysilyl propyl methacrylate, tetramethylorthosilicate, and methyl methacrylate were developed for moisture protection and strengthening of glass objects. The hydrophobic behavior of the hybrid was obtained by adding different fluorinated precursors to the hybrid solution. Experimental…

Surface Modification and SuperhydrophobicityAerogels and thermal insulationSilicone and Siloxane Chemistry

Versatile Collagens in Invertebrates

Jürgen Engel1997-09-19Science

In his Perspective, Engel discusses the diverse structural features of collagens, a ubiquitous fibrillar protein that forms the main support of skin and tendons. A unique example is reported in this issue by Coyne et al ., who describe the amino acid sequence of the specialized collagen that forms the byssal threads t…

Silk-based biomaterials and applicationsMarine Biology and Environmental ChemistryTendon Structure and Treatment

Extensible Collagen in Mussel Byssus: A Natural Block Copolymer

Kathryn J. Coyne、Xiaoxia Qin、J. Herbert Waite1997-09-19Science

To adhere to solid surfaces, marine mussels produce byssal threads, each of which is a stiff tether at one end and a shock absorber with 160 percent extensibility at the other end. The elastic extensibility of proximal byssus is extraordinary given its construction of collagen and the limited extension (less than 10 p…

Knee injuries and reconstruction techniquesSilk-based biomaterials and applicationsMarine Biology and Environmental Chemistry

Structural Stability of Vacancy-ordered Yb2.75C60

K. M. Rabe、P. H. Citrin1997-09-18arXiv

The fcc-based structure of Yb2.75C60 is unique among metal-doped fullerene compounds, exhibiting long-range-ordered vacancies, significantly off-centered divalent Yb cations, and distorted, crystallographically inequivalent, orientationally ordered C60 anions. A simple electrostatic-energy analysis, which models the c…

Materials Science

Proton‐Dependent Monomer–Oligomer Interconversion of Metal Complexes

Naohide Matsumoto、Yukiko Mizuguchi、Genjin Mago 等 7 位作者1997-09-17Angewandte Chemie International Edition in English

The reversible reaction of a monomeric CuII complex to a cyclic hexamer (crystal structures shown below) is the first example interconversion between a potential guest complex and a complex that cannot function as a guest [Eq. (a)]. It is—like in living organisms—controlled by a very common external signal, namely pro…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry

β‐Peptides: Novel Secondary Structures Take Shape

Ulrich Koert1997-09-17Angewandte Chemie International Edition in English

Why don't we live in β-peptide world? This is a legitimate question in light of new findings by D. Seebach et al. and S. Gellman et al. on the secondary structures of β-peptides. Peptides composed of less than ten β-amino acid residues can from stable, secondary structure motifs like the 31-M-helix shown on the right.…

Glycosylation and Glycoproteins ResearchSupramolecular Self-Assembly in MaterialsChemical Synthesis and Analysis

A Facile Synthesis of Unusual Liquid‐Crystalline Gold(I) Dicarbene Compounds

Kwang Ming Lee、Ching Kuan Lee、Ivan J. B. Lin1997-09-17Angewandte Chemie International Edition in English

A highly ordered lamellar mesophase is exhibited by the thermally stable liquid-crystalline gold(I) dicarbene compounds presented here. The crystal structure of one of these compounds is depicted on the right.

Synthetic Organic Chemistry MethodsAdvanced Materials and MechanicsLiquid Crystal Research Advancements

Total energy differences between SiC polytypes revisited

Sukit Limpijumnong、Walter R. L. Lambrecht1997-09-17arXiv

The total energy differences between various SiC polytypes (3C, 6H, 4H, 2H, 15R and 9R) were calculated using the full-potential linear muffin-tin orbital method using the Perdew-Wang-(91) generalized gradient approximation to the exchange-correlation functional in the density functional method. Numerical convergence…

Materials Science

Transport Coefficients of InSb in a Strong Magnetic Field

HIROAKI NAKAMURA、Kazuaki Ikeda、Satarou Yamaguchi1997-09-17arXiv

Improvement of a superconducting magnet system makes induction of a strong magnetic field easier. This fact gives us a possibility of energy conversion by the Nernst effect. As the first step to study the Nernst element, we measured the conductivity, the Hall coefficient, the thermoelectric power and the Nernst coeffi…

Materials Science

Speckle from phase ordering systems

Gregory Brown、Per Arne Rikvold、Mark Sutton 等 4 位作者1997-09-16arXiv

The statistical properties of coherent radiation scattered from phase-ordering materials are studied in detail using large-scale computer simulations and analytic arguments. Specifically, we consider a two-dimensional model with a nonconserved, scalar order parameter (Model A), quenched through an order-disorder trans…

cond-mat.stat-mechMaterials Science

Efficient ab-initio method for the calculation of frequency dependent non-linear optical response in semiconductors: application to second harmonic generation

Sergey N. Rashkeev、Walter R. L. Lambrecht、Benjamin Segall1997-09-16arXiv

A LMTO implementation of Aversa and Sipe's length-gauge formalism for calculating the full frequency dependent second-harmonic generation in the independent particle approximation is presented. It is applied to GaAs, GaP, 3C-SiC, c-BN and wurtzite and zincblende GaN and AlN. The use of the scissor's operator for corre…

Materials Science

Effect of lattice distortions on the competition between the double and superexchange mechanisms inLaMnO3

O. N. Mryasov、R. F. Sabiryanov、A. J. Freeman 等 4 位作者1997-09-15Physical review. B, Condensed matter

Double exchange (DE), superexchange (SE), and higher-order contributions to the exchange interaction energy between Mn layers in ${\mathrm{LaMnO}}_{3}$ are studied using the linear-muffin-tin-orbital method as generalized to treat noncollinear magnetic configurations. The degree of the internal lattice distortion $(f)…

Multiferroics and related materialsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Photocurrent enhancement in light-soaked chalcogenide glasses

Naoko Toyosawa、Keiji Tanaka1997-09-15Physical review. B, Condensed matter

Photocurrent changes with light soaking have been studied in amorphous ${\mathrm{As}}_{2}{\mathrm{S}(\mathrm{S}\mathrm{e},\mathrm{T}\mathrm{e})}_{3}$ and Se and crystalline ${\mathrm{As}}_{2}{\mathrm{S}}_{3}$ and Se at 10--300 K. In the chalcogenide glasses the photoconductive degradation occurs at 300 K, while at low…

Chalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallographyPhase-change materials and chalcogenides