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Effects of (Small) Permanent Charge and Channel Geometry on Ionic Flows via Classical Poisson--Nernst--Planck Models

Shuguan Ji、Weishi Liu、Mingji Zhang2015-01-01SIAM Journal on Applied Mathematics

In this work, we examine effects of permanent charges on ionic flows through ion channels via a quasi-one-dimensional classical Poisson--Nernst--Planck (PNP) model. The geometry of the three-dimensional channel is presented in this model to a certain extent, which is crucial for the study in this paper. Two ion specie…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesQuantum, superfluid, helium dynamics

Partial Oxidation of Methane to Methanol over Heterogeneous Catalyst Co/ZSM-5

Yuni Krisyuningsih Krisnandi、Bimo Ary Pujangga Putra、Muhammad Bahtiar 等 6 位作者2015-01-01Procedia Chemistry

The catalytic activities of four types of Co/ZSM-5 zeolites in partial oxidation of methane were compared to observe the effect of pore size and cobalt species to the reaction. Two types of ZSM-5 structures: microporous and hierarchical; and two ways of Co loading: impregnation and ion exchange were studied. The catal…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

New AIEgens containing tetraphenylethene and silole moieties: tunable intramolecular conjugation, aggregation-induced emission characteristics and good device performance

Jie Yang、Ning Sun、Jing Huang 等 9 位作者2015-01-01Journal of Materials Chemistry C

Three AIE luminogens were successfully synthesized by the covalent incorporation of tetraphenylethene into the dibenzosilole core, and their emission colours were tuned through simple structural modifications.

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

One-pot synthesis of sandwich-like reduced graphene oxide@CoNiAl layered double hydroxide with excellent pseudocapacitive properties

Peipei Huang、Changyan Cao、Yongbin Sun 等 6 位作者2015-01-01Journal of Materials Chemistry A

Sandwich-like nanocomposites with cobalt nickel aluminum layered double hydroxide growth on both sides of reduced graphene oxide show excellent pseudocapacitive properties.

Supercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and ApplicationsNanomaterials for catalytic reactions

A Λ-shaped donor–π–acceptor–π–donor molecule with AIEE and CIEE activity and sequential logic gate behaviour

Xiaofei Mei、Guixiu Wen、Jingwei Wang 等 7 位作者2015-01-01Journal of Materials Chemistry C

A novel Λ-shaped donor–π–acceptor–π–donor molecule BCPMM with AIEE, CIEE and polymorphism-dependent fluorescence properties was utilized to construct five simple logic gates and more than ten kinds of sequential combinational logic systems.

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Boron based two-dimensional crystals: theoretical design, realization proposal and applications

Xianbin Li、Sheng‐Yi Xie、Hui Zheng 等 5 位作者2015-01-01Nanoscale

The successful realization of free-standing graphene and the various applications of its exotic properties have spurred tremendous research interest for two-dimensional (2D) layered materials. Besides graphene, many other 2D materials have been successfully produced by experiment, such as silicene, monolayer MoS2, few…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

The functional dissection of the plasma corona of SiO 2 -NPs spots histidine rich glycoprotein as a major player able to hamper nanoparticle capture by macrophages

Chiara Fedeli、Daniela Segat、Regina Tavano 等 10 位作者2015-01-01Nanoscale

A coat of strongly-bound host proteins, or hard corona, may influence the biological and pharmacological features of nanotheranostics by altering their cell-interaction selectivity and macrophage clearance. With the goal of identifying specific corona-effectors, we investigated how the capture of amorphous silica nano…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesBlood properties and coagulation

Interaction between Human Serum Albumin and Different Anatase TiO2 Nanoparticles: A Nano-bio Interface Study

Viviana Vergaro、Claudia Carlucci、Mariafrancesca Cascione 等 10 位作者2015-01-01Nanomaterials and Nanotechnology

In this investigation, differently shaped and surface functionalized TiO 2 anatase nanoparticles and human serum albumin (HSA) were selected to study protein-nanoparticles interaction both in a solution and on flat surfaces, thereby mimicking a medical device. Anatase nanocrystals were characterized by transmission el…

Nanoparticles: synthesis and applicationsQuantum Dots Synthesis And PropertiesElectrochemical Analysis and Applications

Alignment of nanostructured tripeptide gels by directional ultrasonication

Charalampos G. Pappas、Pim W. J. M. Frederix、Tapiwa Mutasa 等 11 位作者2015-01-01Chemical Communications

We demonstrate an in situ ultrasonic approach to influence self-assembly across the supramolecular to micron length scales, showing enhancement of supramolecular interactions, chirality and orientation, which depends on the peptide sequence and solvent environment. This is the first successful demonstration of using o…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Enhanced average thermoelectric figure of merit of n-type PbTe 1−x I x –MgTe

Priyanka Jood、M. Ohta、Masaru Kunii 等 7 位作者2015-01-01Journal of Materials Chemistry C

The average thermoelectric figure of merit <italic>ZT</italic> of n-type PbTe <sub>1−x</sub> I <sub>x</sub> –MgTe is successfully enhanced through nano and meso structuring.

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Highly flexible and robust N-doped SiC nanoneedle field emitters

Shanliang Chen、Pengzhan Ying、Lin Wang 等 10 位作者2015-01-01NPG Asia Materials

Flexible field emission (FE) emitters, whose unique advantages are lightweight and conformable, promise to enable a wide range of technologies, such as roll-up flexible FE displays, e-papers and flexible light-emitting diodes. In this work, we demonstrate for the first time highly flexible SiC field emitters with low…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Effect of Al/Si substitution on the structure and luminescence properties of CaSrSiO 4 :Ce 3+ phosphors: analysis based on the polyhedra distortion

Shihai Miao、Zhiguo Xia、Мaxim S. Моlokeev 等 6 位作者2015-01-01Journal of Materials Chemistry C

The polyhedra distortion originating from the variation of [(Si,Al)O <sub>4</sub> ] induced a red-shift of the Ce <sup>3+</sup> emission in CaSrSi <sub>1−x</sub> Al <sub>x</sub> O <sub>4</sub> :Ce <sup>3+</sup> ,Li <sup>+</sup> phosphors.

Luminescence Properties of Advanced MaterialsGlass properties and applicationsNuclear materials and radiation effects

Photo-crosslinking of a self-assembled coumarin-dipeptide hydrogel

Se Hye Kim、Yuan Sun、Jonah A. Kaplan 等 5 位作者2015-01-01New Journal of Chemistry

The photo-crosslinking of a coumarin-functionalized dipeptide hydrogel enhances the stability of the self-assembled nanofibers that comprise the hydrogel.

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

The Biocompatibility of Degradable Magnesium Interference Screws: An Experimental Study with Sheep

Ulrich Thormann、Volker Alt、Lydia Heimann 等 9 位作者2015-01-01BioMed Research International

Screws for ligament reconstruction are nowadays mostly made of poly-L-lactide (PLLA). However, magnesium-based biomaterials are gathering increased interest in this research field because of their good mechanical property and osteoanabolic influence on bone metabolism. The aim of this pilot study was to evaluate the b…

Orthopaedic implants and arthroplastyMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

An all-copper plasmonic sandwich system obtained through directly depositing copper NPs on a CVD grown graphene/copper film and its application in SERS

Xuanhua Li、Xingang Ren、Yongxing Zhang 等 5 位作者2015-01-01Nanoscale

A simple, low-cost, all-copper sandwich system has been obtained through directly depositing Cu nanoparticles (NPs) onto a graphene sheet, which has already been grown on a Cu foil (Cu-NGF). The new design inherits two key advantages: (1) the materials of the NGF coupling system are composed of only cheaper Cu instead…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchCopper-based nanomaterials and applications

Sugar and pH dual-responsive snap-top nanocarriers based on mesoporous silica-coated Fe 3 O 4 magnetic nanoparticles for cargo delivery

Xilong Qiu、Qinglan Li、Yue Zhou 等 6 位作者2015-01-01Chemical Communications

A facile strategy to prepare snap-top magnetic nanocarriers has been developed where ultrasmall superparamagnetic Fe3O4 nanoparticles were used as the core with mesoporous silica as the shell followed by the covalent installation of a layer of β-cyclodextrins on the outer surfaces. The smart hybrid nanomaterials showe…

Nanoparticle-Based Drug DeliveryDendrimers and Hyperbranched PolymersCharacterization and Applications of Magnetic Nanoparticles

Electronic structures and electronic spectra of all-boron fullerene B 40

Rongxing He、Xiao Cheng Zeng2015-01-01Chemical Communications

This study is motivated by the recent discovery of the first all-boron fullerene analogue, a B40 cluster with D(2d) point-group symmetry, dubbed borospherene (Nat. Chem., 2014, 6, 727). Insight into the electronic structures and spectral properties of B40 is timely and important to understand the borospherene and the…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsBoron Compounds in Chemistry

Three-dimensional two-fold interpenetrated Cr III –Gd III heterometallic framework as an attractive cryogenic magnetorefrigerant

Sui‐Jun Liu、Xin-Rong Xie、Teng‐Fei Zheng 等 7 位作者2015-01-01CrystEngComm

The hydrothermal reaction of CrO3, Gd2O3 and iminodiacetic acid (H2IDA) yields a three-dimensional (3D) two-fold interpenetrated complex [CrGd(IDA)2(C2O4)]∞ (1). The oxalate anions were generated in situ under hydrothermal conditions. Magnetic studies suggest the presence of weak antiferromagnetic coupling between CrI…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLayered Double Hydroxides Synthesis and Applications