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Enhanced photoluminescence of porous silicon nanoparticles coated by bioresorbable polymers

M. B. Gongalsky、Alexander Kharin、Л. А. Осминкина 等 7 位作者2012-08-08Nanoscale Research Letters

A significant enhancement of the photoluminescence (PL) efficiency is observed for aqueous suspensions of porous silicon nanoparticles (PSiNPs) coated by bioresorbable polymers, i.e., polylactic-co-glycolic acid (PLGA) and polyvinyl alcohol (PVA). PSiNPs with average size about 100 nm prepared by mechanical grinding o…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

The new insight into dynamic crossover in glass forming liquids from the apparent enthalpy analysis

Julio Cesar Martinez-Garcia、Jorge Martinez-Garcia、Sylwester J. Rzoska 等 4 位作者2012-08-08The Journal of Chemical Physics

One of the most intriguing phenomena in glass forming systems is the dynamic crossover (T(B)), occurring well above the glass temperature (T(g)). So far, it was estimated mainly from the linearized derivative analysis of the primary relaxation time τ(T) or viscosity η(T) experimental data, originally proposed by Stick…

Material Dynamics and PropertiesGlass properties and applicationsPhotochemistry and Electron Transfer Studies

The Bioactive and Therapeutic Potential ofHemidesmus indicusR. Br. (Indian Sarsaparilla) Root

Sarita Das、Satpal Singh Bisht2012-08-08Phytotherapy Research

The root of Hemidesmus indicus R. Br., commonly known as Indian Sarsaparilla, is used traditionally to treat a wide variety of illnesses including rheumatism, leprosy, impotence, urinary tract and skin infections. The anticancer, antioxidant, anti-inflammatory, antipyretic, analgesic, antimicrobial, antidiabetic, hepa…

Essential Oils and Antimicrobial ActivityPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Cytotoxic effects of ZnO hierarchical architectures on RSC96 Schwann cells

Yixia Yin、Qiang Lin、Haiming Sun 等 7 位作者2012-08-08Nanoscale Research Letters

The alteration in intracellular Zn2+ homeostasis is attributed to the generation of intracellular reactive oxygen species, which subsequently results in oxidative damage of organelles and cell apoptosis. In this work, the neurotoxic effects of ZnO hierarchical architectures (nanoparticles and microspheres, the prism-l…

Nanoparticles: synthesis and applicationsAdvanced Nanomaterials in CatalysisAnesthesia and Neurotoxicity Research

Emergence of Polymer Stereocomplexes for Biomedical Applications

Annabelle Bertin2012-08-08Macromolecular Chemistry and Physics

Abstract Polylactide (PLA) and poly(methyl methacrylate) (PMMA) constitute, already for several decades, the gold standards for various biomedical applications due to their biocompatibility/inertness. Moreover, they have an additional property: they can form stereocomplexes (SCs) that have a more compact crystalline s…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Structure Refinement and Two-Center Luminescence of Ca3La3(BO3)5:Ce3+ under VUV–UV Excitation

Chunmeng Liu、H. Liang、Xiaojun Kuang 等 6 位作者2012-08-08Inorganic Chemistry

A series of Ca(3)La(3(1-x))Ce(3x)(BO(3))(5) phosphors were prepared by a high-temperature solid-state reaction technique. Rietveld refinement was performed using the powder X-ray diffraction (XRD) data, which shows occupation of Ce(3+) on both Ca(2+) and La(3+) sites with a preferred location on the La(3+) site over t…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesNuclear materials and radiation effects

Silicon Nanocrystal OLEDs: Effect of Organic Capping Group on Performance

Melanie L. Mastronardi、Eric J. Henderson、Daniel P. Puzzo 等 10 位作者2012-08-08Small

The synthesis of highly luminescent, colloidally-stable and organically-capped silicon nanocrystals (ncSi) and their incorporation into a visible wavelength organic light-emitting diode (OLED) is reported. By substituting decyl chains with aromatic allylbenzene capping ligands and size-selecting visible emitting ncSi,…

Quantum Dots Synthesis And PropertiesSemiconductor materials and devicesSilicon Nanostructures and Photoluminescence

Geometry of interfaces: topological complexity in biology and materials

Stephen T. Hyde、Gerd E. Schröder‐Turk2012-08-08Interface Focus

The geometrization of physics, which views physical phenomena through the prism of geometry and topology, has left a lasting imprint on many areas of physics, from Einstein's revolutionary adoption of Riemannian geometry to build his theories of relativity, to the rapidly multiplying zoo of topological phases in quant…

Supramolecular Self-Assembly in Materials

Influence of hydrogen addition to an Ar plasma on the structural properties of TiO2−x thin films deposited by RF sputtering

I. Luciu、Ruben Bartali、N. Laidani2012-08-08Journal of Physics D Applied Physics

Abstract The influence of hydrogen addition to an Ar plasma on the structural properties of TiO 2− x films produced by RF sputtering of a TiO 2 target at room temperature was studied. The structural properties of the films were characterized by x-ray photoelectron spectroscopy while the surface morphology was analysed…

ZnO doping and propertiesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Uncovering Aragonite Nanoparticle Self-assembly in Nacre—A Natural Armor

Gangsheng Zhang、Xiaodong Li2012-08-08Crystal Growth & Design

Nacre (mother-of-pearl) has long been identified as the best natural armor, with superior mechanical strength and eminent toughness. How does nacre disperse 95 vol % aragonite nanoparticles in 5% biopolymer matrix without agglomeration? Can we learn from this to produce nacre-like nanocomposites with a high volume fra…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Atomistic Molecular Dynamic Simulations of Multiferroics

Dawei Wang、Jeevaka Weerasinghe、L. Bellaïche2012-08-08Physical Review Letters

A first-principles-based approach is developed to simulate dynamical properties, including complex permittivity and permeability in the GHz-THz range, of multiferroics at finite temperatures. It includes both structural degrees of freedom and magnetic moments as dynamic variables in Newtonian and Landau-Lifshitz-Gilbe…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Optimized Design of a 32-nm CNFET-Based Low-Power Ultrawideband CCII

Ale Imran、Mohd. Hasan、Aminul Islam 等 4 位作者2012-08-08IEEE Transactions on Nanotechnology

CMOS technology faces significant challenges like tunneling effect, random dopant fluctuation, and line edge roughness at channel lengths below 45 nm. Carbon nanotube-based electronics seems to be a better prospect for extending the saturating Moore's law because of its higher mobility, scalability, and better channel…

Carbon Nanotubes in CompositesAnalog and Mixed-Signal Circuit DesignAdvancements in Semiconductor Devices and Circuit Design

Binding Modes of Fluorinated Benzylphosphonic Acids on the Polar ZnO Surface and Impact on Work Function

Christopher A. Wood、Hong Li、Paul Winget 等 4 位作者2012-08-08The Journal of Physical Chemistry C

The interfaces formed between a zinc-terminated polar zinc oxide (0002) surface and a series of chemisorbed fluorinated benzylphosphonic acids have been studied at the density functional theory level. The results indicate that there occur substantial changes in the adsorption energy and surface work function whether t…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsMolecular Junctions and Nanostructures

Temperature-Sensitive Macroscopic Assembly Based on Molecular Recognition

Yongtai Zheng、Akihito Hashidzume、Yoshinori Takashima 等 5 位作者2012-08-08ACS Macro Letters

The interaction of polyacrylamide(pAAm)-based gel modified with benzyl (Bz) moiety (Bz( x )-gel, where x denotes the mol % content of Bz moiety) with a pAAm-based gel possessing cyclodextrin (CD) moieties (αCD-gel, βCD-gel, and γCD-gel) was investigated at various temperatures to elucidate the effect of temperature on…

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Photochemical oxidation of CVD-grown single layer graphene

Shichao Zhao、Sumedh P. Surwade、Zhiting Li 等 4 位作者2012-08-08Nanotechnology

CVD-grown single layer graphene undergoes rapid photochemical oxidation in the presence of ultraviolet light and oxygen. The oxidation results in a homogeneous decay of the graphitic material; no nanoscale line cracks or pits were observed with an atomic force microscope. The conductivity of the graphene film decrease…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Synthesis and Structural Characterization of NaxSi136 (0 < x ≤ 24) Single Crystals and Low-Temperature Transport of Polycrystalline Specimens

Stevce Stefanoski、Christos D. Malliakas、Mercouri G. Kanatzidis 等 4 位作者2012-08-08Inorganic Chemistry

Na(x)Si(136) clathrate-II single crystals with x = 2.9, 5.1, 8.2, and 14.7 were prepared by a two-step process. In the first step, Na(24)Si(136) single crystals were grown from the precursor Na(4)Si(4) by reaction of the vapor phase with spatially separated graphite in a closed volume. In the second step, the Na(24)Si…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

PET copolyesters made from a d -mannitol-derived bicyclic diol

Cristina Lavilla、Antxon Martı́nez de Ilarduya、Abdelilah Alla 等 4 位作者2012-08-08Polymer Chemistry

The carbohydrate-based bicyclic diol 2,4:3,5-di-O-methylene-D-mannitol (Manx) was made to react in the melt with ethylene glycol and dimethyl terephthalate to produce random PExManxyT copolyesters covering the whole range of molar compositions. The copolyesters had weight-average molecular weights in the 33 000–41 000…

biodegradable polymer synthesis and propertiesCatalysis for Biomass ConversionCarbon dioxide utilization in catalysis

Angle-Dependent Carrier Transmission in Graphene p–n Junctions

Surajit Sutar、Everett Comfort、J. Liu 等 6 位作者2012-08-08Nano Letters

Angle-dependent carrier transmission probability in graphene p-n junctions is investigated. Using electrostatic doping from buried gates, p-n junctions are formed along graphene channels that are patterned to form different angles with the junction. A peak in the junction resistance is observed, which becomes pronounc…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Fast Synthesis of Thiolated Au25 Nanoclusters via Protection–Deprotection Method

Xun Yuan、Yong Yu、Qiaofeng Yao 等 5 位作者2012-08-08The Journal of Physical Chemistry Letters

This letter reports a new synthesis strategy for atomically precise Au nanoclusters (NCs) by using a protection-deprotection method. The key in our synthesis strategy is to introduce a surfactant molecule to protect thiolate-Au(I) complexes during their reduction. The protecting layer provides a good steric hindrance…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Adsorption of Fibronectin, Fibrinogen, and Albumin on TiO2: Time-Resolved Kinetics, Structural Changes, and Competition Study

Marta Pegueroles、Chiara Tonda‐Turo、Josep A. Planell 等 5 位作者2012-08-08Biointerphases

An understanding of protein adsorption process is crucial for designing biomaterial surfaces. In this work, with the use of a quartz-crystal microbalance with dissipation monitoring, we researched the following: (a) the kinetics of adsorption on TiO(2) surfaces of three extensively described proteins that are relevant…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications