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Alumina−Pepsin Hybrid Nanoparticles with Orientation-Specific Enzyme Coupling

Ju Li、Jianquan Wang、Vasilis G. Gavalas 等 5 位作者2002-12-06Nano Letters

Hybrid alumina nanoparticles with pepsin were prepared in a controlled and efficient manner. Phosphorylated pepsin can be coupled to alumina through the interaction between phosphoserine on pepsin and the alumina surface in an orientation-specific manner. A comparison of data obtained with nanoparticles and microsized…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesPolymer Surface Interaction Studies

Seasonal and interannual variations in diatom assemblages in Murray River connected wetlands in north-west Victoria, Australia

Peter Gell、I. R. K. Sluiter、Jennie Fluin2002-12-06Marine and Freshwater Research

Epipelic diatom assemblages collected from three wetlands connected to the Murray River displayed considerable variation in response to flooding and drying phases. Murray River water input usually generated diatom assemblages dominated by Aulacoseira species. After isolation, the diatom flora of two wetlands shifted t…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Multiedge refinement of extended x-ray-absorption fine structure of manganese zinc ferrite nanoparticles

S. Calvin、Everett E. Carpenter、Bruce Ravel 等 5 位作者2002-12-06Physical review. B, Condensed matter

The structure of nanoparticle manganese zinc ferrites synthesized by a reverse micellar method is determined by analysis of the extended x-ray-absorption fine structure in combination with other techniques. Both empirical and theoretical standards are employed; manganese, zinc, and iron edges are refined simultaneousl…

Magnetic Properties and Synthesis of FerritesX-ray Spectroscopy and Fluorescence AnalysisIron oxide chemistry and applications

HPLC of Monolayer-Protected Gold Nanoclusters

Victoria L. Jimenez、Michael C. Leopold、Carolyn L. Mazzitelli 等 5 位作者2002-12-06Analytical Chemistry

Polydisperse samples of Au nanoparticles protected with monolayers of hexanethiolate ligands (C6 MPCs) and with mixed monolayers of hexanethiolate and mercaptoundecanoic acid (C6/MUA MPCs) have been chromatographically separated using C8 120-A columns and acetone/ toluene mobile phase. The spectral details of eluted p…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical sensors and biosensorsElectrochemical Analysis and Applications

Structural Variations Across the Lanthanide Series of Macrocyclic DOTA Complexes: Insights into the Design of Contrast Agents for Magnetic Resonance Imaging

F. Benetollo、G. Bombieri、Luisella Calabi 等 5 位作者2002-12-06Inorganic Chemistry

It was early shown that the macrocyclic Ln(DOTA) complexes (DOTA = 1,4,7,10-tetra-azacyclododecane-N,N',N' ',N' "-tetraacetic acid) exists in solution as a mixture of two enantiomeric pairs of diastereoisomers differing in the ligand conformation, namely, square antiprismatic (SA) and twisted square antiprismatic (TSA…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Noncoaxial resonance of an isolated multiwall carbon nanotube

Jang‐Hee Yoon、C. Q. Ru、A. Mioduchowski2002-12-06Physical review. B, Condensed matter

This brief report studies noncoaxial mechanical resonance of an isolated multiwall carbon nanotube. Noncoaxial resonant frequencies and the associated noncoaxial vibrational modes are calculated. For shorter or periodically supported multiwall carbon nanotubes, the lowest noncoaxial resonant frequencies predicted by t…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structures

Quasiperiodic extended Bloch states in a surface wave experiment

M. Torres、J. L. Aragon、Juan P. Adrados 等 5 位作者2002-12-06arXiv

Bloch-like surface waves associated with a quasiperiodic structure are observed for the first time in a classic wave propagation experiment which consists of pulse propagation with a shallow fluid covering a quasiperiodically drilled bottom. We show that a transversal pulse propagates as a plane wave with quasiperiodi…

Materials Science

Enhanced substrate-induced coupling in two-dimensional gold nanoparticle arrays

Nordin Félidj、J. Aubard、G. Lévi 等 7 位作者2002-12-06Physical review. B, Condensed matter

The influence of substrate induced coupling on plasmon excitations is probed by means of visible and near-infrared extinction microspectroscopy on various arrays of gold oblate spheroidal particles deposited onto a 20-nm-thick gold film. At zero incidence angle and for an interparticle spacing smaller than 250 nm, the…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Magnetic-field dependence of electron spin relaxation in n-type semiconductors

Franz X. Bronold、Ivar Martin、Avadh Saxena 等 4 位作者2002-12-06arXiv

We present a theoretical investigation of the magnetic field dependence of the longitudinal ($T_1$) and transverse ($T_2$) spin relaxation times of conduction band electrons in n-type III-V semiconductors. In particular, we find that the interplay between the Dyakonov-Perel process and an additional spin relaxation ch…

Materials Science

Mode coupling and polar nanoregions in the relaxor ferroelectricPb(Mg1/3Nb2/3)O3

S. Wakimoto、C Stock、Zuo‐Guang Ye 等 6 位作者2002-12-06Physical review. B, Condensed matter

We present a quantitative analysis of the phonon line shapes obtained by neutron inelastic scattering methods in the relaxor ferroelectric $\mathrm{Pb}({\mathrm{Mg}}_{1/3}{\mathrm{Nb}}_{2/3}){\mathrm{O}}_{3}$ (PMN). Differences in the shapes and apparent positions of the transverse acoustic-- (TA) and transverse optic…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Direct evidence of soft mode behavior near the Burns temperature in thePbMg1/3Nb2/3O3relaxor ferroelectric

S. B. Vakhrushev、Stuart Shapiro2002-12-06Physical review. B, Condensed matter

Inelastic neutron scattering measurements of the relaxor ferroelectric ${\mathrm{PbMg}}_{1/3}{\mathrm{Nb}}_{2/3}{\mathrm{O}}_{3}$ (PMN) in the temperature range $490\mathrm{K}<T<880\mathrm{K}$ directly observe the soft mode (SM) associated with the Curie-Weiss behavior of the dielectric constant $\ensuremath{\va…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

The Alloy Theoretic Automated Toolkit: A User Guide

A. van de Walle、M. Asta、G. Ceder2002-12-06arXiv

Although the formalism that allows the calculation of alloy thermodynamic properties from first-principles has been known for decades, its practical implementation has so far remained a tedious process. The Alloy Theoretic Automated Toolkit (ATAT) drastically simplifies this procedure by implementing decision rules ba…

Materials Sciencecond-mat.stat-mech

Energy spectra and eigenstates of quasiperiodic tight-binding Hamiltonians

Uwe Grimm、Michael Schreiber2002-12-06arXiv

Analytic and numerical results for quasiperiodic tight-binding models are reviewed, with emphasis on two and three-dimensional models which so far are beyond a mathematically rigorous treatment. In particular, we consider energy spectra of aperiodic tight-binding models and the corresponding level statistics, which ar…

cond-mat.dis-nnMaterials ScienceStrongly Correlated Electrons

Left handed materials

P. Markos、C. M. Soukoulis2002-12-06arXiv

We review recent progress in the studies of left handed materials.

Materials Science

Simple model for the power-law blinking of single semiconductor nanocrystals

R. Verberk、Antoine M. van Oijen、Michel Orrit2002-12-06OpenAlex

We assign the blinking of nanocrystals to electron tunneling towards a uniform spatial distribution of traps. This naturally explains the power-law distribution of off times, and the power-law correlation function we measured on uncapped CdS dots. Capped dots, on the other hand, present extended on times leading to a…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Low Temperature SOFCs with the Ruthenium Pyrochlore Cathode

Takashi Takeda、Ryoji Kanno、Tsubosaka Kenji 等 4 位作者2002-12-05Electrochemistry

Bismuth ruthenium oxide with the pyrochlore structure was examined for the cathode of SOFC. The power generating characteristics of the SOFC was examined for the single cell of the SOFC constructed with the pyrochlore cathode with a composition, Bi2Ru2O7, and the yttria stabilized zirconia as the electrolyte. The char…

Advancements in Solid Oxide Fuel CellsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Theoretical Study on Cystine-Based Cyclobisamides

Francesco Ferrante、Gianfranco La Manna2002-12-05The Journal of Physical Chemistry A

Nanotubular structures made of cystine-based cyclobisamides assembled by stacking through hydrogen bonding between amidic groups were recently synthesized. A quantum mechanical study at Hartree−Fock and DFT levels was performed on such monomers and dimers, and the obtained geometrical data were compared with the corre…

Synthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Water and oil repellency of polysiloxanes with highly fluorinated alkyl side chains

Yutaka Furukawa、Mami Kotera2002-12-05Journal of Applied Polymer Science

Abstract A series of fluorinated polysiloxanes (FLSs) with the 3,3,4,4,5,5,6,6,6‐nonafluorohexyl group (C 4 F 9 C 2 H 4 ), 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11‐heptadecafluoroundecyl group (C 8 F 17 C 3 H 6 ), 3‐(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9‐heptadecafluorononanamido) propyl group [HDFNAG; C 8 F 17 (CO)NHC 3…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry

Biodegradable brushlike graft polymers. I. Polymerization of ϵ‐caprolactone onto water‐soluble hydroxypropyl cellulose as the backbone by the protection of the trimethylsilyl group

Caiqi Wang、Yuping Dong、Huimin Tan2002-12-05Journal of Polymer Science Part A Polymer Chemistry

Abstract After the protection of partial hydroxyl groups with trimethylsilyl (TMS) groups, hydroxypropyl cellulose becomes soluble in organic solvents, and the number of hydroxyl groups as initiating groups can be controlled. As a result, a new brushlike graft poly(ϵ‐caprolactone) can be prepared with hydroxypropyl ce…

Bone Tissue Engineering MaterialsHydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and properties