Materials Literature
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Nanotubular materials have unique water transport and storage properties that have the potential to advance separations, catalysis, drug delivery, and environmental remediation technologies. The development of novel hybrid materials, such as metal-organic nanotubes (MONs), is of particular interest, as these materials…
Fresh fruit not rotting vegetables: Ethylene released from fruits and vegetables accelerates their spoiling even in refrigerators. To oxidatively remove traces of ethylene from a gas mix, supported metal nanoparticles were tested. A Pt catalyst supported on mesoporous silica gave complete conversion of 50 ppm ethylene…
Barnacle cement (BC) was utilized 'beneficially' as a surface anchor on stainless steel (SS) for coupling of functional polymer brushes via "click" reactions in both "grafting-to" and "grafting-from" processes. Ethylene sulfide (ES), propargyl carbonylimidazole (PPC) and azidoethyl carbonylimidazole (AEC) reacted with…
We report detailed dc magnetization and linear and nonlinear ac susceptibility measurements on the hole doped disordered cobaltite La0.5Ba0.5CoO3. Our results show that the magnetically ordered state of the system consists of coexisting non-ferromagnetic phases along with percolating ferromagnetic clusters. The percol…
We report on many-body corrections to one-electron energy spectra of bulk bismuth tellurohalides---materials that exhibit a giant Rashba-type spin splitting of the band-gap edge states. We show that the corrections obtained in the one-shot $\mathit{GW}$ approximation noticeably modify the spin-orbit-induced spin split…
The electric, magnetic, and thermal properties of three perovskite cobaltites with the same 30% hole doping and ferromagnetic ground state were investigated down to very low temperatures. With decreasing size of large cations, the ferromagnetic Curie temperature and spontaneous moments of cobalt are gradually suppress…
Using the electrochemical route, cobalt ferrite nanoparticles (NPs) with two different sizes were synthesized and stabilized in water by coating with citric acid. The specific absorption rate (SAR) values of aqueous suspensions of magnetic nanoparticles with crystal sizes of 13 and 28 nm were investigated in the frequ…
The stoichiometric single- and bilayer ZnO(0001) have been prepared by reactive deposition of Zn on Au(111) and studied in detail with X-ray photoelectron spectroscopy, scanning tunneling microscopy, and density functional theory calculations. Both single- and bilayer ZnO(0001) adopt a planar, graphite-like structure…
This paper reports on photodetection properties of the graphene-Si schottky junction by measuring current–voltage characteristics under 1.55-$\mu{\rm m}$excitation laser. The measurements have been done on a junction fabricated by depositing mechanically exfoliated natural graphite on top of the pre-patterned silicon…
Co2FeAl (CFA) thin films with thickness varying from 10 nm to 115 nm have been deposited on MgO(001) substrates by magnetron sputtering and then capped by Ta or Cr layer. X-rays diffraction (XRD) revealed that the cubic $[001]$ CFA axis is normal to the substrate and that all the CFA films exhibit full epitaxial growt…
Theoretical research has predicted that a ripple of graphene generates an effective gauge field on its low-energy electronic structure and could lead to Landau quantization. Here, we demonstrate using a combination of an experimental method (scanning tunneling microscopy) and a theoretical approach (tight-binding appr…
A generic class of metamaterials is introduced and is shown to exhibit frequency dependent double negative effective properties. We develop a rigorous method for calculating the frequency intervals where either double negative or double positive effective properties appear and show how these intervals imply the existe…
1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) is a principal component of plastic explosives used in acts of terrorism and within improvised explosive devices, among others. Approaches to detect RDX compatible with remote, "stand-off" sampling that do not require preconcentration strategies, such as the swabs commonly e…
The thermal conductivities of solid silicon thin films and silicon thin films with periodic pore arrays are predicted using a Monte Carlo technique to include phonon-boundary scattering and the Boltzmann transport equation. The bulk phonon properties required as input are obtained from harmonic and anharmonic lattice…
In this paper, the use of biocompatible carbon dots (C-Dots) as caps on the surface of mesoporous silica nanoparticles (MSPs) for the design of intelligent on-demand molecular delivery and cell imaging system is described. These C-Dots-attached MSPs exhibited low cytotoxicity toward the cells and strong luminescence b…
Highly porous activated carbon with a large surface area and pore volume was synthesized by KOH activation using commercially available activated carbon as a precursor. By modification with polydimethylsiloxane (PDMS), highly porous activated carbon showed superhydrophobicity with a water contact angle of 163.6°. The…
As conventional transistors become smaller and thinner in the quest for higher performance, a number of hurdles are encountered. The discovery of electronic-grade 2-D crystals has added a new “layer” to the list of conventional semiconductors used for transistors. This paper discusses the propert…
Today, we stand at the edge of exploring carbon nanotube (CNT) and graphene based polymer nanocomposites as next generation multifunctional materials. However, irrespective of the methods of composite preparation, development of electrical conductivity with high electromagnetic interference (EMI) value at very low loa…
A robust prototypical anti-icing coating with a self-lubricating liquid water layer (SLWL) is fabricated via grafting cross-linked hygroscopic polymers inside the micropores of silicon wafer surfaces. The ice adhesion on the surface with SLWL is 1 order of magnitude lower than that on the superhydrophobic surfaces and…
Vascularization is one of the great challenges that tissue engineering faces in order to achieve sizeable tissue and organ substitutes that contain living cells. There are instances, such as skin replacement, in which a tissue-engineered substitute does not absolutely need a preexisting vascularization. However, tissu…