Materials Literature
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A two-dimensional chiral structure with an h-shape and H-shape on opposing sides of a dielectric layer is proposed that can realize simultaneously dual-band asymmetric transmission of linearly and circularly polarized waves in the near-infrared band. Meanwhile, the structure realizes a maximum asymmetric transmission…
K2NiF4-type LaSrAlO4 and Sr2TiO4 exhibit anisotropic and isotropic thermal expansion, respectively; however, their structural origin is unknown. To address this unresolved issue, the crystal structure and thermal expansion of LaSrAlO4 and Sr2TiO4 have been investigated through high-temperature neutron and synchrotron…
We investigate support effects on the CO oxidation reaction on graphene–supported Pt 13 nanoclusters using first-principles density functional theory calculations. As CO adsorption on Pt 13 clusters is found to be substantially stronger than O adsorption, we focus on understanding CO oxidation kinetics on CO-saturated…
ABSTRACT We report here a simple strategy for fabricating asymmetrically superhydrophobic cotton fabric via a mist copolymerization of three monomers, 2,2,2‐trifluoroethyl methacrylate (TFMA), 2‐isocyanatoethyl methacrylate (IEM), and divinylbenzene (DVB). The copolymer layer on the cotton surface was confirmed by X‐r…
Superhydrophobic/hydrophobic surfaces have attracted wide attention because of their broad applications in various regions, including coating, textile, packaging, electronic devices, and bioengineering. Many studies have been focused on the fabrication of superhydrophobic/hydrophobic surfaces using natural materials.…
Hybrid solar cells made of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) ( PEDOT: PSS) and appropriate amounts of a cosolvent and a fluorosurfactant on planar n-type silicon substrates showed a photoconversion efficiency (PCE) of above 13%. These cells also exhibited stable, reproducible, and high external q…
Abstract The coordination compound Eu(DAF) 2 (NO 3 ) 3 ( 1 , DAF = 4,5‐diazafluorene), which shows strong red fluorescence, has been synthesized and characterized. The luminescence‐quenching effect of 1 has been applied to the detection of water in CH 3 CN. For the first time, the response mechanism has been uncovered…
ABSTRACT A series of phenyl polysiloxane‐modified polyurea/polyurethanes ( SPUs ) with different silicone loadings (10, 20, 30, and 40 wt %) have been designed and synthesized. The structures of SPUs were confirmed by 1 H NMR, 13 C NMR, and FT‐IR. The impact of phenyl polysiloxane content on the properties of SPUs was…
Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses. The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts low surface free ene…
ABSTRACT In this article, we report on the process for creating microcellular and nanocellular polysulfone (PSU) foams. Microcellular foams with cell size up to 8 µm and nanocellular foams with cell size in the range of 20–30 nm were created. A range of CO 2 concentration was achieved by varying saturation temperature…
Long circulation in the blood, efficient cellular internalization, and intracellular drug release in the tumor cells are major challenges in the development of ideal anticancer drug delivery systems. In this paper, hydrophilicity/hydrophobicity reversable and redox-sensitive poly(oligo(ethylene glycol) methacrylates-s…
In this Letter, we disclose a fast switchable Fresnel zone lens (FZL) by confining the ferroelectric liquid crystals (FLCs) in multiple microscopically defined photo-aligned alignment domains. The photo-alignment (PA) offers good control on the anchoring energy (W) by mean of irradiation doses (ID) and thus excellent…
Long lifetimes of hot carriers can lead to qualitatively new types of responses in materials. The magnitude and time scales for these responses reflect the mechanisms governing energy flows. We examine the microscopics of two processes which are key for energy transport, focusing on the unusual behavior arising due to…
Multiferroic ceramics with extraordinary susceptibilities coexisting are vitally important for the multi-functionality and integration of electronic devices. However, multiferroic composites, as the most potential candidates, will introduce inevitable interface deficiencies and thus dielectric loss from dissimilar pha…
Research interests on radiosensitive property of gold nanoparticles (GNPs) are rapidly raised because of the extensively proved in vitro effectiveness and clinical necessity. However, the issue of targeted accumulation of GNPs in tumor tissues hindered the transference to in vivo applications. In this study, hybrid na…
We use first-principles density functional theory to investigate the effect of both tensile and compressive strain on the work functions of various metal dichalcogenide monolayers. We find that for all six species considered, including MoS2, WS2, SnS2, VS2, MoSe2 and MoTe2, that compressive strain of up to 10% decreas…
Two new cesium selenites containing TaO6 or TiO4F2 octahedra, namely, Cs(TaO2)3(SeO3)2 (1) and Cs(TiOF)3(SeO3)2 (2), have been prepared using standard high temperature solid-state method and hydrothermal reaction, respectively. Compound 1 crystallizes in P3̅m1 and features an unusual [(TaO2)3(SeO3)2](-) sandwich-like…
BACKGROUND: Novel polymeric nanoparticles (NPs) specifically designed for delivering chemotherapeutics in the body and aimed at improving treatment activity and selectivity, cover a very relevant area in the field of nanomedicine. Here, we describe how to build a polymer shell of Hyaluronan (HA) and Polyethyleneimine…
Graphene-enhanced Raman scattering (GERS) spectra and coherent anti-Stokes Raman scattering (CARS) of thymine molecules adsorbed on a single-layer graphene were studied. The enhancement factor was shown to depend on the molecular groups of thymine. In the GERS spectra of thymine, the main bands are shifted with respec…
Brain tumor is one of the most challenging diseases to treat. The major obstacle in the specific drug delivery to brain is blood-brain barrier (BBB). Mostly available anti-cancer drugs are large hydrophobic molecules which have limited permeability via BBB. Therefore, it is clear that the protective barriers confining…