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Preparation and Insulation Properties of Epoxy-Layered Silicate Nanocomposite

Takahiro Imai、Fumio Sawa、Tamon Ozaki 等 6 位作者2004-01-01IEEJ Transactions on Fundamentals and Materials

Recent rapid progress in nanotechnology has focused research and development efforts on new high performance materials. Organic-inorganic hybrid materials such as nylon-layered silicate nanocomposites have attracted special interest and various studies continue to be conducted on thermoplastic resins.In this study, we…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry

Fatigue, Fretting Fatigue and Corrosion Characteristics of Biocompatible Beta Type Titanium Alloy Conducted with Various Thermo-Mechanical Treatments

Toshikazu Akahori、Mitsuo Niinomi、Hisao Fukui 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

Plain and fretting fatigue properties of β type titanium alloy, Ti-29Nb-13Ta-4.6Zr, underwent various thermo-mechanical treatments were investigated in order to judge its potential for biomedical applications. Ti-29Nb-13Ta-4.6Zr aged directly at 723 K for 259.2 ks after cold rolling shows the greatest fatigue strength…

Orthopaedic implants and arthroplastyHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Synthesis and characterization of functionalized 3,4-propylenedioxythiophene and its derivatives

Sarada P. Mishra、Rabindra Sahoo、Ashootosh V. Ambade 等 5 位作者2004-01-01Journal of Materials Chemistry

A functionalized monomer based on 3,4-propylenedioxythiophene, namely ProDOT-OH, was synthesized easily in a single step from commercially available starting materials and was successfully polymerized electrochemically resulting in the formation of an electroactive conjugated film on the working electrode. The presenc…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Efficient SERS substrates made by electroless silver deposition into patterned silicon structures

Fengming Liu、Mino Green2004-01-01Journal of Materials Chemistry

A nano fabrication process using caesium chloride in an island lithography scheme has been used to make wells in a silicon dioxide layer on silicon. Silver structures have been made in these wells using an electroless process that involves the reduction of silver ions and oxidation of silicon in the presence of fluori…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresNanofabrication and Lithography Techniques

Rapid synthesis of nanoparticles of hexagonal type In2O3 and spherical type Tl2O3 by microwave irradiation

Chitta Ranjan Patra、Aharon Gedanken2004-01-01New Journal of Chemistry

Semiconducting nanoparticles of indium and thallium oxides (In2O3 and Tl2O3) have been successfully synthesized in high yield (>95%) by microwave irradiation. The oxides are synthesized in a simple domestic microwave oven (DMO) by adding an aqueous ammonia solution to the aqueous solutions of indium chloride (InCl3) a…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsMicrowave Dielectric Ceramics Synthesis

Laser Transmission Welding of Semicrystalline Thermoplastics - Part II: Analysis of Mechanical Performance of Welded Nylon

Val A. Kagan、G. P. Pinho2004-01-01Journal of Reinforced Plastics and Composites

Selecting thermoplastics for a wide industrial application (automotive, appliances, lawn and garden, power tools, etc.) strongly depends on the plastic material composition, part design, processing (molding and welding) conditions. The structure of used thermoplastics, mechanical properties and composition (reinforcem…

Design Education and PracticeAdditive Manufacturing and 3D Printing TechnologiesMaterial Selection and Properties

Effect of substitution of 3,4-ethylenedioxythiophene (EDOT) on the electronic properties of the derived electrogenerated low band gap conjugated polymersElectronic supplementary information (ESI) available: experimental and spectroscopic data. See http://www.rsc.org/suppdata/jm/b4/b403818e/

Igor F. Perepichka、Eric Levillain、Jean Roncali2004-01-01Journal of Materials Chemistry

Introduction of a long alkoxy chain at an sp3 carbon of the ethylenedioxy bridge of EDOT induces a large increase of the band gap of the resulting polymer.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Role of pore curvature on the thermal stability of gold nanoparticles in mesoporous silica

Mangesh T. Bore、Hien N. Pham、Timothy L. Ward 等 4 位作者2004-01-01Chemical Communications

Pores arranged in a two-dimensional hexagonal structure inside spherical mesoporous silica particles help to prevent the thermal sintering of gold nanoparticles compared to straight pores in MCM-41.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Spectroscopy and Lanthanide Impurity Level Locations in CaGa[sub 2]S[sub 4]:Ln[sup 3+] (Ln=Ce, Pr, Tb, Er, Tm)

Aurélie Bessière、P. Dorenbos、C.W.E. van Eijk 等 6 位作者2004-01-01Journal of The Electrochemical Society

The emission and excitation spectra of single crystals of doped with and were measured with the aim to determine the location of the lanthanide energy levels relative to the valence and conduction band of the host crystal. By combining energies known for charge transfer bands involving trivalent lanthanides with syste…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Fabrication of lotus-type porous iron and its mechanical properties

Soong‐Keun Hyun、Teruyuki Ikeda、Hideo Nakajima2004-01-01Science and Technology of Advanced Materials

Porous iron whose long cylindrical pores are aligned in one direction has been fabricated by unidirectional solidification of the melt in a mixture gas of hydrogen (nitrogen) and argon. Both hydrogen and nitrogen saturated in the molten iron are rejected at the solid–liquid interface during the solidification due to t…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsPowder Metallurgy Techniques and Materials

Effects of Silane Coupling Agent Amount on Mechanical Properties and Hydrolytic Durability of Composite Resin After Hot Water Storage

Mansuang Arksornnukit、Hidekazu Takahashi、Norihiro Nishiyama2004-01-01Dental Materials Journal

The purpose of this study was to evaluate the effects of the silane coupling agent amount on the flexural properties and hydrolytic durability on an experimental composite resin for understanding the optimum amount of silanation. A spherical filler was silanated with 7 different amounts of gamma-MPTS, 0, 0.17, 0.34, 0…

Dental materials and restorationsAdvanced ceramic materials synthesisSurface Modification and Superhydrophobicity

Lanthanum modified bismuth titanate prepared by a hydrolysis method

Yanmei Kan、Xihai Jin、Guojun Zhang 等 6 位作者2004-01-01Journal of Materials Chemistry

La-modified bismuth titanate ceramics with compositions of Bi4−xLaxTi3O12 (x = 0, 0.2, 0.5, 0.75) were fabricated using powders prepared by a hydrolysis method. It was found that the partial substitution of lanthanum for bismuth in the Bi4Ti3O12 lattice significantly influenced the crystallization behavior, IR charact…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Chiral, single-molecule nanomagnets: synthesis, magnetic characterization and natural and magnetic circular dichroism

Philippe Gerbier、Neus Domingo、Jordi Gómez‐Segura 等 8 位作者2004-01-01Journal of Materials Chemistry

The first three chiral dodecamanganese clusters that behave as single-molecule magnets are reported. All reveal natural optical activity, which is stronger for the 2-chloropropionate derivative than for either the (S)-6-methoxy-α-methyl-2-naphthaleneacetate or the (S)-2-phenylbutyric acetate compounds. For the cluster…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

Preparation of alkyl-surface functionalized germanium quantum dots via thermally initiated hydrogermylationElectronic supplementary information (ESI) available: FT-IR spectra of the hydride terminated reaction intermediate and n-undecyl surface Ge nanoclusters. See http://www.rsc.org/suppdata/cc/b3/b314887d/

Enrico Fok、Meiling Shih、A. Meldrum 等 4 位作者2004-01-01Chemical Communications

A new, thermally initiated hydrogermylation-based method for the synthesis and surface functionalization of air- and moisture-stable germanium quantum dots is reported.

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceCarbon and Quantum Dots Applications

Formation of CdSe nanocrystals onto oxidized, ozonized single-walled carbon nanotube surfacesElectronic supplementary information (ESI) available: additional HRTEM images; discussion of FT-IR and UV-visible-near IR data; XPS spectra. See http://www.rsc.org/suppdata/cc/b4/b404204b/

Sarbajit Banerjee、Stanislaus S. Wong2004-01-01Chemical Communications

We present the in situ formation of crystalline CdSe quantum dots on the surfaces of oxidized, ozonized single-walled carbon nanotubes, which is a rational synthetic route to the synthesis of complex hierarchical assemblies.

Carbon Nanotubes in CompositesQuantum Dots Synthesis And PropertiesFullerene Chemistry and Applications

Joining Composite Materials and Structures: Some Thought-Provoking Possibilities

Robert W. Messler2004-01-01Journal of Thermoplastic Composite Materials

Custom-engineered functionally-specific properties leading to greatly enhanced design versatility have drawn designers to composites, but will make these materials-of-preference only if better ways can be found for producing better joints. The very micro- and macrostructure that gives rise to the unparalleled properti…

Design Education and PracticePolymer composites and self-healingMaterial Selection and Properties

Photo-reversible Pb2+-complexation of thermosensitive poly(N-isopropyl acrylamide-co-spiropyran acrylate) in water

Takayuki Suzuki、Tatsuya Kato、Hiraku Shinozaki2004-01-01Chemical Communications

Photo-reversible Pb2+-complexation in a purely aqueous environment exhibiting a thermosensitive phase transition at a lower critical solution temperature was achieved using a synthetic copolymer composed of N-isopropyl acrylamide and spiropyran acrylate.

Molecular Sensors and Ion DetectionPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Overcharge Protection for Rechargeable Lithium Batteries Using Electroactive Polymers

Guoying Chen、Thomas J. Richardson2004-01-01Electrochemical and Solid-State Letters

A conducting polymer shunt capable of providing overcharge protection for rechargeable lithium batteries via a reversible, internal, self-actuating mechanism is described. A microporous separator was impregnated with poly(3-butylthiophene), an electrochemically active polymer that becomes electronically conducting whe…

Advanced Battery Materials and TechnologiesAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Ultra-low-? materials based on nanoporous fluorinated polyimide with well-defined pores via the RAFT-moderated graft polymerization process

Y. W. Chen、W. C. Wang、W. H. Yu 等 8 位作者2004-01-01Journal of Materials Chemistry

Thermally-initiated living radical graft polymerization of poly(ethylene glycol) methyl ether methacrylate (PEGMA) with ozone-pretreated fluorinated polyimide (FPI) via the reversible addition–fragmentation chain transfer (RAFT)–moderated process was carried out. The chemical composition and structure of the copolymer…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Size dependent redox behavior of monolayer protected silver nanoparticles (2–7 nm) in aqueous medium

Nirmalya K. Chaki、Jadab Sharma、A. B. Mandle 等 6 位作者2004-01-01Physical Chemistry Chemical Physics

Monolayer protected nanoclusters are of current interest due to their ease of synthesis, high stability and possibility to precisely control their aspect ratio by preparation procedures, so that they can be tuned for a wide range of applications. Since these nanostructured metallic particles show fascinating size depe…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications