Materials Literature
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Carbon nanotubes (CNTs) have been of high interest because of their potential to complement or to replace current biomedical sensor and assay techniques. By taking advantage of their unique electrical and optical properties, CNTs can be integrated into highly sensitive sensors and probes. We highlight recent advances…
The present study takes an analytical approach for solving the free vibration problem of a microstructured beam model, in which transverse displacement springs are added to allow for the transverse shear deformation effect in addition to the rotational springs. The exact vibration frequencies for the discrete microstr…
Abstract Polyimide (PI) aerogels containing rigid-rod biphenyl, benzimidazole, and triphenylpyridine moieties have been developed. The flexible PI aerogels exhibited excellent thermal stability with glass-transition temperatures (Tg) higher than 350 °C. Initial porous structures in the PI aerogels could be maintained…
The recently reported crystal structure of the Au28(TBBT)20 cluster (TBBT: p-tert-butylbenzenethiolate) is analyzed with (time-dependent) density functional theory (TD-DFT). Bader charge analysis reveals a novel trimeric Au3(SR)4 binding motif. The cluster can be formulated as Au14(Au2(SR)3)4(Au3(SR)4)2. The electroni…
Electromechanical coupling, a phenomenon present in collagenous materials, may influence cell-extracellular matrix interactions. Here, electromechanical coupling has been investigated via piezoresponse force microscopy in transparent and opaque membranes consisting of helical-like arrays of aligned type I collagen fib…
Highly fluorescing biological labels with excitation in near-infrared window II have attracted the interest of scientific community as they are capable of increasing both penetration depth and imaging quality. However, studies on the utilization of quantum dots (QDs) in biological imaging appear to be rather limited t…
Gold nanorods (AuNRs) have been largely investigated driven by their promising potentials in drug delivery, imaging, and photodynamic therapy because of their distinctive physicochemical properties. It is widely known that AuNRs can be taken up by different cells, however, the trafficking of the nanorods in cells are…
Ag/Ag2S hybrid nanostructures have recently received much attention, because of their synthetically tunable plasmonic properties and enhanced chemical stability. Sulfidation of pregrown Ag nanocrystals is a facile process for making Ag/Ag2S nanostructures. Understanding the sulfidation process can help in finely contr…
Auger recombination (AR) can be an important loss mechanism for optoelectronic devices, but it is typically not very efficient at low excitation densities. Here we show that in conductive quantum-dot solids, AR is the dominant charge carrier decay path even at excitation densities as low as 10⁻³ per quantum dot, and t…
Quantum-confined graphene-like electronic states are directly observed in graphene oxide and photothermally reduced graphene oxide via transient spectroscopy. An unexpected novel hybrid state arising from amorphous carbon-like peripheral structure with high sp(3) /sp(2) carbon ratio in close vicinity of confined graph…
Understanding in vivo drug release kinetics is critical for the development of nanoparticle-based delivery systems. In this study, we developed a fluorescence resonance energy transfer (FRET) imaging approach to noninvasively monitor in vitro and in vivo cargo release from polymeric nanoparticles. The FRET donor dye (…
Abstract The aim of this study is to investigate the effect of surface modification through sodium hydroxide (NaOH) treatment and fiber length on the tensile strength of coir fiber of reinforced epoxy composites. The coir fibers were treated with 2%, 4%, 6%, 8%, and 10% concentration of NaOH separately for 10 days. Th…
The development of effective and alternative tissue-engineered skin replacements to autografts, allografts and xenografts has became a clinical requirement due to the problems related to source of donor tissue and the perceived risk of disease transmission. In the present study 3D tissue engineered construct of serici…
Repair or replacement of damaged tissues using tissue engineering technology is considered to be a fine solution for enhanced treatment of different diseases such as skin diseases. Although the nanofibers made of synthetic degradable polymers, such as polylactic acid (PLA), have been widely used in the medical field,…
The concept of the electromagnetic wave transparency is introduced into the thermal field. The conditions of the thermal transparency for a multilayered sphere with isotropic coatings, a coated spheroid with an isotropic coating, and a coated sphere with a radial anisotropic core or a radial anisotropic coat are deduc…
Heterogeneous catalysts play an important role in surface catalytic reactions, but selective bond breaking and control of reaction products in catalytic processes remain significant challenges. High-vacuum tip-enhanced Raman spectroscopy (HV-TERS) is one of the best candidates to realize surface catalytic reactions. H…
The solubility of nifedipine (NIF) in binary mixtures of ethanol (EtOH) + water and propylene glycol (PG) + water at 293.2, 298.2, 303.2, 308.2, and 313.2 K was measured. The Jouyban–Acree model and its combination with van’t Hoff equation was used to predict the solubility of NIF in the mixed solvents at different te…
A neutron scattering investigation of the magnetoelectric coupling in PbFe${}_{1/2}$Nb${}_{1/2}$O${}_{3}$ has been undertaken. Ferroelectric order occurs below 400 K, as evidenced by the softening with temperature and subsequent recovery of the zone center transverse optic phonon mode energy ($\ensuremath{\hbar}{\ensu…
We present a comprehensive study of the adsorption behavior of iron phthalocyanine on the low-index crystal faces of silver. By combining measurements of the reciprocal space by means of photoelectron momentum mapping and low energy electron diffraction, the real space adsorption geometries are reconstructed. At monol…
We present a general formalism of ultrafast diffractive voltammetry approach as a contact-free tool to investigate the ultrafast surface charge dynamics in nanostructured interfaces. As case studies, the photoinduced surface charging processes in oxidized silicon surface and the hot electron dynamics in nanoparticle-d…